Solar Photocatalytic Degradation of Food Dye (Tartrazine) using Zinc Oxide Catalyst

  • Authors

    • Muhammad Nasri Abdul Rahman
    • Nor Aireen Abd Rahim
    • Wan Farahiyah Wan Kamarudin
    • Zildawarni Irwan
    • Abd Rahman Mat Amin
    • Adida Muhammud
    • Siti Munirah Muda
    • Noor Erni Fazlina Mohd. Akhir
    2018-12-29
    https://doi.org/10.14419/ijet.v7i4.42.25719
  • Solar Photocatalytic, Tartrazine, Food Dyes, Wastewater treatment, catalyst Zinc Oxide
  • Abstract

    Food dyes are used in food processing industries as coloring and additive so that the food can be stored for a long time. The effluent discharged from the industries has become a serious issue as it can cause water pollution. Solar photocatalytic degradation was widely used to degrade most of the dyes in wastewater due to its high effectiveness. The main objective of this study was to investigate the effectiveness of degradation of Tartrazine using the photocatalytic process by using ZnO as photocatalyst and sunlight as the irradiation source. This study also was conducted to compare the percentage degradation of Tartrazine at different conditions which are amount of catalyst, pH of dye solution, exposure time and presence and absence of sunlight and photocatalyst. The degradation of Tartrazine was analyzed by using UV-Vis spectrophotometer. A laboratory set-up was designed to evaluate the optimum weight of ZnO, optimum pH of Tartrazine solutions, optimum time exposure and also was operated in the presence of ZnO as photocatalyst and sunlight as the irradiation source. The result showed that, the photocatalytic degradation of Tartrazine proved to be effective under solar radiation by using ZnO as photocatalyst. The optimum photodegradation occurred at optimum weight of ZnO, pH of Tartrazine and time of radiation. The optimum weight of ZnO was 20 mg, and the optimum pH of Tartrazine solution was pH 6. The most effective condition for photodegradation of Tartrazine was degradation with ZnO catalyst and with solar radiation. The radiation time was 1 hour with (93.91±0.57) % degradation. The formation of OH∙ required both the presence of catalyst and solar radiation.

     

     

  • References

    1. [1] Ghimpusan, M., Nechifor, G., Nechifor, A. C., Dima, S. O., & Passeri, P. (2017). Case studies on the physical-chemical parameters' variation during three different purification approaches destined to treat wastewaters from food industry. Journal of environmental management, 203, 811-816.

      [2] Ullah, I., Ali, S., & Akram, M. (2013). Degradation of Reactive Black B dye in wastewater using oxidation process. International Journal of Chemical and Biochemical Sciences, 4, 96-100.

      [3] Tikhomirova, T. I., Ramazanova, G. R., & Apyari, V. V. (2017). A hybrid sorption–spectrometric method for determination of synthetic anionic dyes in foodstuffs. Food chemistry, 221, 351-355.

      [4] Moutinho, I. L. D., Bertges, L. C., & Assis, R. V. C. (2007). Prolonged use of the food dye tartrazine (FD&C yellow n° 5) and its effects on the gastric mucosa of Wistar rats. Brazilian journal of biology, 67(1), 141-145.

      [5] Ong, C. B., Mohammad, A. W., Rohani, R., Ba-Abbad, M. M., & Hairom, N. H. H. (2016). Solar photocatalytic degradation of hazardous Congo red using low-temperature synthesis of zinc oxide nanoparticles. Process Safety and Environmental Protection, 104, 549-557.

      [6] Han, F., Kambala, V. S. R., Srinivasan, M., Rajarathnam, D., & Naidu, R. (2009). Tailored titanium dioxide photocatalysts for the degradation of organic dyes in wastewater treatment: a review. Applied Catalysis A: General, 359(1-2), 25-40.

      [7] Abe, F. R., Mendonça, J. N., Moraes, L. A., de Oliveira, G. A., Gravato, C., Soares, A. M., & de Oliveira, D. P. (2017). Toxicological and behavioral responses as a tool to assess the effects of natural and synthetic dyes on zebrafish early life. Chemosphere, 178, 282-290.

      [8] Gautam, R. K., Gautam, P. K., Banerjee, S., Rawat, V., Soni, S., Sharma, S. K., & Chattopadhyaya, M. C. (2015). Removal of tartrazine by activated carbon biosorbents of Lantana camara: kinetics, equilibrium modeling and spectroscopic analysis. Journal of Environmental Chemical Engineering, 3(1), 79-88.

      [9] Zazouli, M. A., Ghanbari, F., Yousefi, M., & Madihi-Bidgoli, S. (2017). Photocatalytic degradation of food dye by Fe3O4–TiO2 nanoparticles in presence of peroxymonosulfate: The effect of UV sources. Journal of environmental chemical engineering, 5(3), 2459-2468.

      [10] Ozturk, B., & Soylu, G. S. P. (2016). Promoting role of transition metal oxide on ZnTiO3–TiO2 nanocomposites for the photocatalytic activity under solar light irradiation. Ceramics International, 42(9), 11184-11192.

      [11] Reza, K. M., Kurny, A. S. W., & Gulshan, F. (2017). Parameters affecting the photocatalytic degradation of dyes using TiO 2: a review. Applied Water Science, 7(4), 1569-1578.

      [12] Mariselvam, R., Ranjitsingh, A. J. A., Mosae Selvakumar, P., Alarfaj, A. A., & Munusamy, M. A. (2016). Spectral studies of UV and solar photocatalytic degradation of AZO dye and textile dye effluents using green synthesized silver nanoparticles. Bioinorganic chemistry and applications, 2016.

      [13] Gupta, V. K., Jain, R., Nayak, A., Agarwal, S., & Shrivastava, M. (2011). Removal of the hazardous dye—tartrazine by photodegradation on titanium dioxide surface. Materials Science and Engineering: C, 31(5), 1062-1067.

      [14] Chakrabarti, S., & Dutta, B. K. (2004). Photocatalytic degradation of model textile dyes in wastewater using ZnO as semiconductor catalyst. Journal of hazardous materials, 112(3), 269-278.

      [15] Hashim, H. A. A., Mohamed, A. R., & Teong, L. K. (2001). Solar photocatalytic degradation of tartrazine using titanium dioxide. Jurnal Teknologi, 35, 31-40.

      [16] Chen, X., Wu, Z., Liu, D., & Gao, Z. (2017). Preparation of ZnO photocatalyst for the efficient and rapid photocatalytic degradation of azo dyes. Nanoscale research letters, 12(1), 143.

      [17] Danwittayakul, S., Jaisai, M., & Dutta, J. (2015). Efficient solar photocatalytic degradation of textile wastewater using ZnO/ZTO composites. Applied Catalysis B: Environmental, 163, 1-8.

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  • How to Cite

    Nasri Abdul Rahman, M., Aireen Abd Rahim, N., Farahiyah Wan Kamarudin, W., Irwan, Z., Rahman Mat Amin, A., Muhammud, A., Munirah Muda, S., & Erni Fazlina Mohd. Akhir, N. (2018). Solar Photocatalytic Degradation of Food Dye (Tartrazine) using Zinc Oxide Catalyst. International Journal of Engineering & Technology, 7(4.42), 222-226. https://doi.org/10.14419/ijet.v7i4.42.25719

    Received date: 2019-01-11

    Accepted date: 2019-01-11

    Published date: 2018-12-29