Di- and tetranuclear gadolinium (III) complexes of 2-hydroxypropane-1,2,3-tricarboxylic acid and 1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid : identification and characterization
Keywords:Citric and Camphoric Acid, Coloress Complexes, Indirect Photometry Detection, Gadolinium Complexes, Stability of Contrast Agents.
Our studying involved, Identification and characterization of two novel gadolinium complexes with 2-hydroxypropane-1,2,3-tricarboxylic acid (citric acid) noted H3L and 1,2,2-trimethylcyclopentane-1, 3-dicarboxylic acid (camphoric acid) noted H2L in aqueous solution and in pH range 5,5â€“7,5. These acids containing the donor atoms (oxygen of OH and COOH), the formatted complexes are colorless and have no absorption band UVâ€“visible. So, to determine the composition and stabilities of these complexes in solution, we have used an analytical technique called Â«Indirect Photometry Detection (IPD) Â» have identified multi-nuclear and multi-dentate complexes studied in this work. Giving for these colorless complexes with a mole ratio (M:L): (4:2) for Gd (III)â€“Citric acid and (2:2) Gd (III)â€“Camphoric acid. In addition, we have shown that the compositions and stabilities constant of these complexes are depended on the acidity of the medium.
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