Corrosion inhibition of carbon steel using fatty amide derivatives and an oxygen scavenger under elevated temperatures

  • Authors

    • Izni Mariah Ibrahim
    • Ezan Suhailah Mohd Kassim
    • Junaidah Jai
    • Muhamad Daud
    • Md Amin Hashim
    2018-11-27
    https://doi.org/10.14419/ijet.v7i4.18.21942
  • corrosion inhibition, fatty amides, oxygen scavengers, sodium sulphite, electrochemical test

  • Abstract

    In this study, fatty amides and sodium sulphite were introduced as corrosion inhibitor and oxygen scavenger respectively. The synergistic effect of corrosion inhibition of carbon steel in 3.5% sodium chloride solution was investigated under elevated temperatures (30, 40, and 50 °C). The corrosion inhibitor was synthesized using reflux reaction from material of palm fatty acid distillate. The performance of sodium sulphite as oxygen scavenger was tested using dissolved oxygen meter. The corrosion inhibition efficiency of the corrosion inhibitors was studied using the electrochemical test namely linear polarization resistance method. The results revealed that the combination of fatty amides and sodium sulphite inhibits the corrosion of carbon steel by reducing the concentration of dissolved oxygen in the solution and increased the inhibition efficiency.

     

     

  • References

    1. [1] X. Jiang, Y. G. Zheng, and W. Ke, “Effect of flow velocity and entrained sand on inhibition performances of two inhibitors for CO2 corrosion of N80 steel in 3% NaCl solution,†Corros. Sci., vol. 47, no. 11, pp. 2636–2658, 2005.

      [2] A. I. Ali and Y. S. Mahrous, “Corrosion inhibition of C-steel in acidic media from fruiting bodies of Melia azedarach L extract and a synergistic Ni2+ additive,†Rsc Adv., vol. 7, no. 38, pp. 23687–23698, 2017.

      [3] I. M. Ibrahim, J. Jai, and M. A. Hashim, “Inhibitive effect of fatty amide and secondary species on the corrosion of carbon steel,†Adv. Mater. Res., vol. 1133, pp. 366–370, 2016.

      [4] T. Laabaissi et al., “Adsorption and corrosion inhibition effect of benzodiazepine derivative on carbon steel in 2.0 M H3PO4 medium,†J. Mater. Environ. Sci., vol. 7, no. 5, pp. 1538–1548, 2016.

      [5] A. H. Al Hamzi et al., “The role of acridin-9 (10H)-one in the inhibition of carbon steel corrosion: thermodynamic, electrochemical and DFT studies,†Int. J. Electrochem. Sci, vol. 8, pp. 2586–2605, 2013.

      [6] R. Farahmand, B. Sohrabi, A. Ghaffarinejad, and M. R. Zamani Meymian, “Synergistic effect of molybdenum coating and SDS surfactant on corrosion inhibition of mild steel in presence of 3.5% NaCl,†Corros. Sci., no. April 2017, 2018.

      [7] L. M. Rivera-Grau et al., “Effect of organic corrosion inhibitors on the corrosion performance of 1018 carbon steel in 3% NaCl solution,†Int. J. Electrochem. Sci., vol. 8, no. 2, pp. 2491–2503, 2013.

      [8] H. Möller, E. T. Boshoff, and H. Froneman, “The corrosion behaviour of a low carbon steel in natural and synthetic seawaters,†J. South African Inst. Min. Metall., no. August, pp. 585–592, 2006.

      [9] S. A. Umoren, M. M. Solomon, I. I. Udosoro, and A. P. Udoh, “Synergistic and antagonistic effects between halide ions and carboxymethyl cellulose for the corrosion inhibition of mild steel in sulphuric acid solution,†Cellulose, vol. 17, no. 3, pp. 635–648, 2010.

      [10] A. Y. Musa, A. B. Mohamad, A. A. H. Kadhum, M. S. Takriff, and L. T. Tien, “Synergistic effect of potassium iodide with phthalazone on the corrosion,†J. Corros. Sci., vol. 53, 2011.

      [11] S. Javadian, A. Yousefi, and J. Neshati, “Synergistic effect of mixed cationic and anionic surfactants on the corrosion inhibitor behavior of mild steel in 3.5% NaCl,†Appl. Surf. Sci., vol. 285, no. PARTB, pp. 674–681, 2013.

      [12] S. A. Umoren and M. M. Solomon, “Recent developments on the use of polymers as corrosion inhibitors - A review,†Open Mater. Sci. J., vol. 8, pp. 39–54, 2014.

      [13] L. P. Koskan and W. J. Benton, “Inhibition of carbon dioxide corrosion of metals,†5607623, 1997.

      [14] R. T. Loto, “Pyrimidine derivatives as environmentally-friendly corrosion inhibitors: A review,†Int. J. Phys. Sci., vol. 7, no. 19, pp. 2136–2144, 2012.

      [15] A. A. Aghzzaf, B. Rhouta, E. Rocca, A. Khalil, and J. Steinmetz, “Corrosion inhibition of zinc by calcium exchanged beidellite clay mineral: A new smart corrosion inhibitor,†Corros. Sci., vol. 80, pp. 46–52, 2014.

      [16] S. Gudić, L. Vrsalović, M. Kliškić, I. Jerković, A. Radonić, and M. Zekić, “Corrosion inhibition of AA 5052 aluminium alloy in NaCl solution by different types of honey,†Int. J. Electrochem. Sci., vol. 11, pp. 998–1011, 2016.

      [17] H. H. Ou, Q. T. P. Tran, and P. H. Lin, “A synergistic effect between gluconate and molybdate on corrosion inhibition of recirculating cooling water systems,†Corros. Sci., vol. 133, no. December 2017, pp. 231–239, 2018.

      [18] S. K. Shukla and E. E. Ebenso, “Corrosion inhibition, adsorption behavior and thermodynamic properties of streptomycin on mild steel in hydrochloric acid medium,†Int. J. Electrochem. Sci., vol. 6, no. 8, pp. 3277–3291, 2011.

      [19] M. A. Bedair, M. M. B. El-Sabbah, A. S. Fouda, and H. M. Elaryian, “Synthesis, electrochemical and quantum chemical studies of some prepared surfactants based on azodye and Schiff base as corrosion inhibitors for steel in acid medium,†Corros. Sci., vol. 128, no. April, pp. 54–72, 2017.

      [20] C. Rahal et al., “Olive leaf extract as natural corrosion inhibitor for pure copper in 0.5M NaCl solution: A study by voltammetry around OCP,†J. Electroanal. Chem., vol. 769, pp. 53–61, 2016.

      [21] K. Boumhara et al., “Use of Artemisia Mesatlantica essential oil as green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution,†Int. J. Electrochem. Sci., vol. 9, no. 3, pp. 1187–1206, 2014.

      [22] M. A. Hashim, S. N. M. Saleh, and M. R. M. Toff, “Surface adsorption mechanism: A molecular self assembly phenomenon with application to surface protection,†2010, vol. 1217, pp. 279–286.

      [23] B. Greaves, S. C. Poole, C. M. H. Hwa, and J. C.-J. Fan, “Method for inhibition of oxygen corrosion in aqueous systems by the use of a tannin activated oxygen scavenger,†1998.

      [24] S. S. Bandodkar, “Scavenging oxygen dissolved in water for minimizing corrosion in metals,†Goa University, India, 2011.

      [25] J. Cossy and C. Pale-Grosdemange, “A convenient synthesis of amides from carboxylic acids and primary amines,†Tetrahedron Lett., vol. 30, no. 21, pp. 2771–2774, 1989.

      [26] N. I. K. Al-darmaki, “Extraction and enrichment of minor lipid components of palm fatty acid distillate using supercritical carbon dioxide,†University of Birmingham, 2012.

      [27] O. Abel-Anyebe, K. I. Ekpenyong, and A. Eseyin, “A novel synthetic route to fatty amides in non-aqueous reaction of fatty esters with ammonium salts and methyl amine,†Int. J. Chem., vol. 5, no. 1, pp. 80–86, 2013.

      [28] D. B. Hobson, P. J. Richardson, P. J. Robinson, E. A. Hewitt, and I. Smith, “Kinetics of the oxygen-sulfite reaction at waterflood concentrations: Effect of catalysts and seawater medium,†Ind. Eng. Chem. Res., vol. 26, pp. 1818–1822, 1987.

      [29] North Metal & Chemical Company, “Technical Services: DEHA vs sodium sulfite,†1997.

      [30] T. I. Wu and J. K. Wu, “Effect of sulfate ions on corrosion inhibition of AA 7075 aluminum alloy in sodium chloride solutions,†Corrosion, vol. 51, no. 3, pp. 185–190, 1995.

      [31] I. A. Akpan and N. O. Offiong, “Electrochemical linear polarization studies of amodiaquine drug as a corrosion inhibitor for mild steel in 0 . 1M HCL Solution,†Chem. Mater. Res., vol. 7, no. 1, pp. 17–21, 2015.

  • Downloads

  • How to Cite

    Mariah Ibrahim, I., Suhailah Mohd Kassim, E., Jai, J., Daud, M., & Amin Hashim, M. (2018). Corrosion inhibition of carbon steel using fatty amide derivatives and an oxygen scavenger under elevated temperatures. International Journal of Engineering & Technology, 7(4.18), 316-320. https://doi.org/10.14419/ijet.v7i4.18.21942

    Received date: 2018-11-27

    Accepted date: 2018-11-27

    Published date: 2018-11-27