Preparation of Aniline Dimer-COOH Modified Magnetite (Fe3O4) Nanoparticles by Ultrasonic Dispersion Method

  • Abstract
  • Keywords
  • References
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  • Abstract

    The magnetite (Fe3O4) nanoparticles capped with certain level of aniline dimer-COOH were prepared via assisted ultrasonic dispersion method and characterized by X-ray Diffraction spectra (XRD), Field Emission Scanning Electron Microscope (FESEM), Ultraviolent UV-visible (UV-vis) and Fourier Transformation Infrared spectroscopy (FTIR). The XRD result shows that both the sample of Fe3O4 nanoparticles synthesized without aniline dimer-COOH have similar peaks with the one that were capped with aniline dimer-COOH, this indicated the higher purity crystalline peaks of Fe3O4 nanoparticles was successfully synthesized. The Field Emission Scanning Electron Microscope (FESEM) result shows that, the aniline dimer-COOH modified magnetite nanoparticles are less agglomerated with spherical shape and continues size distribution, and the obtained image from EDS indicates the present of Fe3O4 nanoparticles by showing Fe-O group of element. The magnetic properties of the magnetite nanoparticles prepared by ultrasonic irradiation method was observed by vibrating sample magnetometer (VSM), the hysteresis loop of Fe3O4 nanoparticles observed by VSM has a saturation magnetization at 89.46 emug-1 indicating super paramagnetic behavior of the Fe3O4 nanoparticles.  

  • Keywords

    Magnetite Nanoparticles; Magnetic Properties; Morphologies; Ultrasonic Dispersion Method.

  • References

      [1] Márquez F et al., “Synthesis and Characterization of Monodisperse Magnetite Hollow Microspheres”, Soft Nanosci. Lett., Vol. 1, No. April, (2011), pp. 25–32.

      [2] Singh BP et al., “Synthesis , characterization , and electrochemical response of iron oxide nanoparticles for sensing acetaminophen”, Mater. Res. Express, Vol. 3, No. 10, (2014), pp. 1–13.

      [3] Chattopadhyay S, Bajpai OP & Setua DK, “A Brief Overview on Ferrite (Fe3O4) Based Polymeric Nanocomposites: Recent Developments and Challenges”, J. Res. Updat. Polym. Sci., Vol. 3, No. 4, (2015), pp. 184–204.

      [4] Han X & Wang YS, “Studies on the synthesis and microwave absorption properties of Fe3O4/polyaniline FGM”, Phys. Scr., Vol. T129, (2007), pp. 335–339.

      [5] Mamani JB, Gamarra LF & de S Brito GE, “Synthesis and characterization of Fe3O4 nanoparticles with perspectives in biomedical applications”, Mater. Res., Vol. 13, No. 11, 2014.

      [6] Hariani PL, Faizal M, Ridwan R, Marsi M & Setiabudidaya D, “Synthesis and Properties of Fe3O4 Nanoparticles by Co-precipitation Method to Removal Procion Dye”, Int. J. Environ. Sci. Dev., Vol. 4, No. 3, (2013), pp. 336–340.

      [7] Wu Q, Chen M, Chen K, Wang S, Wang C & Diao G, “Fe3O4-based core/shell nanocomposites for high-performance electrochemical supercapacitors”, J. Mater. Sci., Vol. 51, No. 3, 2016, pp. 1572–1580.

      [8] Mallahi M, Shokuhfar A, Vaezi MR, Esmaeilirad A & Mazinani V, “Synthesis and characterization of Bismuth oxide nanoparticles via sol-gel method”, Am. J. Eng. Res., Vol. 03, No. 04, (2014), pp. 162–165.

      [9] Bhaumik M, Maity A & Gupta VK, “Synthesis and characterization of Fe0/TiO2 nano-composites for ultrasound assisted enhanced catalytic degradation of reactive black 5 in aqueous solutions”, J. Colloid Interface Sci., Vol. 506, (2017), pp. 403–414.

      [10] Nemati A, Shadpour S, Khalafbeygi H & Barkhi M, “Hydrothermal Synthesis and Size Control of Fe3O4 Nanoparticles in the Presence of 2,2’,2”,2”′-(ethane-1,2-diylbis(azanetriyl))tetraacetohydrazide”, Synth. React. Inorganic, Met. Nano-Metal Chem., Vol. 44, No. 8, (2014), pp. 1161–1165.

      [11] Eivari HA & Rahdar A, “Some Properties of Iron Oxide Nanoparticles Synthesized in Different Conditions”, World Appl. Program., Vol. 3, No. 2, (2013), pp. 52–55.

      [12] R. P. Singh, “Prospects of Organic Conducting Polymer Modified Electrodes: Enzymosensors”, Int. J. Electrochem., Vol. 202, (2012), pp. 1–14.

      [13] Nene AG, Takahashi M & Somani PR, “Fe3O4 and Fe Nanoparticles by Chemical Reduction of Fe ( acac ) 3 by Ascorbic Acid : Role of Water”, No.4, (2016), pp. 20–28.

      [14] Farias-Mancilla R, Elizalde-Galindo JT, Vigueras-Santiago E, Hernández-Escobar CA, Vega-Rios A & Zaragoza-Contreras EA, “Synthesis and Characterization of Polyaniline/Magnetite Nanocomposite”, Avestia Publ. Int. J. Theor. Appl. Nanotechnol. J., Vol. 4, (2016), pp. 1929–1248.

      [15] [15] Holland H & Yamaura M, “Synthesis of Magnetite Nanoparticles by Microwave Irradiation and Characterization”, Powder Technol., (2009).

      [16] Lopez JA, González F, Bonilla FA, Zambrano G & Gómez ME, “synthesis and characterization of Fe3O4 magnetic nanofluid”, Rev. Latinoam. Metal. y Mater., Vol. 30, No. 60, (2010), pp. 60–66.

      [17] McCarthy PA, Huang J, Yang SC & Wang HL, “Synthesis and characterization of water-soluble chiral conducting polymer nanocomposites”, Langmuir, Vol. 18, No. 1, (2002), pp. 259–263.

      [18] Shaker S, Zafarian S, Chakra CS & Rao KV, “Preparation and characterization of magnetite nanoparticles by sol-gel method for water treatment,” Int. J. Innov. Res. Sci. Eng. Technol., Vol. 2, No. 7, (2013), pp 144-152.

      [19] Cao P, Mangadlao JD & Advincula RC, “Stimuli-Responsive Polymers and their Potential Applications in Oil-Gas Industry,” No. August, (2015).

      [20] Lu X, Mao H, Chao D, Zhang W & Wei Y, “Ultrasonic synthesis of polyaniline nanotubes containing Fe3O4 nanoparticles”, Vol. 179, (2006), pp. 2609–2615.

      [21] Jamshidiyan M, Shirani AS & Alahyarizadeh G, “Solvothermal synthesis and characterization of magnetic Fe3O4 nanoparticle by different sodium salt sources,” Mater. Sci., Vol. 35, No. 1, (2017), pp. 50–57.

      [22] Lu X et al., “Aniline dimer-COOH assisted preparation of well-dispersed polyaniline-Fe3O4 nanoparticles”, Nanotechnology, Vol. 16, No. 9, (2005), pp. 1660–1665.




Article ID: 22108
DOI: 10.14419/ijet.v7i4.30.22108

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