CuO and CeO2 co-doped catalytic nanomaterial synthesized from red mud and rice husk ash for the deep oxidation of benzene, toluene and xylene

  • Authors

    • Nguyen Thanh Tinh Institute of Chemical Technology - VAST
    • Nguyen Thi Thuy Van University of Technology - VNU-HCM
    • Nguyen Phung Anh Institute of Chemical Technology - VAST
    • Huynh Ky Phuong Ha University of Technology - VNU-HCM
    • Nguyen Tri Institute of Chemical Technology - VAST
    2018-12-29
    https://doi.org/10.14419/ijet.v7i4.15888
  • CuO, CeO2, Catalytic Material, Red Mud, Rice Husk Ash, Deep Oxidation.

  • Abstract

    CuO-CeO2 catalysts with fixed content supported on material (ZRM) synthesized from red mud and rice husk ash were prepared by wet-ness co-impregnation and conbustion method. The effects of calcination conditions on physic-chemical properties and catalytic performance of CuCe/ZRM catalysts were emphasized. Several techniques, including Brunauer-Emmett-Teller nitrogen physisorption measurements (BET), X-ray powder diffraction (XRD), hydrogen temperature programmed reduction (H2-TPR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to investigate the properties of catalysts. It was obvious that the modification CuO-doped ZRM materials by CeO2 resulted in better surface morphology and more homogenous particles. The results evidenced that calcination conditions strongly affected the particle size, morphology and reduction of CuCe/ZRM catalysts. CuCe/ZRM sample calcined at 500 for 3 hours with higher porous and smaller nanoparticles with higher reduction was the best in terms of activity in deep oxidation of p-xylene at temperature of 275 − 400°C, achieving a 90% p-xylene conversion at 350 oC with WHSV of 12,000

    mL.h-1.g-1. The catalytic activity of the most prominent catalyst (CuCe/ZRM-500-3) sample increased in the following order: benzene < toluene < p-xylene. The presence of water vapor had a negative effect on catalytic activity due to the competition of water molecules with VOCs molecules for adsorption on surface active sites.

     

  • References

    1. [1] Kamal MS, Razzak SA & Hossain MM (2016), Catalytic oxidation of volatile organic compounds (VOCs)–A review. Atmospheric Environment 140, 117-134. https://doi.org/10.1016/j.atmosenv.2016.05.031.

      [2] Schwanke AJ, Pergher SB, Probst LF & Balzer R (2017), Gallium-Containing Mesoporous Silica: Supported Catalysts with High Catalytic Activity for Oxidation of Benzene, Toluene and o-Xylene. Journal of the Brazilian Chemical Society 28, 42-48.

      [3] da Costa WA, Lima CR, da Silva Filho FGS, de Oliveira MS, Cordeiro RM, de Carvalho Junior RN, Martelli MC & Brasil DdSB (2017), Computer simulation of benzene, toluene and p-xylene adsorption onto activated carbon. African Journal of Biotechnology 16, 1176-1181. https://doi.org/10.5897/AJB2016.15812.

      [4] Niaz K, Bahadar H, Maqbool F & Abdollahi M (2015), a review of environmental and occupational exposure to xylene and its health concerns. EXCLI journal 14, 1167.

      [5] Spivey JJ (1987), complete catalytic oxidation of volatile organics. Industrial & Engineering Chemistry Research 26, 2165-2180. https://doi.org/10.1021/ie00071a001.

      [6] Ordóñez S, Bello L, Sastre H, Rosal R & Dıez FV (2002), Kinetics of the deep oxidation of benzene, toluene, n-hexane and their binary mixtures over a platinum on γ-alumina catalyst. Applied Catalysis B: Environmental 38, 139-149. https://doi.org/10.1016/S0926-3373(02)00036-X.

      [7] Kim HS, Kim TW, Koh HL, Lee SH & Min BR (2005), complete benzene oxidation over Pt-Pd bimetal catalyst supported on γ-alumina: influence of Pt-Pd ratio on the catalytic activity. Applied Catalysis A: General 280, 125-131. https://doi.org/10.1016/j.apcata.2004.02.027.

      [8] Mu Z, Li JJ, Duan MH, Hao ZP &Qiao SZ (2008), Catalytic combustion of benzene on Co/CeO2/SBA-15 and Co/SBA-15 catalysts. Catalysis Communications 9, 1874-1877. https://doi.org/10.1016/j.catcom.2008.03.005.

      [9] Li S, Wang H, Li W, Wu X, Tang W & Chen Y (2015), Effect of Cu substitution on promoted benzene oxidation over porous CuCo-based catalysts derived from layered double hydroxide with resistance of water vapor. Applied Catalysis B: Environmental 166, 260-269.https://doi.org/10.1016/j.apcatb.2014.11.040.

      [10] Guo J-G, Li Z, Xi H-X, He C & Wang B-G (2005), Effect of Ceria Doping on the VOCs Oxidation Activity of CuO/CeO2/Zeolite Catalyst. Journal of Chemical Engineering of Chinese Universities 19, 776.

      [11] Liotta L, Ousmane M, Di Carlo G, Pantaleo G, Deganello G, Marcì G, Retailleau L &Giroir-Fendler A (2008), Total oxidation of propene at low temperature over Co3O4–CeO2 mixed oxides: Role of surface oxygen vacancies and bulk oxygen mobility in the catalytic activity. Applied Catalysis A: General 347, 81-88.https://doi.org/10.1016/j.apcata.2008.05.038.

      [12] Yang P, Shi Z, Yang S & Zhou R (2015), High catalytic performances of CeO2–CrOx catalysts for chlorinated VOCs elimination. Chemical Engineering Science 126, 361-369.https://doi.org/10.1016/j.ces.2014.12.051.

      [13] Avgouropoulos G, Ioannides T, Papadopoulou C, Batista J, Hocevar S & Matralis H (2002), A comparative study of Pt/γ-Al2O3, Au/α-Fe2O3 and CuO–CeO2 catalysts for the selective oxidation of carbon monoxide in excess hydrogen. Catalysis Today 75, 157-167.https://doi.org/10.1016/S0920-5861(02)00058-5.

      [14] Avgouropoulos G, Ioannides T, Matralis HK, Batista J &Hocevar S (2001), CuO–CeO2 mixed oxide catalysts for the selective oxidation of carbon monoxide in excess hydrogen. Catalysis Letters 73, 33-40.https://doi.org/10.1023/A:1009013029842.

      [15] Wang Z, Qu Z, Quan X, Li Z, Wang H & Fan R (2013), Selective catalytic oxidation of ammonia to nitrogen over CuO-CeO2 mixed oxides prepared by surfactant-templated method. Applied Catalysis B: Environmental 134, 153-166.https://doi.org/10.1016/j.apcatb.2013.01.029.

      [16] Lin R, Luo M-F, Zhong Y-J, Yan Z-L, Liu G-Y & Liu W-P (2003), Comparative study of CuO/Ce0.7Sn0.3O2, CuO/CeO2 and CuO/SnO2 catalysts for low-temperature CO oxidation. Applied Catalysis A: General 255, 331-336.https://doi.org/10.1016/S0926-860X(03)00639-2.

      [17] Urbutisa & Kitrys S (2014), Dual function adsorbent-catalyst CuO-CeO2/NaX for temperature swing oxidation of benzene, toluene and xylene. Central European Journal of Chemistry 12, 492-501.https://doi.org/10.2478/s11532-013-0398-x.

      [18] Avgouropoulos G & Ioannides T (2003), Selective CO oxidation over CuO-CeO2 catalysts prepared via the urea–nitrate combustion method. Applied Catalysis A: General 244, 155-167.https://doi.org/10.1016/S0926-860X(02)00558-6.

      [19] Luo M-F, Ma J-M, Lu J-Q, Song Y-P & Wang Y-J (2007), High-surface area CuO–CeO2 catalysts prepared by a surfactant-templated method for low-temperature CO oxidation. Journal of Catalysis 246, 52-59.https://doi.org/10.1016/j.jcat.2006.11.021.

      [20] Liu Y, Fu Q & Stephanopoulos M (2004), preferential oxidation of CO in H2 over CuO-CeO2 catalysts. Catalysis Today 93, 241-246.https://doi.org/10.1016/j.cattod.2004.06.049.

      [21] Schubert MM, Hackenberg S, Van Veen AC, Muhler M, Plzak V & Behm RJ (2001), CO oxidation over supported gold catalysts—“Inert†and “active†support materials and their role for the oxygen supply during reaction. Journal of Catalysis 197, 113-122.https://doi.org/10.1006/jcat.2000.3069.

      [22] Qu Y, Lian B, Mo B & Liu C (2013), Bioleaching of heavy metals from red mud using Aspergillus niger. Hydrometallurgy 136, 71-77.https://doi.org/10.1016/j.hydromet.2013.03.006.

      [23] Liu Y, Lin C & Wu Y (2007), Characterization of red mud derived from a combined Bayer Process and bauxite calcination method. Journal of Hazardous materials 146, 255-261.https://doi.org/10.1016/j.jhazmat.2006.12.015.

      [24] Liu Y, Naidu R & Ming H (2011), Red mud as an amend.ment for pollutants in solid and liquid phases. Geoderma 163, 1-12. https://doi.org/10.1016/j.geoderma.2011.04.002.

      [25] Sushil S &Batra VS (2008), Catalytic applications of red mud, an aluminium industry waste: A review. Applied Catalysis B: Environmental 81, 64-77.https://doi.org/10.1016/j.apcatb.2007.12.002.

      [26] Xue S, Zhu F, Kong X, Wu C, Huang L, Huang N & Hartley W (2016), A review of the characterization and revegetation of bauxite residues (Red mud). Environmental Science and Pollution Research 23, 1120-1132.https://doi.org/10.1007/s11356-015-4558-8.

      [27] Ni F, He J, Wang Y & Luan Z (2015), Preparation and characterization of a cost-effective red mud/polyaluminum chloride composite coagulant for enhanced phosphate removal from aqueous solutions. Journal of Water Process Engineering 6, 158-165. https://doi.org/10.1016/j.jwpe.2015.04.003.

      [28] Soldan M, Kobeticova H & Gerulova K (2017), Photocatalytic degradation of methylene blue using glass fibers catalytic layer covered with red mud. Journal of Materials and Applications 6, 23-27.

      [29] Wu J, Gong Z, Lu C, Niu S, Ding K, Xu L & Zhang K (2018), Preparation and performance of modified red mud-based catalysts for selective catalytic reduction of NOx with NH3. Catalysts 8, 35.https://doi.org/10.3390/catal8010035.

      [30] Ordóñez S, Sastre H & DıÌez FV (2001), Characterisation and deactivation studies of sulfided red mud used as catalyst for the hydrodechlorination of tetrachloroethylene. Applied Catalysis B: Environmental 29, 263-273. https://doi.org/10.1016/S0926-3373(00)00207-1.

      [31] Della VP, Kühn I & Hotza D (2002), Rice husk ash as an alternate source for active silica production. Materials Letters 57, 818-821. https://doi.org/10.1016/S0167-577X(02)00879-0.

      [32] Quyen DTN, Loc LC, Ha HKP, Nga DTH, Tri N & Van NTT, "Synthesis of adsorbent with zeolite structure from red mud and rice husk ash and its properties," in The 3rd Int. Conf. on Chem. Eng. Food BioTech., Hochiminh City, Vietnam, 2017.https://doi.org/10.1063/1.5000202.

      [33] Hieu DTM, Thinh TQ, Tri N, Van NTT & Ha HKP (2018), CuO-doped catalytic nanomaterial containing zeolite synthesized from red mud and rice husk ash for CO oxidation. Advances in Natural Sciences: Nanoscience and Nanotechnology (in press).

      [34] Yu J-G, Yu H-G, Cheng B, Zhao X-J, Yu JC & Ho W-K (2003), The effect of calcination temperature on the surface microstructure and photocatalytic activity of TiO2 thin films prepared by liquid phase deposition. The Journal of Physical Chemistry B 107, 13871-13879.https://doi.org/10.1021/jp036158y.

      [35] Boccuzzi F, Chiorino A, Manzoli M, Lu P, Akita T, Ichikawa S & Haruta M (2001), Au/TiO2 nanosized samples: A catalytic, TEM, and FTIR study of the effect of calcination temperature on the CO oxidation. Journal of Catalysis 202, 256-267.https://doi.org/10.1006/jcat.2001.3290.

      [36] Li P, He C, Cheng J, Ma CY, Dou BJ & Hao ZP (2011), Catalytic oxidation of toluene over Pd/Co3AlO catalysts derived from hydrotalcite-like compounds: Effects of preparation methods. Applied Catalysis B: Environmental 101, 570-579.https://doi.org/10.1016/j.apcatb.2010.10.030.

      [37] Galetti AE, Gomez MF, Arrua LA & Abello MC (2011), Ethanol steam reforming over Ni/ZnAl2O4-CeO2. Influence of calcination atmosphere and nature of catalytic precursor. Applied Catalysis A: General 408, 78-86.https://doi.org/10.1016/j.apcata.2011.09.006.

      [38] Nath H & Sahoo A (2014), a study on the characterization of red mud. International Journal on Applied Bioengineering 8,

      [39] Huang A, Lin Y & Yang W (2004), Synthesis and properties of A-type zeolite membranes by secondary growth method with vacuum seeding. Journal of Membrane Science 245, 41-51.https://doi.org/10.1016/j.memsci.2004.08.001.

      [40] Volanti D, Keyson D, Cavalcante L, Simões AZ, Joya M, Longo E, Varela JA, Pizani P & Souza A (2008), Synthesis and characterization of CuO flower-nanostructure processing by a domestic hydrothermal microwave. Journal of Alloys and Compounds 459, 537-542.https://doi.org/10.1016/j.jallcom.2007.05.023.

      [41] Luu CL, Nguyen T, Hoang TC, Hoang MN & Ha CA (2015), The role of carriers in properties and performance of Pt-CuO nanocatalysts in low temperature oxidation of CO and p-xylene. Adv. Nat. Sci.: Nanosci. Nanotechnol. 6, 015011 (9pp).

    2. style='font-size:12.0pt;font-family:"Times New Roman","serif";mso-fareast-font-family:
    3. Batang;mso-ansi-language:EN-US;mso-fareast-language:KO;mso-bidi-language:AR-SA'>
    4. style='mso-element:field-end'>

  • Downloads

  • How to Cite

    Thanh Tinh, N., Thi Thuy Van, N., Phung Anh, N., Ky Phuong Ha, H., & Tri, N. (2018). CuO and CeO2 co-doped catalytic nanomaterial synthesized from red mud and rice husk ash for the deep oxidation of benzene, toluene and xylene. International Journal of Engineering & Technology, 7(4), 4260-4265. https://doi.org/10.14419/ijet.v7i4.15888

    Received date: 2018-07-20

    Accepted date: 2018-12-02

    Published date: 2018-12-29