Corrosion inhibition of carbon steel in perchloric acid by potassium iodide

  • Authors

    • Tarik Attar Superior School of Applied Sciences of Tlemcen, BP 165, 13000 Bel Horizon, Tlemcen, Algeria
    • Abbes Benchadli Laboratory Toxicomed, University Abou Beker Belkaid Tlemcen, BP119, 13000 Tlemcen, Algeria
    • Esma Choukchou-Braham Laboratory Toxicomed, University Abou Beker Belkaid Tlemcen, BP119, 13000 Tlemcen, Algeria
    2019-05-05
    https://doi.org/10.14419/ijac.v7i1.19651
  • Corrosion Inhibition, Carbon Steel, Potassium Iodide, Weight Loss, Adsorption Isotherm.

  • Corrosion processes are responsible for numerous losses mainly in the industrial scope. It is clear that the best way to combat it is pre-vention. The effect of temperature on the corrosion behavior of carbon steel was studied by mass loss measurements in the temperature range 293–333 K. The inhibition efficiency increases with increasing temperature. The inhibitor showed 97.98 % inhibition efficiency at 1.10-3 M concentration of iodide potassium in 1 M perchloric acid solutions. The values of activation energy (Ea), enthalpy of activation (ΔHa) and entropy of activation (ΔSa), free energy of adsorption (ΔGads), enthalpy of adsorption (ΔHads) and entropy of adsorption (ΔSads) were calculated. The adsorption of this inhibitor on carbon steel surface obeys Langmuir adsorption isotherm.

     

     

  • References

    1. [1] Abd El-Maksoud SA, Fouda AS (2005), Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium. Materials Chemistry and Physics, 93, 84-90. https://doi.org/10.1016/j.matchemphys.2005.02.020.

      [2] Al-Otaibi MS, Al-Mayouf AM, Khan M, Mousa AA, Al-Mazroa SA (2014), Corrosion inhibitory action of some plant extracts on the corrosion of mild steel in acidic media. Arabian Journal of Chemistry, 7, 340-346. https://doi.org/10.1016/j.arabjc.2012.01.015.

      [3] Riggs OL (1973), Corrosion Inhibitors (2ndedn), CC. Nathan, Houston.

      [4] Uhlig HH, Revie RW (1985), Corrosion and corrosion control. John Wiley & Sons, New York.

      [5] Loto RT, Loto CA, Popoola API (2012), Corrosion inhibition of thiourea and thiadiazole derivatives: a review. Journal of Materials and Environmental Science, 3, 885-894.

      [6] Attar T, Larabi L (2014), The Inhibition Effect of Potassium Iodide on the Corrosion of Pure Iron in Sulphuric Acid. Advances in Chemistry, 2014, 1-5. https://doi.org/10.1155/2014/827514.

      [7] Bereket G, Yurt A (2002), Inhibition of the corrosion of low carbon steel in acidic solution by selected quaternary ammonium compounds. Anti-Corrosion Methods and Materials, 49, 210-220. https://doi.org/10.1108/00035590210431764.

      [8] Attar T, Larabi L (2014), Corrosion inhibition of cold rolled steel in 0.5M H2SO4 by potassium iodide. Der Pharma Chemica, 6, 181-186.

      [9] Xiumei W, (2012), The Inhibition Effect of Bis-Benzimidazole Compound for Mild Steel in 0.5 M HCl Solution. Int. J. Electrochem Sci, 7, 11149-11160.

      [10] Zarrok H, Zarrouk A, Salghi A, Ramli Y, Hammouti B (2012), Adsorption and Inhibition Effect of 3-Methyl-1-Propargylquinoxalin-2(1H)-One on Carbon Steel Corrosion in Hydrochloric Acid. Int. J. Electrochem. Sci, 7, 8958-8973.

      [11] Obot IB, Obi-Egbedi NO (2010), Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: Experimental and theoretical investigation. Corros Sci, 52, 198-204. https://doi.org/10.1016/j.corsci.2009.09.002.

      [12] Benchadli A, Attar T, Choukchou-Braham E (2018), Corrosion Inhibition of Carbon Steel (XC 38) in Hydrochloric Acid by Potassium Iodide. Journal of Advanced Research in Science and Technology, 5, 834-844.

      [13] Obot IB, Obi-Egbedi NO (2009), Umoren, Antifungal drugs as corrosion inhibitors for aluminium in 0.1 M HCl. Corros. Sci, 51, 1868-1875. https://doi.org/10.1016/j.corsci.2009.05.017.

      [14] Elmsellem H, Basbas N, Chetouani A, Aouniti A, Radi A (2014), Quantum Chemical Studies and Corrosion Inhibitive Properties of Mild Steel by Some Pyridine Derivatives in 1 N HCl Solution. Portugaliae Electrochimica Acta, 32, 77-108. https://doi.org/10.4152/pea.20140207.

      [15] Benabdellah M, Aouniti A, Dafali A, Hammouti B, Benkaddouret M (2006), Investigation of the inhibitive effect of triphenyltin 2-thiophene carboxylate on corrosion of steel in 2 M H3PO4 solutions. Applied Surface Science, 252, 8341–8347. https://doi.org/10.1016/j.apsusc.2005.11.037.

      [16] Abdel Hameed RE (2011), Ranitidine Drugs as Non-Toxic Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Medium. Portugaliae Electrochimica Acta, 29, 273-285. https://doi.org/10.4152/pea.201104273.

      [17] Tang LB, Mu GN, Liu GH (2003), The effect of neutral red on the corrosion inhibition of cold rolled steel in 1.0 M hydrochloric acid,†Corros. Sci, 45, 2251-2262. https://doi.org/10.3390/ma6062436.

      [18] Desimone MP, Gordillo G, Simison SN (2011), The effect of temperature and concentration on the corrosion inhibition mechanism of an amphiphilic amido-amine in CO2 saturated solution. Corrosion Science, 53, 4033–4043. https://doi.org/10.1016/j.corsci.2011.08.009.

      [19] Fekry AM, Ameer MA (2010), Corrosion Inhibition of Mild Steel in Acidic Media Using Newly Synthesized Heterocyclic Organic Molecules. International Journal of Hydrogen Energy, 35, 7641–7651. https://doi.org/10.1016/j.ijhydene.2010.04.111.

      [20] Tang LB, Mu GN, Liu GH (2003), The effect of neutral red on the corrosion inhibition of cold rolled steel in 1.0 M hydrochloric acid. Corros. Sci, 45, 2251-2262. https://doi.org/10.1016/S0010-938X(03)00046-5.

      [21] Bensajjay E, Alehyen S, El Achouri M, Kertit S (2003), Corrosion inhibition of steel by 1phenyl 5mercapto 1,2,3,4tetrazole in acidic environments (0.5 M H2SO4 and 1/3 M H3PO4). Anti-Corros. Meth. Mater, 50, 402-409. https://doi.org/10.1108/00035590310501558.

      [22] Hassan HH (2007), Inhibition of mild steel corrosion in hydrochloric acid solution by triazole derivatives: Part II: time and temperature effects and thermodynamic treatments. Electrochim. Acta, 53, 1722–1730. https://doi.org/10.1016/j.electacta.2007.08.021.

      [23] Durnie W, De Marco R, Jefferson A, Kinsella B (1999), Development of a Structureâ€Activity Relationship for Oil Field Corrosion Inhibitors. J. Electrochem. Soc, 146, 1751-1756. https://doi.org/10.1149/1.1391837.

      [24] Hameed RSA (2011), Aminolysis of polyethylene terephthalate waste as corrosion inhibitor for carbon steel in HCl corrosive medium. Adv. App. Sci. Res. 2, 483-499.

      [25] Singh A, Ahamad I, Yadav DK, Singh VK, Quraishi MA (2012), The effect of environmentally benign fruit extract of shahjan (moringa oleifera) on the corrosion of mild steel in hydrochloric acid solution. Chemical Engineering Communications. 199, 63-77. https://doi.org/10.1080/00986445.2011.570390.

      [26] Attar T, Larabi L, Yahia H (2014), Inhibition effect of potassium iodide on the corrosion of carbon steel (XC 38) in acidic medium. International Journal of Advanced Chemistry, 2, 139-142. https://doi.org/10.14419/ijac.v2i2.3272.

      [27] Dehri I, Ozcan M (2006), The effect of temperature on the corrosion of mild steel in acidic media in the presence of some sulphur-containing organic compounds. Materials Chemistry and Physics, 98,316–323. https://doi.org/10.1016/j.matchemphys.2005.09.020.

      [28] Mohamed SM, Mahmoud AA (2015), Some pyrazole derivatives as corrosion inhibitors for carbon steel in hydrochloric acid solutions. J. eur. chem, 6, 342-349. https://doi.org/10.5155/eurjchem.6.3.342-349.1279.

      [29] Abd El-Rehim SS, Refaey SAM, Taha F, Saleh MB, Ahmed RA (2001), Corrosion inhibition of mild steel in acidic medium using 2-amino thiophenol and 2-cyanomethyl benzothiazole. Journal of Applied Electrochemistry, 31, 429–435. https://doi.org/10.1023/A:1017592322277.

      [30] David E, Talbot J, James D, Talbot R (2010), Corrosion Science and Technology: Materials Science & Technology. CRC Press, 94-95.

  • Downloads

  • How to Cite

    Attar, T., Benchadli, A., & Choukchou-Braham, E. (2019). Corrosion inhibition of carbon steel in perchloric acid by potassium iodide. International Journal of Advanced Chemistry, 7(1), 35-41. https://doi.org/10.14419/ijac.v7i1.19651