Acoustic and volumetric properties of aqueous solution of levofloxacin nickel complexes at 308K

  • Authors

    • Monalisa Das lecturer in Chemistry, Ravenshaw University, Cuttack, odisha, India
    • Smrutiprava Das Head, P.G. dept. of Chemistry, Ravenshaw University, Cuttack
    • Ajaya Patnaik Ravenshaw University, Cuttack
    2014-04-06
    https://doi.org/10.14419/ijac.v2i2.2114

  • Abstract

    The density and ultrasonic velocity were measured for aqueous solutions of nickel complex and its ternary complex with 1,10-phenanthroline at 308 K. Using the experimental data, adiabatic compressibility , acoustic impedance , intermolecular free length and hydration number , apparent molar volume , limiting apparent molar volume , apparent molar compressibility , limiting apparent molar compressibility and their associated constants were calculated. These parameters were used to study the ion-solvent interaction in each solution.

     

    Keywords: Ultrasonic Velocity, Hydration Number, Adiabatic Compressibility, Apparent Molar Volume, Apparent Molar Compressibility.

  • References

    1. Jadav SS, Singh YP & Ragkumar J (1999), J. Ind. Coun. Chem., 16, 20.
    2. Bhatt SC, Semwal H, Lingwal V, Singh K & Semwal BS (2000) Acoustical parameters of some molecular liquids. J. Acous. Soc. India, 28, 293-296.
    3. Verma RP and Kumar S (2000) Ultrasonic velocity and density measurements of ammonium soaps in 2-propanal. Ind. J. pure and appl. Phy., 38, 96-100.
    4. Kalidos M and Ravi S (2002) new method of determining the structure factor of real liquids and their mixtures using ultrasonic velocity. Statistical Mechanics and its Application, 312, 59-69.
    5. Govindrajan S, Kannapan V & Ramesh MD (2003) Ultrasonic studies on the molecular interaction of gallic acid in aqueous methanol and acetone solutions and the role of gallic acid as viscosity reducer. J. Mol. Liq., 107, 289-316.
    6. Patil KJ, Dagade DH (2004) Studies of molecular interactions in aqueous and CCl4 solutions involving 18-crown-6 by application of Kirkwood-Buff theory. J. Chem. Thermodyn., 36, 677-682.
    7. Kamila S, Jena S & Bihari B (2005) Studies on thermo-acoustic parameters in binary liquid mixtures of phosphinic acid ( Cyanex 272) with different diluents at temperature 303.15K: an ultrasonic study. J. Chem. Thermodyn., 37, 820-825.
    8. Awasthi A, Sukla JP & Rastogi M (2004) Ultrasonic and IR study of molecular association process through hydrogen bonding in ternary liquid mixtures. Fluid Phase Equil. 215, 119-127.
    9. Abraham R, Abdulkhadar M, Ashokan CV (2000) Ultrasonic investigation of molecular interaction in binary mixtures of nitriles with methanol/toluene. J. Chem. Thermodyn., 32, 1-16.
    10. Mishra A, Vibhu I, Singh R, Gupta M & Sukla JP (2007) Acoustic, viscometric and optical properties of binary mixtures of tetrahydrofuran with 1-propanol and 2-propanol. Physics and Chemistry of Liquids, 45, 93-104.
    11. Ali A, Nain AK, Chand D & Lal D (2007), Ultrasonic, volumetric and viscometric studies of molecular interactions in binary mixtures of dimethylsulphoxide with polar substituted cyclohexanes at 30°C. Physics and Chemistry of Liquids, 45, 79-91.
    12. . Eqbal M & Verrall RE (1989) apparent molar volume and adiabatic compressibility studies of aqueous solutions of some drug compounds at 250C. Canadian Journal of Chemistry, 67, 727-735.
    13. Jayamadhuri N, Naidu PS & Prasad KR (2012) Ultrasonic Velocity, Density and Viscosity Studies in the Aqueous Solutions of Hydrate Compounds. Research Journal of Pharmaceutical, Biological and Chemical Sciences, 3, 861-875.
    14. Fish DN, Chow AT (1997) the clinical pharmacokinetics of levofloxacin. Clin. Pharma. Cokineto. 32, 101-119.
    15. Mendoza G, Martinez LMR, Alonso RP, Solons X & Esparza RM ( 1987) Synthesis and characterization of mixed ligand complexes of copper with nalidixic acid and (NN) donors, crystal structure of Cu(Phen)(NaI)-(H2O)]NO3.3H2O. Inorganic Chimica Acta., 138, 41-47.
    16. Diez GM & Panner KH (1993), some mixed-ligand complexes of copper (II) with drugs of the quinolone family and (NN) donors. Crystal structure of [Cu (phen) (Cnx)(H2O)]NO3 • H2O. Journal of Inorganic Biochemistry, 50, 65-78.
    17. Wallis SC, Gahan LR, Charles BG, Hambley TW & Duckworth PA (1996) Copper(II) complexes of the fluoroquinolone antimicrobial ciprofloxacin. Synthesis, X-ray structural characterization, and potentiometric study. Journal of Inorganic Biochemistry, 62, 1-16.
    18. Diaz GM, Alonso RP, Esparza RM.( 1996). Stability constants of copper (II) mixed complexes with some 4-quinolone antibiotics and (N-N) donors. Journal of Inorganic Biochemistry, 64, 207-214.
    19. Turel I. (2002) the interaction of metal ions with quinolone antibacterial agents. Coord. Chem Rev, 232, 27-47.
    20. Sakurai M, Nakawaga T.( 1984) Densities of dilute solutions of water in n-alkanols at 278.15, 288.15, 298.15, 308.15, and 318.15 K Partial molar volumes of water in n-alkanols. J. Chem Thermodynamics, 16, 171-174.
    21. Imran M, Kokab T, Latif S, Liviu M, Mohmood.(2010) Characterization and in vitro Antibacterial Studies of Complexes using Quinoline Antibiotics as Primary Ligand. J. Chem Soc. Pak., 32, 223-228.
    22. Harned HS, Owen BB (1958) The Physical chemistry of electrolyte solutions, 3rd Edn.Reinhold, Newyork.p- 358.
    23. Masson DO (1929) Solute molecular volumes in relation to solvation and ionization. Phil. Mag, 8, 218-235.
    24. Dash UN & Supakar S (1929) Acoustic letters, 16, and 135.
    25. Wood AB (1960) A Text Book of sound, 3rd Edn. (G. Bell, London), p. 51 & 577.
    26. Gucker FT (1933) the Apparent Molal Heat Capacity, Volume, and Compressibility of Electrolytes. Chem. Rev., 13, 111-130.
    27. Debye P & Huckel E (1932) the theory of electrolytes. I. Lowering of freezing point and related phenomena. Physik. Z., 24, 185-206.
    28. Passynsky A (1938) Actaphysicochim, 8, 357.
    29. Ramasami P & Kakkar R (2006) Partial molar volumes and adiabatic compressibilities at infinite dilution of aminocarboxylic acids and glycylglycine in water and aqueous solutions oaf sodium sulphate at (288.15, 298.15 and 308.15) K. J. Chem. Thermodyn, 38, 1385-1395.
    30. Bansal KR (1990) a text book of organic chemistry, 2nd ed. (Willey Estern ltd, New Delhi), p-477.
    31. Panday JD, Shukla A, Rai RD & Mishra KJ (1989) Ultrasonic, volumetric and viscometric studies of tetracycline and its allied compound. J. Chem. Eng. Data, 34, 29-31.

  • Downloads

  • How to Cite

    Das, M., Das, S., & Patnaik, A. (2014). Acoustic and volumetric properties of aqueous solution of levofloxacin nickel complexes at 308K. International Journal of Advanced Chemistry, 2(2), 66-69. https://doi.org/10.14419/ijac.v2i2.2114

    Received date: 2014-03-03

    Accepted date: 2014-03-29

    Published date: 2014-04-06