Effect of usage on the fatty acid composition and properties of neat palm oil, waste palm oil, and waste palm oil methyl ester

  • Authors

    • Awogbemi Omojola University of KwaZulu Natal, Durban
    • Inambao Freddie University of KwaZulu Natal, Durban
    • Onuh Emmanuel Idoko University of KwaZulu Natal, Durban
    2020-02-07
    https://doi.org/10.14419/ijet.v9i1.29557
  • Characterization, FAME, Fatty Acid, Feedstock, Waste Palm Oil.
  • The need to find an environmentally friendly, renewable, and biodegradable fuel to reduce the growing dependence on fossil fuels and its attendant performance and emission inadequacies has increased research in biodiesel. Due to its low cost, availability, and a veritable means of waste disposal, waste vegetable oil from restaurants, waste fats from slaughterhouses, grease from wastewater treatment plants has gained prominence as biodiesel feedstock. This present effort compares the properties and fatty acid (FA) composition of neat palm oil (NPO), waste palm oil (WPO), and waste palm oil methyl ester (WPOME). WPO used to fry fish and chips (WPOFC), and waste palm oil used to fry sausage and chips (WPOSC) were collected at the point of disposal. The WPOFC and WPOSC were converted to WPOMEFC and WPOMESC, respectively, by transesterification and subjected to property determination and gas chromatography-mass spectrometer analysis. The characterization showed that the ratio of saturated FA to unsaturated FA changed from 19.64 %:80.36 % for NPO, to 37.67 %:62.33 % for WPOFC, 54.75 %:45.25 % for WPOSC, 30.43 %:69.58 % for WPOMEFC and 16.2 %:83.8 % for WPOMESC. These outcomes can be attributed to the effect of repeated heating and cooling during frying, contamination from moisture, food fried, and the transesterification reaction.

     

     

  • References

    1. [1] P. Sadorsky, "Shifts in energy consumption driven by urbanization. In: Davidson," The Oxford Handbook of Energy and Society, p. 179, 2018. https://doi.org/10.1093/oxfordhb/9780190633851.013.17.

      [2] Worldometers. "World Population by Year" . Available on http://www.worldometers.info/world-population/world-population-by-year/ [Online].

      [3] F. Soto et al., "A comparative study of performance and regulated emissions in a medium-duty diesel engine fueled with sugarcane diesel-farnesane and sugarcane biodiesel-LS9," Energy, vol. 176, pp. 392-409, 2019/06/01/ 2019. https://doi.org/10.1016/j.energy.2019.04.011.

      [4] I. Örs, S. Sarıkoç, A. E. Atabani, S. Ünalan, and S. O. Akansu, "The effects on performance, combustion and emission characteristics of DICI engine fuelled with TiO2 nanoparticles addition in diesel/biodiesel/n-butanol blends," Fuel, vol. 234, pp. 177-188, 2018/12/15/ 2018. https://doi.org/10.1016/j.fuel.2018.07.024.

      [5] L. A. Raman, B. Deepanraj, S. Rajakumar, and V. Sivasubramanian, "Experimental investigation on performance, combustion and emission analysis of a direct injection diesel engine fuelled with rapeseed oil biodiesel," Fuel, vol. 246, pp. 69-74, 2019/06/15/ 2019. https://doi.org/10.1016/j.fuel.2019.02.106.

      [6] J. C. Kurnia, S. V. Jangam, S. Akhtar, A. P. Sasmito, and A. S. Mujumdar, "Advances in biofuel production from oil palm and palm oil processing wastes&58; A review," Biofuel Research Journal, vol. 3, no. 1, pp. 332-346, 2016. https://doi.org/10.18331/BRJ2016.3.1.3.

      [7] M. Saifuddin, P. Goh, W. Ho, K. Moneruzzaman, and A. Fatima, "Biodiesel production from waste cooking palm oil and environmental impact analysis," Bulgarian Journal of Agricultural Science, vol. 20, no. 1, pp. 186-192, 2014.

      [8] Biofuel Fact Sheet: Fatty Acid Methyl Esters (FAME) (2011) Available from: http://www.etipbioenergy.eu/images/fame-fact-sheet.pdf [Online].

      [9] M. F. Awalludin, O. Sulaiman, R. Hashim, and W. N. A. W. Nadhari, "An overview of the oil palm industry in Malaysia and its waste utilization through thermochemical conversion, specifically via liquefaction," Renewable and Sustainable Energy Reviews, vol. 50, pp. 1469-1484, 2015/10/01/ 2015. https://doi.org/10.1016/j.rser.2015.05.085.

      [10] A. K. Azad, M. Rasul, M. M. K. Khan, S. C. Sharma, and M. Hazrat, "Prospect of biofuels as an alternative transport fuel in Australia," Renewable and Sustainable Energy Reviews, vol. 43, pp. 331-351, 2015. https://doi.org/10.1016/j.rser.2014.11.047.

      [11] A. E. Atabani, A. S. Silitonga, I. A. Badruddin, T. Mahlia, H. Masjuki, and S. Mekhilef, "A comprehensive review on biodiesel as an alternative energy resource and its characteristics," Renewable and sustainable energy reviews, vol. 16, no. 4, pp. 2070-2093, 2012. https://doi.org/10.1016/j.rser.2012.01.003.

      [12] I. B. Banković-Ilić, I. J. Stojković, O. S. Stamenković, V. B. Veljkovic, and Y.-T. Hung, "Waste animal fats as feedstocks for biodiesel production," Renewable and Sustainable Energy Reviews, vol. 32, pp. 238-254, 2014/04/01/ 2014. https://doi.org/10.1016/j.rser.2014.01.038.

      [13] H. H. Mardhiah, H. C. Ong, H. H. Masjuki, S. Lim, and H. V. Lee, "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, vol. 67, pp. 1225-1236, 2017/01/01/ 2017. https://doi.org/10.1016/j.rser.2016.09.036.

      [14] J. Janaun and N. Ellis, "Perspectives on biodiesel as a sustainable fuel," Renewable and Sustainable Energy Reviews, vol. 14, no. 4, pp. 1312-1320, 2010. https://doi.org/10.1016/j.rser.2009.12.011.

      [15] I. Atadashi, M. Aroua, A. A. Aziz, and N. Sulaiman, "Production of biodiesel using high free fatty acid feedstocks," Renewable and sustainable energy reviews, vol. 16, no. 5, pp. 3275-3285, 2012. https://doi.org/10.1016/j.rser.2012.02.063.

      [16] Statista. Consumption of vegetable oils worldwide from 2013/14 to 2018/2019, by oil type (in million metric tons). Available from: https://www.statista.com/statistics/263937/vegetable-oils-global-consumption/ [Online].

      [17] M. Barrientos. Palm oil. Available on https://www.indexmundi.com/about.html [Online].

      [18] Roundtable on Sustainable Palm Oil (RSPO) - 2011 (2012) Malaysia sets record as world’s largest producer of certified sustainable palm oil. 2011. Available from: https://rspo.org/news-and-events/news/malaysia-sets-record-as-worlds-largest-producer-of-certified-sustainable-palm-oil [Online].

      [19] R. Abdullah, "World Palm Oil supply, demand, price and prospects: Focus on Malaysian and Indonesian Palm Oil industries," Oil Palm Industry economic Journal, vol. 11, no. 2, pp. 13 - 25, 2011.

      [20] D. T. d. Almeida, F. M. Curvelo, M. M. Costa, T. V. J. F. S. Viana, and Technology, "Oxidative stability of crude palm oil after deep frying akara (Fried Bean Paste)," vol. 38, no. 1, pp. 142-147, 2018. https://doi.org/10.1590/1678-457x.02217.

      [21] N. Idun-Acquah, G. Y. Obeng, E. J. S. Mensah, and Technology, "Repetitive Use of Vegetable Cooking Oil and Effects on Physico-Chemical Properties–Case of Frying with Redfish (Lutjanus fulgens)," vol. 6, no. 1, pp. 8-14, 2016.

      [22] T. Mengistie, A. Alemu, and A. J. C. I. Mekonnen, "Comparison of physicochemical properties of edible vegetable oils commercially available in Bahir Dar, Ethiopia," vol. 4, no. 2, pp. 130-135, 2018.

      [23] M. Wanjiya, M. Makangila, L. J. I. J. o. E. Mukosha, Energy, and Environment, "Used Cooking Oils as a Source Material for Biodiesel Production: Case Study for Kitwe Town, Zambia," vol. 3, no. 4, p. 32, 2018. https://doi.org/10.11648/j.ijeee.20180304.11.

      [24] E. M. Shahid and Y. Jamal, "Production of biodiesel: a technical review," Renewable and Sustainable Energy Reviews, vol. 15, no. 9, pp. 4732-4745, 2011. https://doi.org/10.1016/j.rser.2011.07.079.

      [25] M. Balat and H. Balat, "Progress in biodiesel processing," Applied energy, vol. 87, no. 6, pp. 1815-1835, 2010. https://doi.org/10.1016/j.apenergy.2010.01.012.

      [26] I. Thushari, S. Babel, and C. Samart, "Biodiesel production in an autoclave reactor using waste palm oil and coconut coir husk derived catalyst," Renewable Energy, vol. 134, pp. 125-134, 2019/04/01/ 2019. https://doi.org/10.1016/j.renene.2018.11.030.

      [27] T. T. V. Tran et al., "Green biodiesel production from waste cooking oil using an environmentally benign acid catalyst," Waste management, vol. 52, pp. 367-374, 2016. https://doi.org/10.1016/j.wasman.2016.03.053.

      [28] E. M. Vargas, M. C. Neves, L. A. Tarelho, and M. I. Nunes, "Solid catalysts obtained from wastes for FAME production using mixtures of refined palm oil and waste cooking oils," Renewable Energy, 2019. https://doi.org/10.1016/j.renene.2019.01.048.

      [29] I. Thushari and S. Babel, "Preparation of solid acid catalysts from waste biomass and their application for microwave-assisted biodiesel production from waste palm oil," Waste Management & Research, vol. 36, no. 8, pp. 719-728, 2018. https://doi.org/10.1177/0734242X18789821.

      [30] F. Harahap, S. Silveira, and D. Khatiwada, "Cost competitiveness of palm oil biodiesel production in Indonesia," Energy, vol. 170, pp. 62-72, 2019. https://doi.org/10.1016/j.energy.2018.12.115.

      [31] Z. Ullah, M. A. Bustam, and Z. Man, "Biodiesel production from waste cooking oil by acidic ionic liquid as a catalyst," Renewable Energy, vol. 77, pp. 521-526, 2015/05/01/ 2015. https://doi.org/10.1016/j.renene.2014.12.040.

      [32] Sahar et al., "Biodiesel production from waste cooking oil: An efficient technique to convert waste into biodiesel," Sustainable Cities and Society, vol. 41, pp. 220-226, 2018/08/01/ 2018. https://doi.org/10.1016/j.scs.2018.05.037.

      [33] O. Awogbemi, F. L. Inambao, and E. I. Onuh, "Development and Characterization of Chicken Eggshell waste as Potential Catalyst For Biodiesel Production," International Journal of Mechanical Engineering and Technology,, vol. 9, no. 12, pp. 1329 - 1346, 2018.

      [34] BS EN 14214:2012+A2:2019 (2019) Liquid petroleum products. Fatty acid methyl esters (FAME) for use in diesel engines and heating applications. Requirements and test methods. Available from: https://shop.bsigroup.com/ProductDetail/?pid=000000000030217517.

      [35] M. Bockisch, Fats and oils handbook (Nahrungsfette und Öle). Amsterdam: Elsevier, 2015.

      [36] Use of pH meter. Available from: webserver.mbi.ufl.edu/~rowland/protocols/phmeter.pdf [Online]. Congealing temperature. Available from: https://www.drugfuture.com/Pharmacopoeia/usp38/data/v38332/usp38nf33s2_c651.html [Online].

      [37] Shimadzu Corporation (2008) Equipment manual. Gas Chromatograph Mass Spectrometer GCMS-QP2010 Plus. Scimadzu Corporation, Japan,. Scimadzu Corporation, Japan.

      [38] P. Verma and M. P. Sharma, "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, vol. 62, pp. 1063-1071, 2016/09/01/ 2016. https://doi.org/10.1016/j.rser.2016.04.054.

      [39] L. F. Chuah, J. J. Klemeš, S. Yusup, A. Bokhari, and M. M. Akbar, "Influence of fatty acids in waste cooking oil for cleaner biodiesel," Clean Technologies and Environmental Policy, vol. 19, no. 3, pp. 859-868, 2017. https://doi.org/10.1007/s10098-016-1274-0.

      [40] M. Canakci and A. N. Özsezen, "Evaluating waste cooking oils as alternative diesel fuel," Gazi University Journal of Science, vol. 18, no. 1, pp. 81-91, 2005.

      [41] T. H. DoÄŸan, "The testing of the effects of cooking conditions on the quality of biodiesel produced from waste cooking oils," Renewable Energy, vol. 94, pp. 466-473, 2016/08/01/ 2016. https://doi.org/10.1016/j.renene.2016.03.088.

      [42] M. N. Uddin, K. Techato, M. G. Rasul, N. M. S. Hassan, and M. Mofijur, "Waste coffee oil: A promising source for biodiesel production," Energy Procedia, vol. 160, pp. 677-682, 2019/02/01/ 2019. https://doi.org/10.1016/j.egypro.2019.02.221.

      [43] J. Chebet, T. Kinyanjui, and P. K. Cheplogoi, "Impact of frying on iodine value of vegetable oils before and after deep frying in different types of food in Kenya," Journal of Scientific and Innovative Research, vol. 5, no. 5, pp. 193-196, 2016.

      [44] E. A. Alhibshi, J. A. Ibraheim, and A. S. Hadad, "Effect of heat processing and storage on characteristic and stability of some edible oils," in Proceedings 6th Int'l Conference on Agriculture, Environment and Biological Sciences. doi, 2016, vol. 10.

      [45] L. F. Chuah, S. Yusup, A. R. Abd Aziz, A. Bokhari, J. J. Klemeš, and M. Z. Abdullah, "Intensification of biodiesel synthesis from waste cooking oil (Palm Olein) in a Hydrodynamic Cavitation Reactor: Effect of operating parameters on methyl ester conversion," Chemical Engineering and Processing: Process Intensification, vol. 95, pp. 235-240, 2015/09/01/ 2015. https://doi.org/10.1016/j.cep.2015.06.018.

      [46] T. Maneerung, S. Kawi, Y. Dai, and C.-H. Wang, "Sustainable biodiesel production via transesterification of waste cooking oil by using CaO catalysts prepared from chicken manure," Energy Conversion and Management, vol. 123, pp. 487-497, 2016/09/01/ 2016. https://doi.org/10.1016/j.enconman.2016.06.071.

      [47] Y. M. Zein, A. K. Anal, D. Prasetyoko, and I. Qoniah, "Biodiesel Production from Waste Palm Oil Catalyzed by Hierarchical ZSM-5 Supported Calcium Oxide," Indonesian Journal of Chemistry, vol. 16, no. 1, pp. 98-104, 2016. https://doi.org/10.22146/ijc.21184.

      [48] S. A. Kadapure et al., "Studies on process optimization of biodiesel production from waste cooking and palm oil," vol. 11, no. 3, pp. 167-172, 2018. https://doi.org/10.1080/19397038.2017.1420107.

      [49] W. E. Artz, P. C. Osidacz, and A. R. Coscione, "Iron accumulation in oil during the deepâ€fat frying of meat," Journal of the American Oil Chemists' Society, vol. 82, no. 4, p. 249, 2005. https://doi.org/10.1007/s11746-005-1063-8.

      [50] E. Choe and D. Min, "Chemistry of deepâ€fat frying oils," Journal of food science, vol. 72, no. 5, pp. R77-R86, 2007. https://doi.org/10.1111/j.1750-3841.2007.00352.x.

      [51] V. P. Nguyen, H. H. M. Nguyen, D. T. Nguyen, H. L. Nguyen, and T. M. Huynh, "Optimization of biodiesel production from waste cooking oil using static mixer technology in Vietnam," Biofuels, pp. 1-8, 2018. https://doi.org/10.1080/17597269.2018.1426165.

      [52] S. K. Nayak, P. C. Mishra, and G. R. Behera, "Experimental investigation on dual-fuel engine utilizing waste cooking oil and producer gas," Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, vol. 39, no. 4, pp. 369-376, 2017. https://doi.org/10.1080/15567036.2015.1122684.

      [53] Ä°. Rahmanlar, S. Yücel, and D. Özçimen, "The Production of methyl esters from waste frying oil by microwave method," Asiaâ€Pacific Journal of Chemical Engineering, vol. 7, no. 5, pp. 698-704, 2012. https://doi.org/10.1002/apj.620.

  • Downloads

  • How to Cite

    Omojola, A., Freddie, I., & Emmanuel Idoko, O. (2020). Effect of usage on the fatty acid composition and properties of neat palm oil, waste palm oil, and waste palm oil methyl ester. International Journal of Engineering & Technology, 9(1), 110-117. https://doi.org/10.14419/ijet.v9i1.29557