Biomorphic Silicon Carbide from Malaysian Hardwood

  • Authors

    • Noor Leha Abdul Rahman
    • Koay Mei Hyie
    • Anizah Kalam
    • Fauziah Md Yusof
    2018-11-30
    https://doi.org/10.14419/ijet.v7i4.26.22178
  • biomorphic SiC, Kapur, dark red Meranti, infiltration, flexure strength
  • Porous silicon carbide with mimicking the original microstructure of wood are prepared by pyrolysis and subsequently impregnated with silicon by silicon melt infiltration. The infiltration process was performed at 1500 °C for 3 hours holding times in inert atmosphere. Two types of wood were used as precursor which is Kapur and dark red Meranti.The morphology of resulting porous SiC have been investigated using scanning electron microscope (SEM/EDX) and X-ray diffraction (XRD) analysis. The density of the samples was characterized by Archimedes methods. The excess of silicon was removed by etching with the mixture of hydrofluoric and nitric acid. The flexural strength was tested by the three-point flexural method at room temperature.It has been shown that the final SiC for both precursors have similar density. The existence of SiC was proved by the XRD result, whereas EDX analysis of silicon content revealed that the formation of silicon carbide in dark red Meranti is higher than that of Kapur. The flexural strength and modulus of dark red Meranti samples were much higher than those of the kapur samples because of higher formation of silicon carbide in dark red Meranti.

     

     

  • References

    1. [1] zaini md Nor, “solid waste management in malaysia,†in International Conference On Urban Development And Management, 2010, http://www.swcorp.gov.my/docfile/kertas-taklimat/SWMPresentationOktober.pdf

      [2] L. A. Manaf, M. Armi, A. Samah, N. Ilyana, and M. Zukki, “Municipal solid waste management in Malaysia : Practices and challenges,†vol. 29, pp. 2902–2906, 2009.

      [3] Y. Moh and L. A. Manaf, “Resources , Conservation and Recycling Solid waste management transformation and future challenges of source separation and recycling practice in Malaysia,†"Resources, Conserv. Recycl., vol. 116, pp. 1–14, 2017.

      [4] O. P. Chakrabarti, H. S. Maiti, and R. Majumdar, “Biomimetic synthesis of cellular SiC based ceramics from plant precursor,†Bull. Mater. Sci., vol. 27, no. 5, pp. 467–470, 2004.

      [5] P. Greil, “Biomorphous ceramics from lignocellulosics,†J. Eur. Ceram. Soc., vol. 21, no. 2, pp. 105–118, 2001.

      [6] T. Conners, “Introduction to Wood Structure and Characteristics,†1914.

      [7] B. L. R. A, “Carbonization Of Wood At 400 ° C For Composite Materials,†state universisty of new york, 2011.

      [8] C. E. B. and D. C. NAGLE, “Wood monoliths-characterization,†vol. 35, no. 2, pp. 267–273, 1997.

      [9] J. Locs, L. Berzina-Cimdina, a. Zhurinsh, and D. Loca, “Effect of processing on the microstructure and crystalline phase composition of wood derived porous SiC ceramics,†J. Eur. Ceram. Soc., vol. 31, no. 1–2, pp. 183–188, Jan. 2011.

      [10] Z. L. Yan, J. Liu, J. C. Zhang, T. Ma, and Z. C. Li, “Comparative Study of Biomorphic Silicon/Silicon Carbide Ceramic from Birch and Compressed Birch,†Key Eng. Mater., vol. 434–435, pp. 609–612, Mar. 2010.

      [11] F. M. Varela-Feria, J. Ramírez-Rico, A. R. de Arellano-López, J. Martínez-Fernández, and M. Singh, “Reaction–formation mechanisms and microstructure evolution of biomorphic SiC,†J. Mater. Sci., vol. 43, no. 3, pp. 933–941, 2008.

      [12] M. Presas, J. Y. Pastor, J. Llorca, a. R. A. López, J. M. Fernández, and R. Sepúlveda, “Microstructure and fracture properties of biomorphic SiC,†Int. J. Refract. Met. Hard Mater., vol. 24, no. 1–2, pp. 49–54, 2006.

      [13] J. Qian, J. Wang, and Z. Jin, “Preparation of biomorphic SiC ceramic by carbothermal reduction of oak wood charcoal,†Mater. Sci. Eng. A, vol. 371, no. 1–2, pp. 229–235, Apr. 2004.

      [14] P. Greil, T. Lifka, and A. Kaindl, “Biomorphic cellular silicon carbide ceramics from wood: II. Mechanical properties,†J. Eur. Ceram. Soc., vol. 18, no. 14, pp. 1975–1983, 1998.

      [15] H. S. Park, J. J. Jang, K. H. Lee, K. H. Lim, S. B. Park, Y. C. Kim, and S. H. Hong, “Effects of microstructure on flexural strength of biomorphic C/SiC composites,†Int. J. Fract., vol. 151, no. 2, pp. 233–245, 2008.

      [16] E. Vogli, H. Sieber, and P. Greil, “Biomorphic SiC-ceramic prepared by Si-vapor phase infiltration of wood,†J. Eur. Ceram. Soc., vol. 22, no. 14–15, pp. 2663–2668, 2002.

      [17] S. D. W. and P. S.s, “Silicon/Silicon Carbide composites fabricated by infiltration of a Silicon Melt into Charcoal,†J.Am.Ceram.Soc, vol. 82, 1999.

      [18] P. . B. Menon, structure & Indentification of Malayan wood. fores research institut malaysia, 1971.

      [19] C. E. Byrne and D. C. Nagle, “Carbonization of wood for advancedmaterials applications,†Carbon N. Y., vol. 35, no. 2, pp. 259–266, 1997.

      [20] F. . Varela-Feria, J. MartıÌnez-Fernández, a. . de Arellano-López, and M. Singh, “Low density biomorphic silicon carbide: microstructure and mechanical properties,†J. Eur. Ceram. Soc., vol. 22, no. 14–15, pp. 2719–2725, 2002.

      [21] N. R. Calderon, M. Martinez-Escandell, J. Narciso, and F. Rodríguez-Reinoso, “The role of carbon biotemplate density in mechanical properties of biomorphic SiC,†J. Eur. Ceram. Soc., vol. 29, no. 3, pp. 465–472, Feb. 2009.

      [22] H. S. Park, J. J. Jang, K. H. Lee, K. H. Lim, S. B. Park, Y. C. Kim, and S. H. Hong, “Effects of microstructure on flexural strength of biomorphic C / SiC composites,†pp. 233–245, 2008.

      [23] A. Fernandez, A. Saffe, R. Pereyra, G. Mazza, and R. Rodriguez, “Kinetic study of regional agro-industrial wastes pyrolysis using non-isothermal TGA analysis,†Appl. Therm. Eng., vol. 106, pp. 1157–1164, 2016.

      [24] “Production And Characterization Of Carbon StructureS,†2008.

      [25] J. C. Margiotta, “Study Of Silicon Carbide Formation By Liquid Silicon Infiltration Of Porous Carbon Structures,†2009.

      [26] A. Esther and S. Childers, “Processing , Microstructure , and Mechanical Properties of Interpenetrating Biomorphic Graphite / Copper Composites,†no. August, 2014.

      [27] C. Torres-Raya, D. Hernandez-Maldonado, J. Ramirez-Rico, C. Garcia-Gañan, A. R. de Arellano-Lopez, and J. Martinez-Fernandez, “Fabrication, chemical etching, and compressive strength of porous biomimetic SiC for medical implants,†J. Mater. Res., vol. 23, no. 12, pp. 3247–3254, 2008.

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    Leha Abdul Rahman, N., Mei Hyie, K., Kalam, A., & Md Yusof, F. (2018). Biomorphic Silicon Carbide from Malaysian Hardwood. International Journal of Engineering & Technology, 7(4.26), 257-261. https://doi.org/10.14419/ijet.v7i4.26.22178