Adsorption Study of Malachite Green Dye of New Schiff Base Liquid Crystal Surface (Thermodynamic and Kinetic)

  • Authors

    • Adraa Abdul Kadhim Wasaf AL-Fatlawy
    • . .
    2018-12-09
    https://doi.org/10.14419/ijet.v7i4.36.24228
  • Schiff basis, liquid crystal, adsorption, isotherm, kinetic.

  • Abstract

    This work incorporates blends of new heterocyclic mixes of (2-amino-6-methoxy benzothiazole), from response with (p-hydroxybenzaldehyde) to yield Schiff bases, the compound have been distinguished (FT-IR ,HNMR) the misomorphic stages were recognized by energized light magnifying lens (POM) and estimated change temperatures for compound by differrntion checking calorimeter (DSC) at that point investigation of fluid precious stone properties and we will contemplate the adsorption of malachite green color on this fluid gem as a surface. Likewise The examination incorporated the trial of applying the isotherm models of Langmuir, Freundlich, harkinsjura and Temkin to the handy adsorption information of the color under investigation utilizing the UV spectroscopy. The active information were demonstrated by utilizing pseudo-first-arrange, pseudo-second-request, Elovich and intra-molecule dispersion energy conditions, Adsorption adsorbents were additionally used to get the estimations of the thermodynamic capacities (Free vitality ∆G, enthalpy ∆H, and ∆S entropy and actuation vitality).

     

  • References

    1. [1] Richard AH & Ferrier RD, Biochemistry Lippincott’s Illustrated Reviews, (2010), pp.235-242.

      [2] Guyton A & Hall J, Textbook of medical physiology, 11th edition, (2006).

      [3] DÄ…browski A, “Adsorption—from theory to practiceâ€, Advances in colloid and interface science, Vol.93, No.1-3, (2001), pp.135-224.

      [4] Sridevi C, “Designing New Vanillin Schiff Bases and their Antibacterial Studiesâ€, Journal of Medical and Bioengineering, Vol.4, No.5, (2014), pp.363-366.

      [5] Haddad HH, “A New Schiff Base Derivatives Designed to Bind Metal Ion (Cu, Co): Thermodynamics and Biological Activity Studiesâ€, American Journal of Analytical Chemistry, Vol.7, No.5, (2016), pp.446-451.

      [6] Silverstein RM, Webster FX & Kiemle DJ, Spectrometric Identification of Organic compounds, 7thed, John Wiley and sons Inc, New York, (2005).

      [7] Pavia DN, Lampman GM & Kriz GS, Introduction to spectroscopy, 3thed,Thomson Learning, Inc, United states of Hanaa Hameed Haddad America, (2001).

      [8] Ishaq M, Saeed K, Ahmad I & Sultan S, “Coal Ash as a Low Cost Adsorbent for the Removal of Xylenol Orange from Aqueous Solution Iranâ€, J. Chem. Chem. Eng., Vol.33, No.1, (2014), pp.53-58.

      [9] BaÅŸar CA, “Applicability of the various adsorption models of three dyes adsorption onto activated carbon prepared waste apricotâ€, Journal of Hazardous Materials, Vol.135, No.1-3, (2006), pp.232-241.

      [10] Shouman MA & Khedr, SAA, “Removal of Cationic Dye from Aqueous Solutions by Modified Acid-Treated Pomegranate Peels (PUNICA GRANATUM): Equilibrium and Kinetic Studiesâ€, Asian J. of App. Sci., Vol.3, No.4, (2015), pp.574-588.

      [11] Hamdaoui O & Naffrechoux E, “Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon: Part I. Two-parameter models and equations allowing determination of thermodynamic parametersâ€, Journal of Hazardous materials, Vol.147, No.1-2, (2007), pp.381-394.

      [12] Freundlich HMF, “Over the Adsorption in Solutionâ€, Journal of Physical Chemistry, Vol.57, (1906), pp.385-471.

      [13] Temkin MJ & Pyzhev V, “Recent Modifications to Langmuir Isothermsâ€, Acta Physiochim URSS, Vol.12, (1940), pp.217- 225.

      [14] Hasan SA, Kadhm LH, Husain ZN & Tuaima AA, “Utilization of cement kiln dust f for removal of some water-soluble dyesâ€, Eur. J. of sci. Res., Vol.93, No.1, (2012), pp.113-124.

      [15] Langergren S & Svenska BK, “Zur theorie der sogenannten adsorption geloester stoffeâ€, Veternskapsakad Handlingar, Vol.24, No.4, (1898), pp.1-39.

      [16] Ho YS & McKay G, “Sorption of dye from aqueous solution by peatâ€, Chemical engineering journal, Vol.70, No.2, (1998), pp.115-124.

      [17] Weber WJ & Morris JC, “Advances in water pollution researchâ€, First International Conference on Water Pollution Research, Vol.2, (1962), pp.235-266.

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  • How to Cite

    Abdul Kadhim Wasaf AL-Fatlawy, A., & ., . (2018). Adsorption Study of Malachite Green Dye of New Schiff Base Liquid Crystal Surface (Thermodynamic and Kinetic). International Journal of Engineering & Technology, 7(4.36), 713-717. https://doi.org/10.14419/ijet.v7i4.36.24228

    Received date: 2018-12-18

    Accepted date: 2018-12-18

    Published date: 2018-12-09