Synthesis and Physiochemical Properties of Zinc Layered Hydroxide-Cinnamate

  • Abstract
  • Keywords
  • References
  • PDF
  • Abstract

    The intercalations of cinnamic acid into zinc layered hydroxide were synthesized by using simple direct method due to the less usage used and simple preparation steps. The physiochemical studies were done to determine the ability of zinc layered hydroxide to traps cinnamic acid in between its interlayer region. The FTIR shows new generation of peak such as OH group, C=O, C=C, C-O and trans C=C at 3379 cm-1, 1643 cm-1, 1578cm-1,1253 cm-1 and 873 cm-1, and increases in basal spacing at 22.06Ǻ indicate the intercalations of cinnamic acid into the zinc layered hydroxide were presence. The morphological surfaces show new changes toward the surfaces of the intercalated compounds.


  • Keywords

    cinnamic acid; cinnamate; intercalation; layered hydroxide salts; zinc layered hydroxide

  • References

      [1] Chisvert A & Salvador A (2007), UV filters in sunscreens and other cosmetics: Regulatory aspects and analytical methods, Analysis of Cosm Prod., pp.83-120.

      [2] Giokas DL, Salvador A & Chisvert A (2007), UV filters: From sunscreens to human body and the environment. TrAC Trends in Analytical Chemistry, Vol.26, No.5, pp.360-374.

      [3] Cursino ACT, Gardolinski JEF, Bezdicka P & Fernando W (2010), Intercalation of anionic organic ultraviolet ray absorber into layered zinc hydroxide nitrate, Journal of Colloid and Interface Science Vol.347, No.1, pp.49-55.

      [4] Demel J, Plestil J, Bezdicka P, Janda P, Klementova M & Lang K (2011), Layered zinc hydroxidesalts: Delamination, preferred orientation of hydroxide lamellae, and formation of ZnO nanodisc, Journal of Colloid and Interficial Science, Vol.360, No.2, pp.532–539.

      [5] Cursino ACT, Rives V, Arizaga GGC, Trujillano R & Wypych F (2015), Rare earth and zinc layered hydroxide salts intercalated with the 2-aminobenzoate anion as organic luminescent sensitizer, Material Research Bulletin, Vol.70, pp.336–342.

      [6] Del Hoyo C (2007), Layered double hydroxides and human health: An overview, Applied Clay Scienc. Vol.36, Issues 1-3, pp.103–121.

      [7] Ahmad R, Hussein MZ, Sarijo SH, Kadir WRWA & Hin TY (2016), Synthesis and characteristics of vopaleric acid-zinc layered hydroxide intercalation material for insect pheromone controlled release formulation, Journal of Materials, pp.1–9.

      [8] Machovsky M, Kuritka I, Sedlak J & Pastorek M (2013), Hexagonal ZnO porous plates prepared from microwave synthesized layered zinc hydroxide sulphate via thermal decomposition, Material Research Bulletin, Vol.48, No.10, pp.4002–4007.

      [9] Li S, Shen Y, Xiao M, Liu D, Fa L & Wu K (2014), Intercalation of 2, 4-dihydroxybenzophenone-5-sulfonate anion into Zn / Al layered double hydroxides for UV absorption properties, Journal of Industrial and Engineering Chemistry, Vol.20, No.4, pp.1280–1284.

      [10] Marangoni R, Bouhent M, Taviot-guého C, Wypych F & Leroux F (2009), Zn2Al layered double hydroxides intercalated and adsorbed with anionic blue dyes: A physico-chemical characterization, Journal of Colloid and Interface Science, Vol.333,Vol.1, No.1, pp.120–127.

      [11] Chauhan A & Chauhan P (2014), Powder XRD technique and its applications in science and technology, Journal of Analytical and Bioanalytical Technique, Vol.5, No.5, pp.1–5.

      [12] Jaafar AM, Anuar AN, Hashim N & Ayob FH (2016), Intercalation study of curcumin into zinc layered hydroxide. Malaysian Journal of Analytical Science, Vol.20, No.6, pp.1359–1364.

      [13] Mohsin SMN, Hussein MZ, Sarijo SH, Fakurazi S, Arulselvan P & Hin TY (2013), Synthesis of (cinnamate-zinc layered hydroxide) intercalation compound for sunscreen application, Chemistry Central Journal, Vol.7, No.26, pp.1–12.




Article ID: 25568
DOI: 10.14419/ijet.v7i4.42.25568

Copyright © 2012-2015 Science Publishing Corporation Inc. All rights reserved.