The Effect of Bases, Catalyst Loading and Reaction Temperature on the Catalytic Evaluation of Supported Palladium(II) Catalyst in the Mizoroki-Heck

  • Authors

    • Siti Kamilah Che Soh
    • Siti Aminah Jusoh
    • Mohd Sukeri Mohd Yusof
    • Wan M. Khairul
    • Mustaffa Shamsuddin
    https://doi.org/10.14419/ijet.v7i3.7.19026
  • Supported Palladium(II) Catalyst, Heterogeneous Catalysis, Mizoroki-Heck Reaction

  • Abstract

    The coupling reaction between aryl halide of 4-bromoacetophenone with methyl acrylate in the presence of supported palladium(II) catalyst has been investigated. The synthesized catalyst is air and moisture-stable turned out to be efficient and selective for Mizoroki-Heck reaction under operating conditions. Three parameters have been explored to monitor the performance of catalytic activities which    focused on the effect of bases, catalyst loading and reaction temperature. Furthermore, the catalyst can be easily recovered quantitatively by simple filtration and reused in at least three consecutive cycles of Mizoroki-Heck reaction.

     

     

  • References

    1. [1] Ohtaka, A., et al., Linear Polystyrene-Stabilized PdO Nanoparticles-Catalyzed Mizoroki-Heck Reactions in Water. Molecules. 2011. 16: 9067-9076.

      [2] Wen, C., et al., Recent Advances in Silver-Based Heterogeneous Catalysts for Green Chemistry Processess. Applied Catalysis B: Environmenta. 2014. 160: 730-741.

      [3] Dal Santo, V., et al., Design and Use of Nanostructured Single-Site Heterogeneous Catalysts for the Selective Transformation of Fine Chemicals. Molecules. 2010. 15: 3829-3856.

      [4] Kolahdoozan, M., et al., 2012. Synthesis of Heterogeneous Copper Catalyst based on Amino-Functionalized Triazine Rings Supported by Silica-Gel for oxidation of Alcohols. Journal of Chemistry. 2012. p. 1-7.

      [5] Agrell, J., et al., Production of Hydrogen by Partial Oxidation of Methanol over Zn-O-Supported Palladium Catalysts Prepared by Microemulsion Technique. Applied Catalysis A: General. 2003. 242: 233-245.

      [6] Huang, Y., et al., Polystyrene Microsphere-Immobilized Palladium(II) Porphyrin as Mild, Reusable and Highly Efficient Catalyst for Heck Reaction. Particuology. 2014. 22: 128-133.

      [7] Karimi, K., et al., Palladium Nanoparticles Supported on Polymer: An Efficient and Reusable Heterogeneous Catalyst for the Suzuki Cross-Coupling Reactions and Aerobic Oxidation of Alcohols. Catalysis Communications. 2013. 38: 10-15.

      [8] Che Soh, S. K., et al., Synthesis and Physicochemical Analysis of Polystyrene-Anchored Pd(II) Metal Complex. Scientific Research Journal. 2014. 11: 1-10.

      [9] Sutar, A. K., et al., Polymer Anchored Copper(II) Complex Supported by –ONNO- Schiff Base: Efficient Catalysts for Oxidation of Phenol. Indian Journal of Applied Research. 2013. 3: 44-48.

      [10] Bagherzadeh, M., et al., Supported Pd Nanoparticles on Mn-Based Metal-Organic Coordination Polymer: Efficient and Recyclable Heterogeneous Catalyst for Mizoroki-Heck Cross Coupling Reaction of Terminal Alkenes. Inorganic Chemistry Communications. 2014. 44:10-14.

      [11] Amini, M., et al., Suzuki-Miyaura Cross-Coupling Reactions in Water using In Situ Generated Palladium(II)-Phosphazane Complexes. Chinese Chemical Letters. 2014. 25: 166-168.

      [12] Ibrahim, W. N. W., et al., Symmetrical Palladium(II) N,N,O,O-Schiff Base Complex: Efficient Catalyst for Heck and Suzuki Reactions. Crystal Structure Theory and Applications. 2012. 1: 25-29.

      [13] Islam, M., et al., Heterogeneously catalyzed phosphined-free Heck Cross-Coupling Reaction of Aryl Halides with Reusable Palladium(II) Schiff Base Complex. Journal of the Brazilian Chemical Society. 2011. 22, 319-326.

      [14] Borhade, S. R., et al., Heck Reaction over Palladium Supported on Mickel Ferrite as an Efficient and Inexpensive Catalyst. Indian Journal of Chemistry. 2008. 47B: 1549-1554.

      Heidenreich, R. G., et al., Control of Pd Leaching in Heck Reactions of Bromoarenes catalyzed by Pd Supported on Activated Carbon. Journal of Molecular catalysis A: Chemical. 2002. 182-183: 499-509.

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  • How to Cite

    Kamilah Che Soh, S., Aminah Jusoh, S., Sukeri Mohd Yusof, M., M. Khairul, W., & Shamsuddin, M. (2018). The Effect of Bases, Catalyst Loading and Reaction Temperature on the Catalytic Evaluation of Supported Palladium(II) Catalyst in the Mizoroki-Heck. International Journal of Engineering & Technology, 7(3.7), 467-469. https://doi.org/10.14419/ijet.v7i3.7.19026

    Received date: 2018-09-05

    Accepted date: 2018-09-05