AC Conductivity and Dielectric Properties of Strontium-Lead Borate Glasses
-
2018-11-27 https://doi.org/10.14419/ijet.v7i4.18.21887 -
AC conductivity, borate glass, dielectric properties, electric modulus, impedance spectroscopy. -
Abstract
The AC conductivity and dielectric properties of strontium-lead borate glasses with composition of (90-x)B2O3-10PbO-xSrO (x = 20, 25, 30, 35, 40, 45) were studied in the frequency range of 0.01 Hz to 106 Hz at room temperature to investigate the effects of SrO in the glasses. The variation of AC conductivity with SrO content showed a minimum value at x = 25 mol% before increasing to 25 < x ≤ 35 mol%, followed by a slight decrease of x > 35 mol%. Meanwhile, dielectric constant showed a minimum at x = 25 mol% before increasing to x > 25 mol%. The decrease at x = 25 mol% coincided with the σAC drop at the same concentration. This decrease could be associated with the increasing number of bridging oxygens, which restricted dipole movement. The electric modulus of the investigated samples showed that the trend of the imaginary part of the electrical modulus (M″) was in tandem with the behaviour of AC conductivity.
Â
Â
-
References
[1] Abdel-Baki M and El-Diasty F (2006), Optical properties of oxide glasses containing transition metals: Case of titanium-and chromium-containing glasses. Current Opinion in Solid State and Material Sciences 10 (5-6), 217-229.
[2] Dimitrov V and Komatsu T (2013), Electronic polarizability, optical basicity and single bond strength of oxide glasses. Journal of Chemical Technology and Metallurgy 48, 549-554.
[3] Kaur G, Pandey OP and Singh K (2012). Effect of modifiers field strength on optical, structural and mechanical properties of lanthanum borosilicate glasses. Journal of Non-Crystalline Solids 358, 2589-2596.
[4] Khafagy AH, E-Adawy AA, Higazy AA, El-Rabaie S and Eid AS (2008), Studies of some mechanical and optical properties of (70-x)TeO2+15B2O3+15P2O5+xLi2O glasses. Journal of Non-Crystalline Solids 354, 3152-3158.
[5] Saddeek YB (2004), Structural analysis of alkali borate glasses. Physica B: Condense Matter 344, 163-175.
[6] Shelby JE (2005), Introduction to Glass Science And Technology, 2nd edition, Royal Society of Chemistry, Cambridge.
[7] Latif IAE (2005), Ultrasonic study on the role of Na2O on the structure of Na2O-B2O3 and Na2O-B2O3-SiO2 glasses. Journal of Pure and Applied Ultrasonic 27, 80-91.
[8] Kawashima M, Matsuda Y and Kojima S (2011), Temperature dependence of elastic properties in alkali borate binary glasses. Journal of Molecular Structure 993 (1-3), 155-159.
[9] Yiannopoulos Y, Chryssikos GD and Kamitsos E (2001), Structure and porperties of alkaline earth borate glasses. Physics and Chemistry of Glasses 42 (3),164-172.
[10] Sabri NS, Yahya AK, Abd Shukor R and Talari MK (2016), Anomalous elastic behaviour of xSrO-10PbO-(90-x)B2O3 glass system. Journal of Non-Crystalline Solids 444, 55-63.
[11] Eun-Sub L, Byung-Sook K, Joon-Hyung L and Jeong-Joo K (2007), Characterization of the low temperature firing BaO–B2O3–SiO2 glass: The effect of BaO content. Journal of the European Ceramic Society 27(2–3), 825-829.
[12] Abdel-Khalek EK, Mohamed EA, Shaaban M Salem and Kashif I (2018), Structural and dielectric properties of (100-x)B2O3-(x/2) Fe2O3 glasses and glass-ceramic containing BiFeO3 phase. Journal of Non-Crystalline Solids 492, 41-49.
[13] Chaudhry MA and Bilal S (1995), Concentration-dependent electrical conductivity of phosphate glasses containing zinc oxide. Materials Chemistry and Physics 41(4), 299-301.
[14] Rosdiyana Hisam, Ahmad Kamal Yahya and Halimah Mohamed Kamari (2017), AC Conductivity and dielectric behavior in mixed electronic-ionic 30Li2O-4MoO3-(66-x)TeO2-xV2O5 glass system. Ionics 23(6), 1423-1437.
[15] Rani S, Sanghi S, Ahlawat N and Agarwal A (2015), Influence of Bi2O3 on physical, electrical and thermal properties of Li2O-ZnO-Bi2O3-SiO2 glasses. Journal of Alloy and Compound 619, 659-666.
-
Downloads
-
How to Cite
Hisam, R., K. Yahya, A., Said, D., & F. Mustafa, M. (2018). AC Conductivity and Dielectric Properties of Strontium-Lead Borate Glasses. International Journal of Engineering & Technology, 7(4.18), 143-146. https://doi.org/10.14419/ijet.v7i4.18.21887Received date: 2018-11-27
Accepted date: 2018-11-27
Published date: 2018-11-27