Preparation and microstructure of cobalt(III) poly (acrylate) hybrid materials
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2015-06-09 https://doi.org/10.14419/ijbas.v4i3.4172
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Polyelectrolyte Compounds, Hybrid Materials, Polyacrylic Acid, Cobalt Compounds, Nanocomposites. -
Abstract
The chemical reactions between poly (acrylic acid) and cobalt (III) oxide and between poly (acrylic acid) and cobalt (III) fluoride were studied by Fourier Transform Infrared Spectroscopy. The results demonstrate the formation of cements between the metal and PAA aqueous solutions. Structural information was obtained from the observed frequency shifts of the absorption bands of the carboxylates groups in the cobalt (III) poly (acrylate) relative to those recorded for the purely ionic form. The results show that the bidentate bridging structure is the most likely to occur in both cases. Also, from the analysis of the corresponding coordination chemistry, an octahedral structure may be tentatively assigned to the cobalt (III) poly (acrylate).
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References
[1] A.D. Wilson, S. Crisp; "Organolithic Macromolecular Materials", Chapter 5, Applied Science Publishers, London, 1977.
[2] A. Padilla, J.L. Martinez, A. Sanchez, V.M. Casta-o; Mater. Lett, 12, 445 (1992) http://dx.doi.org/10.1016/0167-577X(92)90211-2.
[3] A. Wilson, J. Nicholson, "Acid-Base Cements", Cap. 5, Cambridge University Press, Cambridge U.K., 1993. http://dx.doi.org/10.1017/cbo9780511524813.
[4] B. Moody, "Comparative Inorganic Chemistry", 403-444, E. Arnold Division of Holder & Stoughton, Londres, 1991.
[5] C. Alvarez-Gayosso, J. Palacios-Alquisira, V. Casta-o; Intern. J. Polymeric Mater., in press.
[6] D.A. Buckingham, "Structure and Stereochemistry of Coordination Compounds", Inorganic Biochemistry, Cap. 1, Vol. I, G.L. Eichhorn Editor, Elsevier Scientific Publishing Company, Amsterdam, 1973.
[7] F. Hoffmann, M. Cornelius, J. Morell, M. Froda, Angewandte Chemie 45, 3216 (2006). http://dx.doi.org/10.1002/anie.200503075.
[8] F. Oosawa, "Polyelectrolytes", Marcel Dekker, New York, 1971.
[9] G.B. Deacon, R.J. Phillips, Coordination Chemistry Reviews, 33, 227 (1980) http://dx.doi.org/10.1016/S0010-8545(00)80455-5.
[10] G. Hernández, F. Rojas, M. GarcÃa, M. Canseco,V.M. Casta-o, Mater. Sci. & Eng. A 355, 338 (2003) http://dx.doi.org/10.1016/S0921-5093(03)00101-1.
[11] H. Hu, J. Saniger, J. GarcÃa-Alejandre, V. M. Casta-o, Mater. Lett. 12, 281 (1991) http://dx.doi.org/10.1016/0167-577X(91)90014-W.
[12] H. Hu, J. Saniger, V.M. Casta-o, Mater. Lett. 14, 83 (1992). http://dx.doi.org/10.1016/0167-577X(92)90179-N.
[13] H. Hu, J. Saniger, V.M. Casta-o, Mater. Lett. 16, 200 (1993). http://dx.doi.org/10.1016/0167-577X(93)90163-R.
[14] J. D. Lee, "Concise Inorganic Chemistry", Chapman & Hall, 783-799, New York, 1991.
[15] J. M. Saniger, H. Hu, V. M. Casta-o, J. GarcÃa-Alejandre, Characterization Techniques for the Solid Solution Interface, 169-176.
[16] J. Saniger, H. Hu, V. M. Casta-o, Mater. Lett. 15, 113 (1992) http://dx.doi.org/10.1016/0167-577X(92)90024-E.
[17] J. Sun, S. Dong, E. Wang, J. Amer. Chem. Soc. 127, 13102 (2005) http://dx.doi.org/10.1021/ja0534809.
[18] J. Varela, V. RodrÃguez, E. Rubio y V.M. Casta-o, J. New Mater. For Electrochem. Syst. 14, 59 (2011)
[19] J.W. Nicholson, S.J. Hawkins, E.A. Wasson; J. Mat. Sci., 4, 32 (1993)
[20] K: Nakamoto, "IR and RS of Inorganic and Coordination Compounds", Cap. 4, John Wiley & Sons, New York, 1986.
[21] L. J. Bellamy "The Infra-red Spectra of Complex Molecules",Methuen, London, 1954.
[22] M.A. Moharram, N. Abdel-Hakeem, H. Shaheen, R.M. Ibrahim, J. Mater. Sci., 21, 1986, 1681-1698. http://dx.doi.org/10.1007/BF01114725.
[23] M. Nicho, J. Saniger, M. Ponce, A. Huanosta, V. Casta-o, J. Appl. Polym. Sci., 66:861 (1977). http://dx.doi.org/10.1002/(SICI)1097-4628(19971031)66:5<861::AID-APP6>3.0.CO;2-T.
[24] N.T. Woodberry; Tappi, 44, 1961, 156A-160A.
[25] R.G. Hill, S.A. Labok; J. Mat. Sci., 26, 67 (1991) http://dx.doi.org/10.1007/BF00576034.
[26] R. Nyquist, R.O. Kagel, "Infrared Spectra of Inorganic Compounds", Academic Press, New York, 1971. http://dx.doi.org/10.1016/b978-0-12-523450-4.50005-5.
[27] R.P. Hopkins; Industrial & Engineering Chemistry, 47, 1955, 2258-2265. http://dx.doi.org/10.1021/ie50551a024.
[28] S. Crisp, B.E. Kent, B.G. Lewis, A.J. Ferner, A.D. Wilson, J. Dent. Res., 59, (6), 1980, 1055-1063. http://dx.doi.org/10.1177/00220345800590060801.
[29] S. Crip, H.J. Prosser, A.D. Wilson, J. Mater. Sci., 11, 36 (1976). http://dx.doi.org/10.1007/BF00541072.
[30] S.M. Rabie, A. Sawaby, M.A. Moharram, A.M. Nassar, K.H. Tahon, J. Appl. Polym. Sci., 41, 445, 1990. http://dx.doi.org/10.1002/app.1990.070410301.
[31] T.W. Lambe, A.S. Michaels; Chemmical Engineering News, 32, 1954, 488-492. http://dx.doi.org/10.1021/cen-v032n006.p488.
[32] W. Ho-Shing, J. Heay-Chain, H. Jiann-Wen, J. Appl. Polym. Sci., 63, 1997, 89-101. http://dx.doi.org/10.1002/(SICI)1097-4628(19970103)63:1<89::AID-APP9>3.0.CO;2-O.
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How to Cite
Alvarez-Gayosso, C., A. Canseco, M., Estrada, R., Palacios-Alquisira, J., Hinojosa, J., & Castano, V. (2015). Preparation and microstructure of cobalt(III) poly (acrylate) hybrid materials. International Journal of Basic and Applied Sciences, 4(3), 255-263. https://doi.org/10.14419/ijbas.v4i3.4172Received date: 2015-01-13
Accepted date: 2015-02-10
Published date: 2015-06-09