Direct Surfactant-Impregnated Activated Carbon for Adsorption of Reactive Blue 4

  • Authors

    • Puasa S.W
    • Ismail K.N
    • Khairi N.A.I.
    2018-11-27
    https://doi.org/10.14419/ijet.v7i4.18.21810
  • Activated carbon, adsorption process, esterquat, impregnated, cationic surfactant, plant-based surfactant, reactive dye.

  • Abstract

    The present investigation deals with the enhanced of adsorptive removal of Reactive Blue 4 (RB4) from an aqueous solution using Surfactant-impregnated Activated Carbon (SIAC). The study on direct impregnation method was investigated using palm-based esterquat (PBE) surfactant. The effects of surfactant concentration, temperature and pH on dye removal were discussed to determine the efficiency of adsorption process. Results obtained from this study shows that the best RB4 dye removal obtained was 67.25% at PBE concentration of 128 mg/L in 5 hours contact time and operating temperature of 50â°C. It was observed that adsorption of RB4 dye was enhanced by modification of AC with cleavable cationic surfactant via direct impregnation method. The selected data obtained was fitted using multilinear regression via Excel Software. The regression analysis shows that the R2 and adjusted R2 obtained were 0.973 and 0.905, respectively. The ANOVA analysis proved that the mathematical expression can be used to predict the adsorptive removal of RB4 dye from an aqueous solution.

     

     

  • References

    1. [1] A. Hasanbeigi and L. Price, "A review of energy use and energy efficiency technologies for the textile industry," Renewable and Sustainable Energy Reviews, Vol. 16, no. 6, (2012), pp. 3648-3665.

      [2] W. I. Nawawi, R. Zaharudin, A. Zuliahani, D. S. Shukri, T. F. Azis, and Z. Razali, "Immobilized TiO2-polyethylene glycol: Effects of aeration and pH of methylene blue dye," (in English), Applied Sciences (Switzerland), Article Vol. 7, no. 5, (2017),

      [3] T. A. Nguyen and R.-S. Juang, "Treatment of waters and wastewaters containing sulfur dyes: A review," Chemical Engineering Journal, Vol. 219, no. Supplement C, (2013), pp. 109-117.

      [4] A. N. Soon and B. H. Hameed, "Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process," Desalination, Vol. 269, no. 1, (2011), pp. 1-16.

      [5] A.-H. Chen and Y.-Y. Huang, "Adsorption of Remazol Black 5 from aqueous solution by the templated crosslinked-chitosans," Journal of Hazardous Materials, Vol. 177, no. 1, (2010), pp. 668-675.

      [6] H. Marsh and F. R. Reinoso, Activated Carbon. Elsevier Science, 2006.

      [7] H.-D. Choi, W.-S. Jung, J.-M. Cho, B.-G. Ryu, J.-S. Yang, and K. Baek, "Adsorption of Cr(VI) onto cationic surfactant-modified activated carbon," Journal of Hazardous Materials, Vol. 166, no. 2, (2009), pp. 642-646.

      [8] C. K. Ahn, D. Park, S. H. Woo, and J. M. Park, "Removal of cationic heavy metal from aqueous solution by activated carbon impregnated with anionic surfactants," Journal of Hazardous Materials, Vol. 164, no. 2, (2009), pp. 1130-1136.

      [9] G. Mezohegyi, F. P. van der Zee, J. Font, A. Fortuny, and A. Fabregat, "Towards advanced aqueous dye removal processes: A short review on the versatile role of activated carbon," Journal of Environmental Management, Vol. 102, no. Supplement C, (2012), pp. 148-164.

      [10] C. Y. Yin, M. K. Aroua, and W. M. A. W. Daud, "Review of modifications of activated carbon for enhancing contaminant uptakes from aqueous solutions," Separation and Purification Technology, Vol. 52, no. 3, (2007), pp. 403-415.

      [11] M. M. Mohamed, "Acid dye removal: comparison of surfactant-modified mesoporous FSM-16 with activated carbon derived from rice husk," Journal of Colloid and Interface Science, Vol. 272, no. 1, (2004), pp. 28-34.

      [12] M. R. Mahmoud, G. E. Sharaf El-deen, and M. A. Soliman, "Surfactant-impregnated activated carbon for enhanced adsorptive removal of Ce(IV) radionuclides from aqueous solutions," Annals of Nuclear Energy, Vol. 72, no. Supplement C, (2014), pp. 134-144.

      [13] M. Auta and B. H. Hameed, "Optimized and functionalized paper sludge activated with potassium fluoride for single and binary adsorption of reactive dyes," Journal of Industrial and Engineering Chemistry, Vol. 20, no. 3, (2014), pp. 830-840.

      [14] J.-Z. Guo, B. Li, L. Liu, and K. Lv, "Removal of methylene blue from aqueous solutions by chemically modified bamboo," Chemosphere, Vol. 111, no. Supplement C, (2014), pp. 225-231.

      [15] A. Behnamfard, M. M. Salarirad, and F. Vegliò, "Removal of Zn(II) ions from aqueous solutions by ethyl xanthate impregnated activated carbons," Hydrometallurgy, Vol. 144-145, no. Supplement C, (2014), pp. 39-53.

      [16] M. Wang, F. Hao, G. Li, J. Huang, N. Bao, and L. Huang, "Preparation of Enteromorpha prolifera-based cetyl trimethyl ammonium bromide-doped activated carbon and its application for nickel(II) removal," Ecotoxicology and Environmental Safety, Vol. 104, no. Supplement C, (2014), pp. 254-262.

      [17] S. W. Puasa, M. S. Ruzitah, and A. S. A. K. Sharifah, "Competitive Binding Interaction between Anionic Reactive Dyes and Cleavable Surfactant Micelles in Micellar-enhanced Microfiltration," Procedia Engineering, Vol. 148, no. Supplement C, (2016), pp. 516-523.

      [18] Z.-L. Qiu et al., "Cross-linked PVC/hyperbranched polyester composite hollow fiber membranes for dye removal," Reactive and Functional Polymers, Vol. 122, (2018), pp. 51-59.

      [19] S. W. Puasa, M. S. Ruzitah, and A. S. A. K. Sharifah, "Simplified colorimetric method using reactive orange 16 for analysis of cationic surfactant," in Advanced Materials Research vol. 701, ed, 2013, pp. 342-346.

      [20] A. Wasti and M. Ali Awan, "Adsorption of textile dye onto modified immobilized activated alumina," Journal of the Association of Arab Universities for Basic and Applied Sciences, Vol. 20, no. Supplement C, (2016), pp. 26-31.

      [21] M. A. M. Salleh, D. K. Mahmoud, W. A. W. A. Karim, and A. Idris, "Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review," Desalination, Vol. 280, no. 1, (2011), pp. 1-13.

      [22] W.-f. Chen, Z.-Y. Zhang, Q. Li, and H.-Y. Wang, "Adsorption of bromate and competition from oxyanions on cationic surfactant-modified granular activated carbon (GAC)," Chemical Engineering Journal, Vol. 203, (2012), pp. 319-325.

      [23] S. Chowdhury and T. K. Saha, "Adsorption of Reactive Blue 4 (RB4) onto Rice Husk in Aqueous Solution," International Journal of Scientific & Engineering Research, Vol. 7, no. 3, (2016), pp. 7-12.

      [24] Y. S. Al-Degs, M. I. El-Barghouthi, A. H. El-Sheikh, and G. M. Walker, "Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon," Dyes and Pigments, Vol. 77, no. 1, (2008), pp. 16-23.

      [25] X. Peng, X. Hu, D. Fu, and F. L. Y. Lam, "Adsorption removal of acid black 1 from aqueous solution using ordered mesoporous carbon," Applied Surface Science, Vol. 294, (2014), pp. 71-80.

      [26] D. Sun, Z. Zhang, M. Wang, and Y. Wu, "Adsorption of Reactive Dyes on Activated Carbon Developed from Enteromorpha prolifera," American Journal of Analytical Chemistry, Vol. 4, no. 7A, (2013), pp. 17-26.

      [27] M. A. Ahmad, N. A. Ahmad Puad, and O. S. Bello, "Kinetic, equilibrium and thermodynamic studies of synthetic dye removal using pomegranate peel activated carbon prepared by microwave-induced KOH activation," Water Resources and Industry, Vol. 6, (2014), pp. 18-35.

      [28] C. S. Kirby and C. A. Cravotta, "Net alkalinity and net acidity 1: Theoretical considerations," Applied Geochemistry, Vol. 20, no. 10, (2005), pp. 1920-1940.

      [29] M. K. Purkait, S. DasGupta, and S. De, "Adsorption of eosin dye on activated carbon and its surfactant based desorption," Journal of Environmental Management, Vol. 76, no. 2, (2005), pp. 135-142.

      [30] W. R. Wilcox. (2010, May). Explanation of results returned by the Regression tool in Excel’s Data Analysis. Available: http://people.clarkson.edu/~wwilcox/ES100/regrint.htm

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  • How to Cite

    S.W, P., K.N, I., & N.A.I., K. (2018). Direct Surfactant-Impregnated Activated Carbon for Adsorption of Reactive Blue 4. International Journal of Engineering & Technology, 7(4.18), 5-8. https://doi.org/10.14419/ijet.v7i4.18.21810

    Received date: 2018-11-27

    Accepted date: 2018-11-27

    Published date: 2018-11-27