The Effect of MAPP Compatibilizing Agent on the Mechanical and Thermal Properties of Polypropylene/PLA Blends
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2019-12-24 https://doi.org/10.14419/ijet.v7i4.14.27675 -
Coupling Agent, Extrusion, Mechanical Properties, Polylactic Acid, Polymer Blends, -
Abstract
In this study, the polymer blends were prepared in the ratios of Polypropylene (PP) to Polylactic acid (PLA) of 70:30 by weight. Maleic anhydride-grafted polypropylene (MAPP) was used as a coupling agent to improve the compatibility between PP and PLA. The MAPP was added into the blend in the ratio of 0, 3, 6 and 9% wt. The polymer blends were prepared by extrusion process using twin screw extruder. The effects of MAPP content on the mechanical and thermal properties of PP/PLA blend were investigated. The result of tensile strength shows no significant increased with the addition of MAPP content. However, Young modulus and Izod impact strength shows significantly increased with the addition of MAPP content. Tensile modulus increased up to 43% with the addition of 6% wt. MAPP. TGA results show that blending PP with PLA cause increased the thermal stability of PLA. The incorporation of 6 % MAPP has shifted the initial weight loss of PP component towards lower temperature.
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References
[1] Byun Y, Kim YT & Whiteside S (2010), Characterization of an antioxidant polylactic acid (PLA) film prepared with a-tocopherol, BHT and polyethylene glycol using film cast extruder. J Food Eng 100: 239–244.
[2] Ivan N-B, Valentini S, Franco D, Luigi T, Jose MK, & Laura P (2016) Design of biodegradable blends based on PLA and PCL: From morphological, thermal and mechanical studies to shape memory behavior. Polymer Degradation and Stability 132, 97-108.
[3] Lee SY, Kang IA, Doh GH, Kim WJ, Kim JS, Yoon HG & Wu Q, (2008), Thermal, mechanical and morphological properties of polypropylene/clay/wood flour nanocomposites. eXPRESS Polymer Letters 2(2),78-87.
[4] Bertini F, Canetti M, Audisio G, Costa G & Falqui L (2006), Characterization and thermal degradation of polypropylene–montmorillonite nanocomposites. Polym. Degrad. Stabil 91: 600-605.
[5] Nalin P, Panuwat S, Duangduen A & Chiravoot P (2014), Blend of polypropylene/poly(lactic acid) for medical packaging application: physicochemical, thermal, mechanical, and barrier properties. Energy Procedia 56, 201-210.
[6] Xiangdong W, Wei L, Hangquan L, Zhongjie D & Chen Z, (2014), Role of maleic-anhydridegrafted-polypropylene in supercritical CO2 foaming of poly (lactic acid) and its effect on cellular morphology. Journal of Cellular Plastics 52(1), 37–56.
[7] Min SK, Youn HK & Woo N K, (2010), Effects of Compatibilizers on the Mechanical Properties and Interfacial Tension of Polypropylene and Poly(lactic acid) Blends. Macromolecular Research. 18, 583-588.
[8] Teli MD & Desai PV (2016), Effect of maleic anhydride grafted polypropylene compatiblizer in enhancing the properties of Polypropylene/ Poly lactic acid polyblend fibres. International Journal for Research in Applied Science & Engineering Technology (IJRASET) 4(5), 285-290.
[9] Sommai P-A, Jutamas K-S-A, Weraporn P-A, Rutchaneekorn W, Narongchai O-C, Sorapong P & Hiroyuki H, (2016), Effect of Compatibilizer on PLA/PP Blend for Injection Molding. Energy Procedia 89, 353 – 360.
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How to Cite
Z. Engku Zawawi, E., Z. Romli, A., F. Mat Suli, S., & Amirrudin Isnin, M. (2019). The Effect of MAPP Compatibilizing Agent on the Mechanical and Thermal Properties of Polypropylene/PLA Blends. International Journal of Engineering & Technology, 7(4.14), 361-364. https://doi.org/10.14419/ijet.v7i4.14.27675Received date: 2019-02-20
Accepted date: 2019-02-20
Published date: 2019-12-24