Synthesis and Characterization of a Silver Nanoparticles-Reduced Graphene Oxide Nanohybrid by using ‘Zingiber Officinale’ Extract as a Reducing and Stabilizing Agent

  • Authors

    • Nurul Izrini Ikhsan
    • Nur Farahah Jaffar
    2019-12-24
    https://doi.org/10.14419/ijet.v7i4.14.27777
  • Use about five key words or phrases in alphabetical order, Separated by Semicolon.
  • An eco-friendly solution-based chemical approach has been used to prepare silver nanoparticles-reduced graphene oxide (AgNPs-rGO) nanohybrid using Zingiber officinale extract as a reducing and stabilizing agent. The products form a stable aqueous solution without any surfactant stabilizers and hence makes it possible to produce AgNPs-rGO nanohybrid on a large scale using low-cost solution processing technique. The nanohybrid was monitored at different concentration of GO solution (0.1 mg/ml, 0.5 mg/ml and 1.0 mg/ml) and characterized using UV- visible (UV-Vis) absorption spectrum, transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman spectroscopy analyses. From the UV-Vis analysis, the formation of silver nanoparticles (AgNPs) was confirmed and showed a surface plasmon resonance (SPR) absorption band at 420 nm for nanohybrids with GO concentration of 0.5 mg/ml. Raman spectra shows an increase in ID/IG ratio for rGO with values of 1.007 corresponding to the concentration of GO (0.5mg/ml) as compared to GO (0.88). Completely spherical Ag nanoparticles (NPs) were found at a nanohybrid with 0.5 mg/ml of GO with an average particle size of 20 nm. The AgNPs-rGO(0.5) nanohybrid exhibit fast electron-transfer kinetics for electrochemical reaction of Fe (CN)63-/4- redox couple, suggesting the potential applications for electrocatalysis and electrochemical sensor.

     

     


  • References

    1. [1] Pandikumar, A., Soon How, G. T., See, T. P., Omar, F. S., Jayabal, S., Kamali, K. Z., . . . Huang, N. M. (2014). Graphene and its nanocomposite material based electrochemical sensor platform for dopamine. RSC Adv., 4(108), 63296-63323.

      [2] Kumar, H., & Kumari, M. (2017). Synthesis, Characterization, and Antibacterial Study of Zinc Oxide-Graphene Nanocomposites. Asian Journal of Pharmaceutical and Clinical Research, 10(9), 206.

      [3] S.S. Maktedar, G. Avashthi, M. Singh, Ultrasound assisted simultaneous reduction and direct functionalization of graphene oxide with thermal and cytotoxicity profile, Ultrason. Sonochem. 34 (2017) 856–864.

      [4] S.S. Mehetre, S.S. Maktedar, Man Singh, Understanding the mechanism of surfacemodification through enhanced thermal and electrochemical stabilities of N- doped graphene oxide, Appl. Surf. Sci. 366 (2016) 514–522.

      [5] Gayatri Dhulappanavar, Basavaraj Hungund, & Ayachit, N. (2011). Characterization of Silver Nanoparticles Biosynthesized Using Lemon Juice.

      [6] P. Zhang, C. Shao, Z. Zhang, M. Zhang, J. Mu, Z. Guo, Y. Liu, In situ assembly of well-dispersed Ag nanoparticles (AgNPs) on electrospun carbon nanofibers (CNFs) for catalytic reduction of 4-nitrophenol, Nanoscale 3 (2011) 3357.

      [7] Rauwel, P., Küünal, S., Ferdov, S., & Rauwel, E. (2015). A Review on the Green Synthesis of Silver Nanoparticles and Their Morphologies Studied via TEM. Advances in Materials Science and Engineering, 2015, 1-9.

      [8] Rawat, M. (2016). A Review on Green Synthesis and Characterization of Silver Nanoparticles and Their Applications: A Green Nanoworld. World Journal of Pharmacy and Pharmaceutical Sciences, 730-762.

      [9] Ikhsan, N. I., Rameshkumar, P., & Huang, N. M. (2016). Controlled synthesis of reduced graphene oxide supported silver nanoparticles for selective and sensitive electrochemical detection of 4-nitrophenol. Electrochimica Acta, 192, 392–399.

      [10] Li, Y., Zhang, H., Wu, B., & Guo, Z. (2017). Improving the oxidation resistance and stability of Ag nanoparticles by coating with multilayered reduced graphene oxide. Applied Surface Science, 425, 194-200.

      [11] Novoselov KS, Geim SV, Morozov SV, Jiang D, Zhang Y, Dubonos SV, et al. Electric field effect in atomically thin carbon films. Science 2004;306(5696):666–9

      [12] Gayatri Dhulappanavar, Basavaraj Hungund, & Ayachit, N. (2011). Characterization of Silver Nanoparticles Biosynthesized Using Lemon Juice.

      [13] Balasooriya, E. R., Jayasinghe, C. D., Jayawardena, U. A., Ruwanthika, R. W. D., Mendis de Silva, R., & Udagama, P. V. (2017).

      [14] Jadhav, K., Dhamecha, D., Dalvi, B., & Patil, M. (2015). Green Synthesis of Silver Nanoparticles UsingSalacia chinensis: Characterization and its Antibacterial Activity. Particulate Science and Technology, 33(5), 445-455.

      [15] Bar, H., Bhui, D. K., Sahoo, G. P., Sarkar, P., De, S. P., & Misra, A. (2009). Green synthesis of silver nanoparticles using latex of Jatropha curcas. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 339(1-3), 134-139.N.

      [16] Huang, H. Lim, C. Chia, M. Yarmo and M. Muhamad, Int. J. Nanomed., 2011, 6, 3443

      [17] Ikhsan, N. I., Rameshkumar, P., & Huang, N. M. (2016). Controlled synthesis of reduced graphene oxide supported silver nanoparticles for selective and sensitive electrochemical detection of 4-nitrophenol. Electrochimica Acta, 192, 392–399.

      [18] Chettri, P., Vendamani, V. S., Tripathi, A., Singh, M. K., Pathak, A. P., & Tiwari, A. (2017). Green synthesis of silver nanoparticle-reduced graphene oxide using Psidium guajava and its application in SERS for the detection of methylene blue. Applied 406, 312–318.

      [19] Ikhsan, N. I., Rameshkumar, P., & Huang, N. M. (2016). Controlled synthesis of reduced graphene oxide supported silver nanoparticles for selective and sensitive electrochemical detection of 4-nitrophenol. Electrochimica Acta, 192, 392–399.

      [20] Huang, Q., Wang, J., Wei, W., & Yan, Q. (2015). A facile and green method for synthesis of reduced graphene oxide / Ag hybrids as efficient surface enhanced Raman scattering platforms. Journal of Hazardous Materials, 283, 123–130

  • Downloads

  • How to Cite

    Izrini Ikhsan, N., & Farahah Jaffar, N. (2019). Synthesis and Characterization of a Silver Nanoparticles-Reduced Graphene Oxide Nanohybrid by using ‘Zingiber Officinale’ Extract as a Reducing and Stabilizing Agent. International Journal of Engineering & Technology, 7(4.14), 498-501. https://doi.org/10.14419/ijet.v7i4.14.27777