AC conductivity and dielectric behavior of poly (o-phenylenediamine)/TiO2 nanocomposites
-
2017-04-11 
https://doi.org/10.14419/ijac.v5i1.7437
-
Polyphenylenediamine, Nanocomposites, Dielectric Property, Ac Conductivity. -
Abstract
Poly (o-phenylenediamine) and their nanocomposites with TiO2 nanoparticles were synthesized using oxidative polymerization technique and the polymer nanocomposites were characterized using spectral techniques like FT-IR, UV-VIS spectroscopy and the morphology have been analyzed by XRD, SEM and TEM. The stability of the prepared polymer nanocomposites was studied using TGA, DTA and found to have high thermal stability. The study of ac conductivity, dielectric property revealed that the formed nanocomposites are semiconducting in nature and can be widely used in the field of energy storage and semiconductor devices, in diodes, batteries etc.
-
References
[1] Mohaseen, S., Tamboli, Milind, V., Kulkarni, Rajendra, H., Patil, Wasudev, N. Gade., Shalaka, C. Navale., Bharat B. Kale, 2012. Colloids and Surfaces B: Biointerfaces, 92, 35– 41. https://doi.org/10.1016/j.colsurfb.2011.11.006.
[2] Pandi Boomi, Halliah Gurumallesh Prabu, Paramasivam Manisamkar and Sundaram Ravikumar, 2014. Applied Surface Science, 300, 66–72. https://doi.org/10.1016/j.apsusc.2014.02.003.
[3] Pandi Boomia, Halliah Gurumallesh Prabua, Jayaraman Mathiyarasu, 2013. Colloids and Surfaces B: Biointerfaces, 103, 9– 14. https://doi.org/10.1016/j.colsurfb.2012.10.044.
[4] Pandi Boomi, Halliah Gurumallesh Prabu, Jayaraman Mathiyarasu, 2014. European Journal of Medicinal Chemistry, 72, 18-25. https://doi.org/10.1016/j.ejmech.2013.09.049.
[5] Pandi Boomi, Halliah Gurumallesh Prabu, 2013. Colloids and Surfaces A: Physicochemical Engineering Aspects, 429, 51- 59. https://doi.org/10.1016/j.colsurfa.2013.03.053.
[6] Mansour Ghaffari-Moghaddam, Hassan Eslahi, 2014. Arabian Journal of Chemistry, 7 (5) 846-855. https://doi.org/10.1016/j.arabjc.2013.11.011.
[7] Yong Kong, Wei Li, Zhiliang Wang, Chao Yao, Yongxin Tao, 2013. Electrochemistry Communications, 26, 59-62. https://doi.org/10.1016/j.elecom.2012.10.016.
[8] Mahasweta Nandi, Swapan Kumar Das, Saurav Giri, Asim Bhaumik, 2011. Microporous and Mesoporous Materials, 142, 557-563. https://doi.org/10.1016/j.micromeso.2010.12.048.
[9] Mei-Rong Huang, Xin-Gui Li, Yuliang Yang, 2001. Polymer Degradation and Stability, 71, 31-38. https://doi.org/10.1016/S0141-3910(00)00137-3.
[10] Garjonyte, R., Malinauskas, A., 1999. Sensors and Actuators B, 56, 85-92. https://doi.org/10.1016/S0925-4005(99)00163-X.
[11] Zhang, Y., Li, H., Luo, Y., Shi, X., Tian, J., 2011. Plos one, 6, 1-11. https://doi.org/10.1371/annotation/4056d03c-20ed-4eca-9568-3e9400e2312e.
[12] Anderson, MR., Mattes, BR., Reiss, H., Kaner, RB, 1991. Science, 252, 1412-5. https://doi.org/10.1126/science.252.5011.1412.
[13] Myler, S., Eaton, S., Higson, SP., 1997. Analytica Chimica Acta, 357, 55-61. https://doi.org/10.1016/S0003-2670(97)00558-8.
[14] Liu, Z., Zu, Y., Guo, S., Fu, Y., Zhang, Y., Liang, H., 2008. Material Science Engineering C, 28, 1284-8. https://doi.org/10.1016/j.msec.2007.12.002.
[15] Cao, Y., Smith, P., 1993. Polymer, 34, 3139-43. https://doi.org/10.1016/0032-3861(93)90381-J.
[16] Cataldo, F., 1996. European Polymer Journal, 32, 43-50. https://doi.org/10.1016/0014-3057(95)00118-2.
[17] Premasiri, AH. Euler, WB. 1995. Macromolecular Chemistry and Physics, 196, 3655-66. https://doi.org/10.1002/macp.1995.021961118.
[18] Chan, HSO, Ng, SC., Hor, TSA. Sun, J., Tan, KL. Tan, BTG. 1991. European Polymer Journal, 27, 1303-8. https://doi.org/10.1016/0014-3057(91)90069-Z.
[19] Li, X-G., Huang, M-R., Chen, R-F., Jin, Y., Yang, Y-L., 2001. Journal of Applied Polymer Science, 81, 3107-31016. https://doi.org/10.1002/app.1762.
[20] Sestrem, RH. Ferreir, DC. Landers, R., Temperini, MLA. Do Nascimento, GM., 2009. Polymer, 50, 6043-8. https://doi.org/10.1016/j.polymer.2009.10.028.
[21] Sestrem, RH. Ferreir, DC. Landers, R., Temperini, MLA. Do Nascimento, GM., 2010. European Polymer Journal, 46, 484-93. https://doi.org/10.1016/j.eurpolymj.2009.12.007.
[22] Huang, M-R., Li, X-G., Yang, Y., 2001. Polymer Degradation and Stability, 71, 31-8. https://doi.org/10.1016/S0141-3910(00)00137-3.
[23] Aashish Roy, Ameena Parveen, Raghunandan Deshpande, Ravishankar Bhat, Anilkumar Koppalkar, 2013. Journal of Nanopartical Research, 15:1337 https://doi.org/10.1007/s11051-012-1337-z.
[24] Mona H. Abdel Rehim, Nahla Ismail, Abd El-Rahman A.A. Badawy, Gamal Turky, 2011. Materials Chemistry and Physics, 128, 507-513. https://doi.org/10.1016/j.matchemphys.2011.03.037.
[25] Meirong Wang, Huaihao Zhang, Chengyin Wang, Guoxiu Wang, 2013. Electrochimica Acta, 106, 301-306. https://doi.org/10.1016/j.electacta.2013.05.097.
[26] Pandi Muthirulan, Chenthamarai Kannan Nirmala Devi, Mariappan Meenakshi Sundaram, 2013. Journal of Environmental Chemical Engineering, 1, 620-627. https://doi.org/10.1016/j.jece.2013.06.025.
[27] Ukrainczyk, L., Bellman, RA., Anderson, AB., 1997. Journal of Physics and Chemistry B, 101(4), 531-539. https://doi.org/10.1021/jp962937l.
[28] Ke, SM., Huang. HT. Ren, L., Wang, YJ, 2009. Journal of Applied Physics, 105 (9) 1–3. https://doi.org/10.1063/1.3125271.
[29] Li Yu, Yihe Zhang, Wangshu Tong, Jiwu Shang, Fengzhu Lv, Paul K. Chu, Wenmin Guo, 2012. Composites: Part A, 43, 2039-2045. https://doi.org/10.1016/j.compositesa.2012.06.001.
[30] Lee, HT. Liao, CS., Chen, SA. 1993. Makromol Chem, 194, 2443. https://doi.org/10.1002/macp.1993.021940903.
[31] Muhammad AKRAM, Athar JAVED, Tasneem Zahra RIZVI, 2005. Turkish Journal of Physics, 29, 355-362.
[32] Bluma G. Soares, Maria Elena Leyva, Guilherme M.O. Barra, Dipak Khastgir, 2006. European Polymer Journal, 42, 676-686. https://doi.org/10.1016/j.eurpolymj.2005.08.013.
[33] Roy M., Nelson J.K., MacCrone R.K., Schadler L.S., 2005. Polymer Nanocomposite Dielectrics -The Role of the Interface.
-
Downloads
-
How to Cite
S., A. (2017). AC conductivity and dielectric behavior of poly (o-phenylenediamine)/TiO2 nanocomposites. International Journal of Advanced Chemistry, 5(1), 29-34. https://doi.org/10.14419/ijac.v5i1.7437Received date: 2017-03-02
Accepted date: 2017-04-06
Published date: 2017-04-11