Observation of Charge Ordering Signal in Monovalent Doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) Manganites

  • Authors

    • Sufia Aqilah Razali
    • Norazilah Ibrahim
    • Suhadir Shamsuddin
    • Mohamad Zaky Noh
    2018-11-30
    https://doi.org/10.14419/ijet.v7i4.30.22021
  • AC Susceptibility, DC Electrical, Scanning Electron Microscope, X-Ray Diffraction

  • Abstract

    K doping in the compound of Nd0.75Na0.25-xKxMn1O3 (x = 0, 0.05 and 0.10) manganites have been investigated to study its effect on crystalline phase and surface morphology as well as electrical transport and magnetic properties. The structure properties of the Nd0.75Na0.25-xKxMnO3 manganite have been characterized using X-ray diffraction measurement and it proved that the crystalline phase of samples were essentially single phased and indexed as orthorhombic structure with space group of Pnma. The morphological study from scanning electron microscope showed there was an improvement on the grains boundaries and sizes as well as the compactness with K doping suggestively due to the difference of ionic radius. On the other hand, DC electrical resistivity measurement showed all samples exhibit insulating behavior. However, analysis of dlnÏ/dT-1 vs. T revealed the clearly peaks could be observed at temperature 210K for x = 0 and the peaks were shifted to the lower temperature around 190 K and 165 K for x = 0.05 and x = 0.1 respectively, indicate the existence of charge ordering (CO) state in the compound. Meanwhile, the investigation on magnetic behavior showed all samples exhibit transition from paramagnetic phase to anti-ferromagnetic phase with decreasing temperature and the TN was observed to shift to lower temperature suggestively due to weakening of CO state

  • References

    1. [1] Yang H, Zhang PY, Wu Q, Ge HL & Pan MX, “Effect of monovalent metal substitution on the magnetocaloric effect of perovskite manganites Pr0.5Sr0.3M0.2MnO3 (M=Na, Li, K and Ag)â€, Journal of Ceramic International, Vol. 324, (2012), pp. 3727-3730.

      [2] Tasarkuyu E, Irmak AE, Coskun A & Akturk S, “Structural, magnetic and transport properties of La0.70Sr0.21K0.09MnO3â€, Journal of Alloys and Compounds, Vol. 588, (2004), pp. 422–427.

      [3] Shamsuddin S, Baset A, Ibrahim MA & Yahya AK, “Effects of Cr substitution and oxygen eduction on elastic anomaly and ultrasonic velocity incharge-ordered Nd0.5Ca0.5Mn1-xCrxO3-d ceramicsâ€, Journal of Superconductivity and Novel Magnetism, Vol. 39, (2013), pp. S185–S188.

      [4] Malik H, Mahmood A, Mahmood K, Yousaf M, Warsi MF, Shakir I, Wahab H, Asghar M and Khan MA, “Influence of cobalt substitution on the magnetic properties of zinc nanocrystals synthesized via micro-emulsion routeâ€, Journal of Ceramics International, Vol. 40, (2012), pp. 9439–9444.

      [5] Mohammad HE & Mahmoud JM, “The electrical transition temperature and magnetoresistance prediction of LaSr2Mn2O7 bilayered manganiteâ€, Journal of King Saud University Engineering Science. http://dx.doi.org/10.1016/j.jksues.2016.03.004.

      [6] Tang T, Huang RS & Zhang SY, “Magnetic and magneotransport properties of Nd0.75Na0.25MnO3 manganiteâ€, Journal of Solid State Communications, Vol. 147, (2008), pp. 190–193.

      [7] Kanamori J, "Superexchange interaction and symmetry properties of electron orbitalsâ€, Journal of Physic Chemistry Solid, Vol. 10, (1959), pp. 87-89.

      [8] Shaikh MW, Mansuri I, Dar MR & Varshney D, “Structural and transport properties of La1-xAgxMnO3 (x = 0.075, 0.1, 0.125 and 0.15) manganitesâ€, Journal of Materials Science in Semiconductor Processing, Vol. 35, (2015), pp. 10–21.

      [9] Mannan NN, Razali SA, Shamsuddin S & Noh MZ, “Crystalline Phase, Surface Morphology and Electrical Properties of Monovalent-doped Nd0.75Na0.25Mn1-yCoyO3 Manganitesâ€, Journal of Science and Technology, Vol. 9, (2017), pp. 65-69.

      [10] Li Y, Miao J, Sui Y, Wang X, Zhang W, Liu Y, Zhu R & Su W, “Synthesis, structural and transport properties of Pr0.75Na0.25Mn1−xFexO3 (0.0≤x≤0.3)â€, Journal of Alloys Compound, Vol. 441(1), (2007), pp. 1–5.

      [11] Zhang X & Li Z, “Influence of Cr-doping on the magnetic and electrical transport properties of Nd0.75Na0.25MnO3â€, Journal of Rare Earths, Vol. 29, (2011), pp. 230–234.

      [12] Maryam A, Ibrahim N, Zakiah M, Yahya AK, Nawazish AK & Khans MN, “Revival of Metal-Insulator and Ferromagnetic-Paramagnetic Transitions by Ni Substitution at Mn Site in Charge-Ordered Monovalent Doped Nd0.75Na0.25MnO3 Manganitesâ€, Journal of Superconductivity and Novel Magnetism https://doi.org/10.1007/s10948-017-4521-7.

      [13] Rozilah R, Ibrahim N, Mohamed Z, Yahya AK, Khan NA & Khan MN, “Inducement of ferromagnetic-metallic phase in intermediate-doped charge-ordered Pr0.75Na0.25MnO3 manganite by K+ substitutionâ€, Journal of Physica B, Vol. 521 (2017), pp. 281–294.

      [14] Zawawi RA, Khairulzaman NN & Shamsuddin S, “Effect of Cr-doped on Crystalline Phase, Surface Morphology and Electrical Properties of Charge-Ordered Nd0.75Na0.25MnO3 Ceramicâ€, Journal of Science and Technology, Vol. 9, (2017), pp. 45-48.

      [15] Liu XJ, Jiang EY, Li ZQ, Li BL, Li WR, Yu A & Bai HL, “Magnetic, electrical transport and electron spin resonance studies of charge-ordered Nd0.75Na0.25MnO3â€, Journal of Physica B, Vol. 348(1), (2014), pp. 146–150.

      [16] Modi A, Bhat MA, Pandey DK, Tarachand, Bhattacharya S, Gaur NK & Okram GS, “Structural, magnetotransport and thermal properties of Sm substituted La0.7-xSmxBa0.3MnO3 (0 ≤ x ≤0.2) manganitesâ€, Journal of Magnetism and Magnetic Materials, Vol. 424, (2017), pp. 459-466.

      [17] Thaljaou R, Pekala K, Pekala M, Boujelben W, SzydÅ‚owska J, Fagnard J F, Vanderbemden P & Cheikhrouhou A, “Magnetic susceptibility and electron magnetic resonance study of monovalent potassium doped manganites Pr0.6Sr0.4-xKxMnO3â€, Journal of Alloys and Compound, Vol. 580, (2013), pp. 137–142.

      [18] Fan J, Pi L, He K, Wang W & Zhang Y, “Charge ordering melting and evidence for a metastable antiferromagnetic phase in Nd0.5(1−x)Ca0.5(1+x)Mn1−xTixO3â€, EPL (Europhys. Lett.), Vol. 74(3), (2006), pp. 506.

      [19] Tarhounia S, Mleiki A, Chaaba I, Khelifa HB, Koubaa WC, Koubaa M, Cheikhrouhou A & Hlil EK, “Structural, magnetic and magnetocaloric properties of Ag-doped Pr0.5Sr0.5-xAgxMnO3 manganites (0.0≤x≤0.4)â€, Journal of Ceramics International, Vol. 43, (2017), pp. 133–143.

      [20] Thaljaoui R, Boujelben W, Pekala M, Pekal K, Mucha J & Cheikhrouhou A, “Structural, magnetic and transport study of monovalent Na-doped manganite Pr0.55Na0.05Sr0.4MnO3â€, Journal of Alloys and Compound, Vol. 558, (2013), pp. 236–243.

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  • How to Cite

    Razali, S. A., Ibrahim, N., Shamsuddin, S., & Noh, M. Z. (2018). Observation of Charge Ordering Signal in Monovalent Doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) Manganites. International Journal of Engineering & Technology, 7(4.30), 85-88. https://doi.org/10.14419/ijet.v7i4.30.22021

    Received date: 2018-11-28

    Accepted date: 2018-11-28

    Published date: 2018-11-30