Ultrasonic velocities and refractive indies of binary liquid mixtures of 1, 4-dioxane with 1 – alkanols (C3, C4, C6 , C8 ) at 303.15 K

  • Authors

    • Seema Agarwa Department Of Chemistry,Institute Of Basic Science,Bundelkhand University,Jhansi(U.P.)India
    • Dhirendra Kumar Sharma
    2022-01-02
    https://doi.org/10.14419/ijac.v9i2.31715
  • Refractive Indices, Density, Ultrasonic Velocity, Molar Volume, Mass Refraction, 1- Alkanol, Molecular Interaction.
  • Density (Ï), ultrasonic velocities (u) and refractive indices (n) of the binary mixture between cyclic ether with 1-propanol, 1-butanol, 1-hexanol, 1-octanol for the entire concentration range have been measured at 303.15K, furthermore, deviation in refractive indies from ideal mixture, molar refraction, deviation in molar refraction from ideal values for these mixture has also been evaluated. The deviations from ideality of the acoustical parameters are explained on the basis of molecular interaction between the component molecules in these binary liquid mixtures. The molecular refraction (Rm), excess molecular refraction ( ) and excess molar volume (VE) were calculated from the experimental data. The results are discussed in term of molecular interactions between the components of the binary mixtures.

     

     

     

  • References

    1. [1] Aminabhavi,T M, Banerjee K,, Bahundgi R.H. “ Thermodynamic interaction in binary mixtures of 1-chloronaphthalene and Monocyclic Aromatics†Indian Journal Of Chemistry, 1999,38A, 768.

      [2] Pal A, Kumar A, “Excess Molar volumes, Viscosities and Refractive Indices of Diethylene Glycol Di methyl ether with Dimethyl carbonate, Diethyl Carbonate and Propylene Carbonate at (298.15K,308.15K and 318.15K)†Journal Of Chemical & Engineering Data, 1998,Vol.43 No.2, pp 143-147. https://doi.org/10.1021/je9701902.

      [3] Al-Dujali,A H, Yaseen A A , Awwal A M , “Refractive indices, Densities and Excess Properties of 4-(2-Hydroxyethyl) morpholine + Water at (298.15, 308.15 and 318.15)K†Journal Of Chemical & Engineering Data, 2000, Vol. No. 45, pp 647-649. https://doi.org/10.1021/je0000322.

      [4] Nain A K , Chandra P, Pandey J D Gopal S , “ Densities, Refractive indices and Excess properties of binary mixtures of 1,4-Dioxane with Benzene, Toluene, O-Xylene, m-Xylene, p-Xylene and Mesitylene at Temperature from (288.15 to 318.15) K†Journal Of Chemical & Engineering Data, 2008, Vol. no. 53(10), pp 2654-2665. https://doi.org/10.1021/je800579j.

      [5] Nain A K “Molecular interaction in binary mixtures of Formamide with 1-Butanol, 2-Butanol, 1,3-Butanediol and 1,4-Butanediol at different temperature: As Ultrasonic and Viscometric Study, “ Fluid Phase Equilibria, 2008, Vol. no. 46, pp 56. https://doi.org/10.1016/j.fluid.2007.12.007.

      [6] Aralaguppi M I Jardar, Aminabhavi,T M, “ Density, Refractive indices, Viscosity and speed of sound in binary mixtures of Cyclohexanone with Benzene, Methylbenzene, 1,4-Dimethylbenzene, 1,3,5-Trimethylbenzene,and Methoxybenzene in the temperature Interval (298.15 to 308.15) K.†Journal Of Chemical & Engineering Data, 1999, Vol. no. 44(3) , pp 446-450. https://doi.org/10.1021/je980219h.

      [7] Pandey J D., Vyas V., Dubey G.P., Tripathi N., Dey R.,†Speed of sound, Viscosity and Refracive Indices Of multicomponent systems: Theoretical Prediction from the properties of Pure Componentsâ€, Journal of Molecular Liquids,1999, 81, 123-133. https://doi.org/10.1016/S0167-7322(99)00061-6.

      [8] Ansari N H., Tiwari A., Sharma D K., Chandra P.,†Refractometric Studies on Molecular Interaction In six binary liquid mixtures†Open J. of Phy. Chem., 2014, 4. https://doi.org/10.4236/ojpc.2014.41001.

      [9] Edas C D., J Phys. Chem. B, 2000,104, 6653. https://doi.org/10.1021/jp993472c.

      [10] Parker A. J., Chem. Rev., 1969, 16,163. https://doi.org/10.1080/03648664.1969.9926304.

      [11] Crwn Zellerbach Crop., Dimethylsulphoxide as a reaction solvent (Camas, Washington (1998).

      [12] Pal A., Kumar A., Journal of Chemical & Engineering Data, 1998 43, 2. https://doi.org/10.1021/je980016t.

      [13] Fucaloro A.F., J. Chem. Edu. 2002, 79, 7, 865. https://doi.org/10.1021/ed079p865.

      [14] Vogel A.I., 5th Ed. Longmans Green, London 1989.

      [15] Roy M N., Sinha A., Sinha B., J. of Solution Chemistry 2005, 34, 11. https://doi.org/10.1007/s10953-005-8022-0.

      [16] Aralaguppi M I., Jadar C V., Aminabhavi T M., J. Chem.eng.data. 1999, 44. https://doi.org/10.1021/je980218p.

      [17] Baragi G.J., Aralaguppi I M., Aminabhavi M T., J. Chem. Eng. Data, 2005, 50.

      [18] Al-Kandary A.J., Al-Jimaz A.S. Abdul-Latif A.M., Physics and Chemistry of Liquid, 2009, 47, 2.

      [19] RodrignezA., J. Canosa and J. Tojo, J. Chem. Eng. Data, 2001,46. https://doi.org/10.1021/je0101193.

      [20] Dubey G. P., Sharma M., J. ThermoPhys. 2008, 29. https://doi.org/10.1007/s10765-008-0435-8.

      [21] Elangovan S., Mullainathan S., Indian J. of Physics, 2013, 87, 7. https://doi.org/10.1007/s12648-013-0288-2.

      [22] Koneti A K., Chintalapati S., J. Advanced in Chemistry, Hindawi Publishing Corporation, 2014.

      [23] Stokes R.H., Pergamon Press, Oxford 1965.

      [24] Sjoblom J., Dyhr H., Hansen O., Finn. Chem. Lett. 1981,110.

      [25] Oswal S.L., Prajapati K.D., Ghael N.Y., Ijardar S P.,Fluid Phase Equilib. 2004, 218, 131. https://doi.org/10.1016/j.fluid.2003.11.012.

      [26] Ali A., Hyder S., Nain A K., Acoustics Lett. 1997, 21, 77; 2000, 23, 183.

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    Agarwa, S., & Kumar Sharma, D. (2022). Ultrasonic velocities and refractive indies of binary liquid mixtures of 1, 4-dioxane with 1 – alkanols (C3, C4, C6 , C8 ) at 303.15 K. International Journal of Advanced Chemistry, 9(2), 201-204. https://doi.org/10.14419/ijac.v9i2.31715