Comparison studies for the removal of a basic dye from aqueous solution using coffee residues and waste tea
Keywords:Adsorption, Methylene Blue, Coffee Residues, Waste Tea, Kinetics.
Dyes are one of the most important industrial pollutants, especially in textile industries. The coffee residues and wastes tea are food industrial solid wastes, were used as low-cost adsorbents for the removal of methylene blue (MB) dye from aqueous solution. Many methods have been proposed in order to remove color from wastewater among which, adsorption is more acceptable due to the ability for its use in the large scale. The influence of various experimental factors such as contact time, adsorbent dosage, temperature and pH of dye solution was investigated. Two simplified kinetic models including pseudo-first-order and pseudo-second-order equation were selected to follow the adsorption processes. It was observed that chemisorptions pseudo-second order kinetic model described the sorption process with high coefficients of determination (R2) better than pseudo-first order kinetic model. Thermodynamic parameters such as Î”GÂ°, Î”HÂ°, and Î”SÂ° were calculated the results of this parameteres indicated that the adsorption of methylene blue onto residues coffee and waste tea were spontaneous process.
 Chatterjee S, Lee DS, Lee MW, Woo SH (2009), Enhanced adsorption of congo red from aqueous solutions by chitosan hydrogel beads impregnated with cetyl trimethyl ammonium bromide. Bioresource Technology100, 2803â€“2809, https://doi.org/10.1016/j.biortech.2008.12.035.
 Kumar PS, Ramalingam S, Sathishkumar K (2011), Removal of methylene blue dye from aqueous solution by activated carbon prepared from cashew nut shell as a new low-cost adsorbent. Korean Journal of Chemical Engineering 28, 149-155, https://doi.org/10.1007/s11814-010-0342-0.
 Hameed BH (2009), Spent tea leaves: a new non-conventional and low-cost adsorbent for removal of basic dye from aqueous solutions. Journal of Hazardous Materials 161, 753-759, https://doi.org/10.1016/j.jhazmat.2008.04.019.
 Kapdan IK, Kargi F (2002), Simultaneous Biodegradation and Adsorption of Textile D Sludge Uni. Process Biochemistry 37, 973-981, https://doi.org/10.1016/S0032-9592(01)00309-0.
 Tocchi C, Federici E, Fidati L, Manzi R, Vincigurerra V, Petruccioli M (2012), Aerobic treatment of dairy wastewater in an industrial three-reactor plant: effect of aeration regime on performances and on protozoan and bacterial communities. Water Research 46, 3334â€“3344, https://doi.org/10.1016/j.watres.2012.03.032.
 Zhang Y, Causserand C, Aimar P, Cravedi JP (2006), Removal of bisphenol A by a nanofiltration membrane in view of drinking water production. Water Research 40, 3793â€“3799, https://doi.org/10.1016/j.watres.2006.09.011.
 Dabrowski A, Hubicki Z, Podkocielny P, Robens E (2004), Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method. Chemosphere 56, 91â€“106, https://doi.org/10.1016/j.chemosphere.2004.03.006.
 Ennigrou DJ, Gzara L, Ben Romdhane MR, Dhahbi M (2009), Cadmium removal from aqueous solutions by polyelectrolyte enhanced ultrafiltration. Desalination 246, 363â€“369, https://doi.org/10.1016/j.desal.2008.04.053.
 Kristianto H, Rahman H, Prasetyo S, Sugih AK (2019), Removal of Congo red aqueous solution using Leucaena leucocephala seedâ€™s extract as natural coagulant. Applied Water Science 9, 88-95, https://doi.org/10.1007/s13201-019-0972-2.
 Hu A, Li M, Chang C, Mao D (2007), Preparation and characterization of a titanium-substituted hydroxyapatite photocatalyst. Journal of Molecular Catalysis A: Chemical 267, 79-85, https://doi.org/10.1016/j.molcata.2006.11.038.
 Ku Y, Jung I-L (2001), Photocatalytic reduction of Cr (VI) in aqueous solutions by UV irradiation with the presence of titanium dioxide, Water Research 35(2001)135- 142, https://doi.org/10.1016/S0043-1354(00)00098-1.
 Panizza M, Barbucci A, Ricotti R, Cerisola G (2007), Electrochemical Degradation of Methylene Blue. Separation and Purification Technology 54, 382-387, https://doi.org/10.1016/j.seppur.2006.10.010.
 Cui L, Wang Y, Hu L, Gao L, Du B, Wei Q (2015), Mechanism of Pb (II) and methylene blue adsorption onto magnetic carbonate hydroxyapatite/graphene oxide. RSC Advances 5, 9759-9770, https://doi.org/10.1039/C4RA13009J.
 Yagub MT, Sen TKS, Afroze S, Ang HM (2014), Dye and its removal from aqueous solution by adsorption: a review, Adv. Colloid Interface Science 209, 172â€“184, https://doi.org/10.1016/j.cis.2014.04.002.
 Akpomie KG, Dawodu FA, Adebowale KO (2015), Mechanism on the sorption of heavy metals from binary solution by a low-cost montmorillonite and its desorption potential. Alexandria Engineering Journal 54, 757â€“767, https://doi.org/10.1016/j.aej.2015.03.025.
 Mohammad M, Maitra S, Ahmad N, Bustam A, Sen T, Dutta BK (2010), Metal ion removal from aqueous solution using physic seed hull. Journal of Hazardous Materials 179, 363â€“372, https://doi.org/10.1016/j.jhazmat.2010.03.014.
 Sun YB, Chen CL, Shao DD et al (2012), Enhanced adsorption of ionizable aromatic compounds on humic acid-coated carbonaceous adsorbents. RSC Advances. 2, 10359â€“10364, https://doi.org/10.1039/c2ra21713a.
 Sintayehu YD, Lencha LT (2016), Adsorption and Kinetic Optimization Study of Acetic Acid from Aqueous Solutions Using Activated Carbon Developed from Vernonia amygdalina Wood. American Journal of Physical Chemistry 5, 128-132, https://doi.org/10.11648/j.ajpc.20160506.14.
 Sen TK, Afroze S, Ang HM (2011), Equilibrium Kinetics and Mechanism of Removal of Methylene Blue from Aqueous Solution by Adsorption onto Pinecone Biomass of Pinus Radiate. Water, Air, & Soil Pollution 218, 499-515, https://doi.org/10.1007/s11270-010-0663-y.
 Zaker Y, Hossain MA (2013), Effect of Various Factors on the Adsorption of Methylene Blue on Silt Fractionated from Bijoypur Soil, Bangladesh, International Research Journal of Environment Sciences 2, 1-7.
 Zhang B, Li F, Wu T, Sun D, Li Y, (2015), Adsorption of p-nitrophenol from aqueous solutions using nanographite oxide. Colloids and Surfaces A: Physicochemical and Engineering Aspects 464, 78â€“88, https://doi.org/10.1016/j.colsurfa.2014.10.020.
 Demirbas E, Kobya M, Senturk E, Ozkan T (2004), Adsorption kinetics for the removal of chromium (VI) from aqueous solutions on the activated carbons prepared from agricultural wastes. Water SA 30, 533-540, https://doi.org/10.4314/wsa.v30i4.5106.
 Ho YS, McKay G (1998), A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents, Process Safety and Environmental Protection 76, 332-340, https://doi.org/10.1205/095758298529696.
 Andrew L, Hsieh KY (2015), Copper-based metal organic framework (MOF), HKUST-1, as an efficient adsorbent to remove p-nitrophenol from water. Journal of the Taiwan Institute of Chemical Engineers 50, 223â€“228, https://doi.org/10.1016/j.jtice.2014.12.008.
 Langmuir I (1916), the constitution and fundamental properties of solids and liquids. Journal of the American Chemical Society 38 (1916)2221-2295, https://doi.org/10.1021/ja02268a002.
 Hall KR, Eagleton LC, Acrivos A, Vermeulen T (1966), Pore-and solid-diffusion kinetics in fixed-bed adsorption under constant-pattern conditions. Industrial engineering chemistry and fundamentals 5, 212â€“223, https://doi.org/10.1021/i160018a011.
 Foo KY (2012), Preparation, characterization and evaluation of adsorptive properties of orange peel based activated carbon via microwave induced K2CO3 activation. Bioresource Technology 104, 679-686, https://doi.org/10.1016/j.biortech.2011.10.005.
 Malik PK, (2003),Use of activated carbons prepared from sawdust and rice-husk for sorption of acid dyes: a case study of acid yellow 36, Dyes and pigments 56, 239-249, https://doi.org/10.1016/S0143-7208(02)00159-6.Nasuha N, Hameed BH (2011), Adsorption of methylene blue from aqueous solution onto NaOH-modified rejected tea. Chemical Engineering Journal 166, 783â€“786, https://doi.org/10.1016/j.cej.2010.11.012