Fatty Acid Methyl Esters Production from Waste Catfish Fat (Pangasius Hypothalamus) Using Barnacle-Zno As A Catalyst
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2018-07-21 https://doi.org/10.14419/ijet.v7i3.11.15968 -
Barnacle Shells, Fatty Acid Methyl Esters, Waste Catfish Fat. -
Abstract
The abundance and diverse populations of Barnacle shells catching the intention as a source of calcium oxide catalyst to transesterify waste catfish fat into methyl ester. Calcium oxide supported with zinc oxide was prepared by ball milling method at 1:2 ratios, calcined for 3 h at 400 °C. The characterization of catalyst revealed both metals were well integrated into a bimetallic oxide. The optimal conditions were found to be: methanol/oil mass ratio, 10:1; catalyst amount, 11 wt% at the reaction temperature, 65 °C with 3 h of reaction time achieving 85.7% of methyl ester conversion. Both feedstock and catalyst from waste source have been successfully utilized to produce biodiesel.
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References
[1] Ahmad, J., Yusup, S., Bokhari, A., & Kamil, R.N.M. (2014). Study of fuel properties of rubber seed oil based biodiesel. Energy Conversion and Managemnt 78, 266–275.
[2] Maniam, G. P., Hindryawati, N., Nurfitri, I., Manaf, I. S. A., Ramachandran, N. & Rahim, M. H. A. (2015). Utilization of waste fat from catfish (Pangasius) in methyl esters preparation using CaO derived from waste marine barnacle and bivalve clam as solid catalysts. Journal of the Taiwan Institute of Chemical Engineers 49, 58-66.
[3] Alagesh, T., N. (2017). 'Ikan patin' at risk of becoming endangered. News Strait Times. https://www.nst.com.my/news/exclusive/2017/11/302318/ikan-patin-risk-becoming-endangered.
[4] Lukić, I., Kesić, Ž., Maksimović, S., Zdujić, M., Liu, H., Krstić, J. & Skala, D. (2013). Kinetics of sunflower and used vegetable oil methanolysis catalyzed by CaO•ZnO. Fuel 113, 367-378.
[5] Xie, W. & Huang, X. (2006). Synthesis of biodiesel from soybean oil using heterogeneous KF/ZnO catalyst. Catalyst Letter 107 (1–2): 53–59.
[6] Lim, B.P., Maniam, G.P. and Hamid, S.A. (2009). Biodiesel from adsorbed waste oil on spent bleacing clay using CaO as a heterogeneous catalyst. European Journal of Scientific Research 33 (2): 347–357.
[7] Kesić, Ž., Lukić, I., Brkić, D., Rogan, J., Zdujić, M., Liu, H. & Skala, D. (2012). Mechanochemical preparation and characterization of CaO•ZnO used as catalyst for biodiesel synthesis. Applied Catalysis A: General 427, 58-65.
[8] Berger, T., Schuh, J., Sterrer, M., Diwald, O. & Knözinger, E. (2007). Lithium ion induced surface reactivity changes on MgO nanoparticles. Journal of Catalysis 247(1), 61-67.
[9] Ngamcharussrivichai, C., Totarat, P. & Bunyakiat, K. (2008). Ca and Zn mixed oxide as a heterogeneous base catalyst for transesterification of palm kernel oil. Applied Catalysis A: General 341:77–85.
[10] Manaf, I.S.A., Embong, N. H., Rahim, M.H.A. & Maniam, G. P. (2016). In-situ transesterification of spent bleaching clay using CaO supported on ZnO as a basic catalyst. ARPN Journal of Engineering and Applied Sciences 11(11), 7229-7232.
[11] Luque, R. & Melero, J. A. (2012). Advances in biodiesel production: Processes and technologies. UK: Woodhead Publishing Limited.
[12] Islam, R., Paul, D. K., Rahman, A., Parvin, T., Islam, D. & Sattar, A. (2012). comparative characterization of lipids and nutrient contents of Pangasius Pangasius and Pangasius Sutchi available in Bangladesh. Journal of Nutrition & Food Sciences 2(2), 1-6.
[13] Maniam, G. P., Hindryawati, N., Nurfitri, I., Jose, R., Rahim, M. H. A., Dahalan, F. A. & Yusoff, M. M. (2013). Decanter cake as a feedstock for biodiesel production: A first report. Energy Conversion and Management 76, 527-532.
[14] Teo, S.H., Rashid, U. & Taufiq-Yap, Y.H. (2014). Heterogeneous catalysis of transesterification of Jatropha curcas oil over calcium-cerium bimetallic oxide catalyst. RSC Advances 4(90): 48836-48847.
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How to Cite
Norhafiza Mohd Khazaai, S., Farah Wahida Abdul Wahid Baki, N., Pragas Maniam, G., & Hasbi Ab. Rahim, M. (2018). Fatty Acid Methyl Esters Production from Waste Catfish Fat (Pangasius Hypothalamus) Using Barnacle-Zno As A Catalyst. International Journal of Engineering & Technology, 7(3.11), 228-231. https://doi.org/10.14419/ijet.v7i3.11.15968Received date: 2018-07-21
Accepted date: 2018-07-21
Published date: 2018-07-21