Biosynthesis of Zinc Oxide Nanoparticles for Corrosion Protection Application

 
 
 
  • Abstract
  • Keywords
  • References
  • PDF
  • Abstract


    The present study reports the successful synthesis of biosynthesized zinc oxide nanoparticles (ZnONPs). The Pandanus Amaryllifolius leaves extract was used as reducing agent with zinc nitrate hexahydrate as precursor. The effects of synthesis temperature on biosynthesis of ZnONP’s are discussed.  The biosynthesized ZnONPs were characterized by X-ray diffraction (XRD) ; and they were found to exhibit the hexagonal wurtzite structure. The diffractograms revealed well-defined, strong and sharp peaks at 2θ positions that correspond to its crystallinity with average size of 16.25 nm. Micrograph images from Field Emission Scanning Electron Microscope (FESEM) have shown polydispersed spherical shape of the biosynthesized ZnONPs. Smaller grain sizes were produced at low synthesis temperature of 60ºC. The elemental composition analysis confirmed the presence of zinc and oxygen by Energy Dispersive X-ray (EDX). The corrosion inhibition efficiency of mild steel in 1.0 M hydrochloric acid (HCl) solution was determined by weight loss method. Of significance, good corrosion inhibition efficiency of 79.43% was obtained by incorporating the biosynthesized ZnONP’s at synthesis temperature of 60ºC.

     

     



  • Keywords


    Zinc oxide nanoparticles, corrosion protection, mild steel, biosynthesis, Pandanus Amaryllifolius.

  • References


      [1] Rouhi, J., Mahmud, S., Naderi, N., Ooi, C.R., and Mahmood, M.R. (2013). Physical properties of fish gelatin-based bio-noncomposite

      [2] Ravindra P. Singh,V.K.(7March,2011).Biological approach of zinc oxide nanoparticles formation and its characterization. Advanced Materials Letters, 313-317.

      [3] Akhir, R. M., & Wahab, Z. A. (2015). Thermal diffusivity studies of ZnO-CuO at high temperatures. Jurnal Teknologi, 76(3), 19-23.

      [4] Beek, W. J., Wienk, M. M., & Janssen, R. A. (2004). Efficient hybrid solar cells from zinc oxide nanoparticles and a conjugated polymer. Advanced Materials, 16(12), 1009-1013

      [5] Vishwakarma, K.,(2013).Green synthesis of ZnO nanoparticles using Abrus precatorius seeds extract and their characterization, Thesis submitted to Department of life science for the partial fulfillment of the.

      [6] Vidya, C., Hiremath, S., Chandraprabha, M. N., Antonyraj, M. A. L., & Venu, I. (2013). Green synthesis of ZnO nanoparticles by Calotropis Gigantea, 2012–2014.

      [7] D.suresh- Suresh, D., Nethravathi, P. C., Rajanaika, H., Nagabhushana, H., & Sharma, S. C. (2015). Green synthesis of multifunctional zinc oxide (ZnO) nanoparticles using Cassia fistula plant extract and their photodegradative, antioxidant and antibacterial activities. Materials Science in Semiconductor Processing, 31, 446-454.

      [8] Senthilkumar, S. R., & Sivakumar, T. (2014). Innovare Academic Sciences Original Article Green Tea ( Camelia sinesis) mediated synthesis of zinc oxide (ZnO) nanoparticles and studied on their antimicrobial activities. International Journal of Pharmacy and Pharmaceutical Sciences, 6(6), 461–465.

      [9] GunalanSangeethaaSivarajRajeshwariaRajendranVenckateshb, Green synthesis of zinc oxide nanoparticles by aloe barbadensis miller leaf extract: Structure and optical properties, Materials Research Bulletin Volume 46, Issue 12, December 2011, Pages 2560-2566

      [10] Amit KumarMittalaYusufChistibUttam ChandBanerjeea , Synthesis of metallic nanoparticles using plant extracts, Biotechnology Advances, Volume 31, Issue 2, March–April 2013, Pages 346-356

      [11] NurulAin SamatabRoslanMd Nora , Sol–gel synthesis of zinc oxide nanoparticles using Citrus aurantifolia extracts, Ceramics International, Volume 39, Supplement 1, May 2013, Pages S545-S548

      [12] ShakeelAhmedaAnnuaSaif AliChaudhrybSaiqaIkrama , A review on biogenic synthesis of ZnO nanoparticles using plant extracts and microbes: A prospect towards green chemistry, Journal of Photochemistry and Photobiology B: Biology, Volume 166, January 2017, Pages 272-284

      [13] P.Ramesh , A.Rajendran , M.Meenakshisundaram , Green Syntheis of Zinc Oxide Nanoparticles Using Flower Extract Cassia Auriculata, Journal of nanoscience and nanotechnology, Vol 2 | Issue 1 | Spring Edition | DOI : February 2014 | Pp 41-45 |

      [14] S. Iravani Green synthesis of metal nanoparticles using plants Green Chem., 13 (2011), pp. 2638-2650

      [15] Sangeetha T, Venkatarathinakumar T, Sankari G (2011) Preliminary phytochemical investigation including HPTLC profile on aerial parts of Vernonia cinerea (L). Int. J. Pharm. Sci. Rev. Res. 11(2): 65-68

      [16] Bhuyan, T., Mishra, K., Khanuja, M., Prasad, R., & Varma, A. (2015). Biosynthesis of zinc oxide nanoparticles from Azadirachta indica for antibacterial and photocatalytic applications. Materials Science in Semiconductor Processing, 32, 55-61.

      [17] Stan, M., Popa, A., Toloman, D., Silipas, T. D., & Vodnar, D. C. (2016). Antibacterial and antioxidant activities of ZnO nanoparticles synthesized using extracts of Allium sativum, Rosmarinus officinalis and Ocimum basilicum. Acta Metallurgica Sinica (English Letters), 29(3), 228-236.

      [18] Mohammed A.Amin Sayed S.Abd El-RehimE.E.F.El-SherbiniRady S.Bayoumi, The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid: Part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies, Electrochimica Acta, Volume 52, Issue 11, 1 March 2007, Pages 3588-3600

      [19] Akhir, R. M., Fairuzi, A. A., & Ismail, N. H. (2015, August). Plant-mediated synthesis of biosilver nanoparticles using Pandanus amaryllifolius extract and its bactericidal activity. In AIP Conference Proceedings (Vol. 1674, No. 1, p. 020018). AIP Publishing.

      [20] Mirzaei, H., & Darroudi, M. (2017). Zinc oxide nanoparticles: Biological synthesis and biomedical applications. Ceramics International, 43(1), 907-914.

      [21] Tohma, H., Gülçin, İ., Bursal, E., Gören, A. C., Alwasel, S. H., & Köksal, E. (2017). Antioxidant activity and phenolic compounds of ginger (Zingiber officinale Rosc.) determined by HPLC-MS/MS. Journal of Food Measurement and Characterization, 11(2), 556-566.


 

View

Download

Article ID: 27775
 
DOI: 10.14419/ijet.v7i4.14.27775




Copyright © 2012-2015 Science Publishing Corporation Inc. All rights reserved.