Performance of Piper Nigrum (Black Pepper) as Corrosion Inhibitor of Ductile Iron

  • Authors

    • Mohd Faizul Idham
    • Mohamad Fathmi Masor
    • Norzila Mohd
    • Bulan Abdullah
    • Siti Khadijah Alias
    2018-12-29
    https://doi.org/10.14419/ijet.v7i4.42.25691
  • Corrosion, Ductile Iron, Gravimetric Test, Green Corrosion Inhibitor, Piper Nigrum
  • Abstract

    The effectiveness of Piper Nigrum as green corrosion inhibitor towards ductile iron in 1M Sodium Hydroxide was studied. Piper Nigrum, also known as black pepper had undergone extraction process in order to get the final product in the form of liquid which acted as inhibitor. The sample of this inhibitor was analyzed by Fourier Transform Infrared Spectroscopy (FTIR) in determining the bonding and the functional group of the inhibitor. Meanwhile, the capability of Piper Nigrum to inhibit corrosion was tested based on concentration of inhibitors by using the gravimetric method. Ductile iron was exposed to 1M Sodium Hydroxide which acted as corrosive medium and inhibitor concentration of 0.1, 0.2 and 0.3 g/L respectively for three hours at constant temperature of 50°C. In addition, there was one ductile iron which was exposed to 1M Sodium Hydroxide in the absence of inhibitor. The ductile iron was then visualized by the microstructure observation through microscope. As a result, FTIR had indicated that the presence of hetero atoms in alkaloids Piperine made Piper Nigrum to have an ability to inhibit corrosion. Besides, Piper Nigrum could achieve maximum inhibition efficiency of 97.97% while the corrosion rate was only 0.8059 mm/year at 0.3 g/L inhibitor. Furthermore, the concentration of inhibitor gave insignificant effect on the microstructure. However, the morphology of ductile iron microstructure had shown slight difference when the ductile iron was immersed in higher concentration of inhibitor. This had proved that the higher concentration of inhibitor, the less corrosion occurred.

     

     

     
  • References

    1. [1] Budi AK, Andhi P, Sulistijono H, & Sutarsis (2014). Study on ginger extract performance as corrosion inhibitor in acid and neutral environments, Advanced Materials Research, 896, pp. 331-334.

      [2] Rosaline JV, Leema AR, & Raja S (2012). A study on the phytochemical analysis and corrosion inhibition on mild steel by Annona Muricata.L leaves extract in 1 N hydrochloric acid, Pelagia Research Library, 3(3), pp. 582-588.

      [3] Aprael SY, Anees AK & Rafal KW (2013). Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid, Alexandria Engineering Journal, 52, pp. 129-135.

      [4] Murlidhar M & Goswami TK (2012). Chemical composition, nutritional, medicinal and functional properties, Open Access Scientific Reports, 1(2), pp. 1-5

      [5] Norzila M, Honey MI, & Nursyafinaz J. (2014). Corrosion inhibition of aluminum in 0.1m hcl by nephelium lappaceum (rambutan) peel extract, Applied Mechanics and Materials, 661, pp. 14-20.

      [6] Singh A & Vinod KS. (2013). Quraishi MA, Inhibition of mild steel corrosion in hcl solution using pipali (Piper longum) fruit extract, Arab J Sci Eng, 38, pp. 85–97.

      [7] Vinod KKP, Sankara M, Narayanan P, Rexin TG. (2011). Green corrosion inhibitor from seed extract of Areca catechu for mild steel in hydrochloric acid medium, Springer, 46, pp. 5208–5215.

      [8] Gopal J, Shadma A, Shanthi S, & Rajiv P. (2015). Musa paradisica peel extract as green corrosion inhibitor for mild steel in HCl solution, Corrosion Science, 90, pp. 107-117.

      [9] Chuan L, Xeuming L, Daixiong Z, Zhen X, Wenjing Y, Xiaongang G. (2014). Fabrication and corrosion behavior of fresh porous silicon in sodium hydroxide solution. Science Direct, 144, pp. 355-360.

      [10] Manoj A, Jinendra SC, Anita D, & Gupta DK. (2013). Green inhibitors for prevention of metal and alloys corrosion: An overview, Chemistry and Materials Research, 3(6), pp.16-24.

      [11] Rahuma MR, Amer H, & Alfergani M (2014). Corrosion inhibition of mild steel in 11% hydrochloric acid, Chemical Science Transactions, 7, pp.3434-3443.

      [12] Punita M, Sitashree B, & Singh MM, (2014). Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor, Corrosion Science, 85, pp. 352-363.

      [13] Oke PK & Ukoba OK. (2013). Analysis of corrosion growth of ductile iron in different environments. Advanced Materials Research, pp. 327-331.

      [14] Bulan A, Khadijah SA, Ahmed J, Hayati NS, Idham MF, & Abdullah R. (2012). XRD evidence for phase structures of niobium alloyed austempered, Advanced Materials Research, 457-458, pp. 431-434.

      [15] Abdullah B, Idham MF, Jaffar A, Zubair AF, & Mazlan M. (2013). Effect of two-cycle heat treatment on mechanical properties of ductile. Applied Mechanics and Materials, 393(79-82). September 2013.

      [16] Idham MF. (2013). Investigation on phases transformation and mechanical properties of ductile iron by new heat treatment process, MSc Thesis.

  • Downloads

  • How to Cite

    Faizul Idham, M., Fathmi Masor, M., Mohd, N., Abdullah, B., & Khadijah Alias, S. (2018). Performance of Piper Nigrum (Black Pepper) as Corrosion Inhibitor of Ductile Iron. International Journal of Engineering & Technology, 7(4.42), 115-118. https://doi.org/10.14419/ijet.v7i4.42.25691

    Received date: 2019-01-11

    Accepted date: 2019-01-11

    Published date: 2018-12-29