Concentration of some heavy metals in Egyptian human hair

 
 
 
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  • Abstract


    In this work, Flame Atomic Absorption Spectrometry (FAAS) was applied for the determination of Cu, Fe, Mg, Mn, Ni, and Zn in twenty four hair samples. The samples were collected covering different ages and gender. The samples are divided as, seventeen samples from people which assumed to be environmentally healthy (control) and seven samples from different workers people such as Iron worker, Cement worker and Duco worker (exposed). Samples were brought into solution using HNO3 and H2O2. In three example samples the molecular structure of the human hair was studied using Fourier Transformer Infrared Spectrometer (FTIR) in the range of 200- 4000 cm -1.The contamination of the sample was discussed for different samples.

    Keywords: Human Hair, Heavy Metals, FAAS, FTIR.


  • References


    1. I.Hassan, G.Tasneem, B. Dermot, and N.Sumsun, Interaction between zinc, cadmium, and lead in scalp hair samples of Pakistani and Irish smokers rheumatoid arthritis subjects in relation to controls, Biomedical and Life Sciences, vol.148, number 2 (2012), 139-147.
    2. A.Duran, M.Tuzen, M.Soylak, Trace element concentrations of some pet foods commercially available in Turkey Food Chem. Toxicol. 48, (2010), 2833. http://dx.doi.org/10.1016/j.fct.2010.07.014.
    3. F.Kabadayi, H.Cesur, Determination of Cu, Pb, Zn, Ni, Co, Cd, and Mn in road dusts of Samsun City Environ. Monit. Assess. 168, (2010), 241. http://dx.doi.org/10.1007/s10661-009-1108-1.
    4. I.Koyuncu, N .Akcin, G.Akcin, K.Mutlu, Comparative Study of Ion-exchange and Flotation Processes for the Removal of Cu2+ and Pb2+ Ions from Natural Waters,Rev. Anal. Chem. 29,(2010), 93. http://dx.doi.org/10.1515/REVAC.2010.29.2.93.
    5. M.Tuzen, M Melek, M.Soylak, J. Hazard. Mater. Coprecipitation of Ni2+, Cd2+ and Pb2+ for preconcentration in environmental samples prior to flame atomic absorption spectrometric determinations 159,(2008), 335. http://dx.doi.org/10.1016/j.jhazmat.2008.02.021.
    6. G. A.Kandhro, T. G.Kazi,. J. A Baig, H. I.Afridi, A. Q.Shah, H. R.Sheikh, N. F.Kolachi, S. K.Wadhwa, Zinc and Iron Determination in Serum and Urine Samples of Thyroid Patients Using Cloud Point Extraction J. AOAC Int. 93,(2010), 1589.
    7. J.Abulhassani, J. L.Manzoori, M.Amjadi, Hollow fiber based-liquid phase microextraction using ionic liquid solvent for preconcentration of lead and nickel from environmental and biological samples prior to determination by electrothermal atomic absorption spectrometry, J. Hazard. Mater. 176,(2010), 481. http://dx.doi.org/10.1016/j.jhazmat.2009.11.054.
    8. Q.He, Z.Hu, Y.Jiang, X.Chang, Z.Tu, L.Zhang, Preconcentration of Cu(II), Fe(III) and Pb(II) with
    9. ((2-aminoethylamino)methyl)phenol-functionalized activated carbon followed by ICP-OES determination.J. Hazard. Mater. 175, (2010), 710. http://dx.doi.org/10.1016/j.jhazmat.2009.10.067.
    10. V. A.Lemos, L. N. Santos, M. A.; M. A. Bezerra, Determination of cobalt and manganese in food seasonings by flame atomic absorption spectrometry after preconcentration with 2-hydroxyacetophenone-functionalized polyurethane foamJ. Food Compos. Anal. 23, (2010), 277. http://dx.doi.org/10.1016/j.jfca.2009.11.004. L.Zhang, X.Chang, Z.Li, Q.He, Selective solid-phase extraction using oxidized activated carbon modified with triethylenetetramine for preconcentration of metal ions, J. Mol. Struct. 964, (2010), 58 http://dx.doi.org/10.1016/j.molstruc.2009.11.009.
    11. J.Dombov and L. papp, Comparison of Sample Preparation Methods for Elemental Analysis of Human Hair ,Microchemical, 59, (1998), 187-193. http://dx.doi.org/10.1006/mchj.1998.1573.
    12. K. S. Rao, T. Balaji, T.P.Rao,Y.Babu and G.R.K.Naidu , Determination of iron, cobalt, nickel, manganese, zinc, copper, cadmium and lead in human hair by inductively coupled plasma-atomic emission spectrometry, Spectrochimica Acta Part B, 57, (2002), 1333-1338. http://dx.doi.org/10.1016/S0584-8547 (02)00045-9.
    13. J. Md Khudzari, H. Wagiran, Md. I. Hossain, N. Ibrahim and M. A. Agam, Heavy metals Mn, Fe, Ni, Cu and Zn in human hair samples using energy dispersive X-ray fluorescence analysis, International Journal of the Physical Sciences, Vol. 6(8),( 2011), pp. 2090-2094.
    14. A.Aluigi, M.Zoccola, C.Vineis, C.Tonin, F Ferrero and M. Cantti, Study on the structure and properties of wool keratin regenerated from formic acid, international Journal of Biological Macromolecules, 41,(2007), 266-273.
    15. E.Wojciechowska,A.W?ochowicz and A.W.Birczy?ska, Application of Fourier-transform infrared and Raman spectroscopy to study degradation of the wool fiber keratin, Journal of Molecular Structure, 511-512, (1999), 307-318.
    16. W.W.Harrison and A. B.Tyree, The determination of trace elements in human fingernails by atomic absorption spectroscopy, ClinChima Acta, 31,(1971),63-73. http://dx.doi.org/10.1016/0009-8981 (71)90362-7.
    17. M.N.Rashed and F. hossam, Heavy Metals in Fingernails and Scalp Hair of Children, Adults and Workers from Environmentally Exposed Areas at Aswan, Egypt ,Environmental Bioindicators Journal, 2,( 2007), 131 145. http://dx.doi.org/10.1080/15555270701553972.

 

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Article ID: 3375
 
DOI: 10.14419/ijbas.v3i4.3375




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