Spectrophotometric determination of the stability constant of vanadium(v)-p-chloro-N-phenyl-p-chlorobenzo- hydroxamic acid complex
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2014-09-16 https://doi.org/10.14419/ijac.v2i2.3213 -
Abstract
The stability constant of the complex vanadium(v) p-chloro-N-Phenyl-p-chlorobenzohydroxamic acid was determined spectropho-tometrically. The ligand p-chloro-N-phenyl-p-chloro-benzohydroxamic acid abbreviated in this paper as PCNPPCBHA was synthesized by the coupling of equimolar solutions of p-chlorobenzoyl chloride and freshly prepared p-chloro-ß-phenyl hydroxylamine; in which the later was prepared by the reduction of p-chloronitrobenzene with zinc powder.
The pH at maximum extraction of the ligand PCNPPCBHA to the metal vanadium(v) and the ratio of the ligand: metal , were determined.
Keywords : Spectrophotometric determination , Vanadium(V) , p - chloro - N - phenyl - p - chloro-benzohydroxamic acid.
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References
- Abdalla, H.A/aziz. (1980), Ph.D thesis, University of Sal-ford, England.
- Abdalla, H.H. (1992), M.SC. Thesis, Faculty. Of Science, University of Khartoum. Sudan.
- Agrawal, Y. K. (1967), J.Chem. And Eng.data, 22, 175.
- Bowie, H. J; Hearn .W .M, and Ward, D.A. (1969), Aust. J.Chem., 22, 175.
- Harvey, A. E, and Manning, D. L (1952). J.Am.Chem.Soc., Vol. 74, 4744. http://dx.doi.org/10.1021/ja01139a005.
- Job (1928), Ann. Chem. Paris, 9, 113.
- Korthoff, I. M. (1963), J.Am.Chem.Soc., 25, 315.
- Mamion.C.J, Griffith.D and Nolan. K.B Eur.J.Inorg.Chem. 2004, 3003.
- Matzanke B.F., Mueller G. and Raymond K.N. (1989) "Siderophore medicated Iron Transport; Chemistry, Biology and Physical Properties in Physical Bioinorganic Chemistry " VCH Publishers NewYork.
- Miller M.J. (1989) Chem.Rev.89, 1536.
- Musser. J.H, Kreft A.F., Bender R.H.W. (1990) J.Med.Chem.33, 240. http://dx.doi.org/10.1021/jm00163a039.
- Odake- Sh., Okayama T. and Obata M. (1991) Chem.Pham.Bull .39, 1489.
- Openshow, H. T., (1995) " A laboratory Manual of Qualitative Organic Analysis''Cambridge University Press, 3rd ed.
- Rappoport .Z and Liebman.J.F(2009) "The chemistry of hy-droxyla mines, oximes and hydroxamic acids " John Wiley and sons ltd,, part 1,187.
- Rasuljan M., Jan N. and Khwaja M.A. (1996) J.Chem.Soc.Pak. 18(2), 101.
- Ryan, D. E. (1960) Analyst, Vol. 785, P 569. http://dx.doi.org/10.1039/an9608500569
- Tandon. S. G, and Bhattacharya, S, (1962), J.Chem. And Eng.data, 7, 553. http://dx.doi.org/10.1021/je60015a036.
- Usha, P. Tandon. S.G (1967), J. of Chem. and Eng.data, 12, (1), 143. http://dx.doi.org/10.1021/je60032a046.
- Vogel, A.I., (1951), "A text book of practical organic chemistry ", Longmans,London 2nd. Ed.
- Warren, C. Vosburgh and Gerald R. Cooper (1941), J. of Am.Chem. Soc., 63, 437. http://dx.doi.org/10.1021/ja01847a025.
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How to Cite
Abualreish, M., & Al msiedeen, A. (2014). Spectrophotometric determination of the stability constant of vanadium(v)-p-chloro-N-phenyl-p-chlorobenzo- hydroxamic acid complex. International Journal of Advanced Chemistry, 2(2), 162-165. https://doi.org/10.14419/ijac.v2i2.3213Received date: 2014-07-21
Accepted date: 2014-08-20
Published date: 2014-09-16