Arsenic behavior in the autoclave-hydrometallurgical processing of refractory sulfide gold-platinum-bearing products
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2018-03-05 https://doi.org/10.14419/ijet.v7i2.2.9897 -
Refractory Sulphide Gold-Bearing Ores, Arsenic, Autoclave Oxidative Leaching, Neutralization, Iron Arsenate, Arsenic-Bearing Precipitation. -
Abstract
Among various types of gold-bearing ores a special place belongs to the ores, which contain gold finely-dispersed in sulphide minerals, mostly in arseno-pyrite and pyrite. Autoclave-hydrometallurgical processing technologies for such raw materials seem to be of a particular interest for study. However, autoclave oxidation of sulfide-arsenic material results in significant amounts of technological solutions with high concentrations of arsenic, iron and sulfuric acid.
This article represents the studies of how arsenic behaves in autoclave oxidative leaching of a refractory sulphide gold-platinum-bearing concentrate. We studied how the composition of arsenic-bearing solutions in autoclave leaching (acidity, concentration of iron and arsenic) influences the depth of arsenic precipitation when neutralized with calcium-containing reagents, which allows converting the maximum amount of arsenic together with iron in the form of iron arsenate into a stable long-term storable precipitation.
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References
[1] Adams M.D. (ed.) Advances in gold ore processing. Elsevier Science, 2005. 1076 p.
[2] Cabri L.J., Chryssoulis S.L., De Villers, J.P.R. Laflamme, J.H.G. and Busek P.R. The nature of ‘invisible gold’ in arsenopyrite. The Canadian Mineralogist, 27, 1990. 353 pp.
[3] Chekushin V.S., Oleynikova N.V. Pererabotkazolotosoderzhashchikhrudnykhkontsentratov (obzormetodov) [Processing of gold ore concentrates (overview of methods)] // IzvestiyaChelyabinskogonauchnogotsentra [Proceedings of the Chelyabinsk Scientific center]. 2005. â„–4 (30). pp. 94-110.
[4] Yannopoulos J.C. Treatment of Refractory Gold Ores. In: The Extractive Metallurgy of Gold. Springer, Boston, MA. 1991. pp. 79-114.https://doi.org/10.1007/978-1-4684-8425-0_5.
[5] Nabojchenko S.S., Shneerson Y.M., Kalashnikova M.I., Chugaev L.V. Avtoklavnajagidrometallurgijacvetnyhmetallov [Autoclaved hydrometallurgy of non-ferrous metals]. Ekaterinburg: GOU UGTU-UPI, 2009. V. 2. 939 p.
[6] Boginskaya A.S., Markelov A.V., Shneerson Y.M., Petrov G.V. Application of mathematical modeling for calculation of autoclave leaching process of refractory sulfide auriferous flotation concentrate // Fundamental research. 2014. â„–3ÑŽ 710-706.
[7] Sánchez M.A., Vergara F., Castro S.H. The removal of arsenic from hydrometallurgical process and effluent streams. University of Concepción. 2000. 10 р.
[8] Fokina S.B. Obzormetodovochistkimysh'yaksoderzhashchikhstochnykhvodmetallurgicheskikhproizvodstv [Methods of sewage treatment of metallurgical manufactures containing arsenic] // Mining informational and analytical bulletin. 2012. â„–2. pp. 406-409.
[9] USEPA (U.S. Environmental Protection Agency). Arsenic treatment technologies for soil waste and water. Office of Solid Waste and Emergency Response. EPA-542-R-02-004. September 2002. 132 p.
[10] Yakovlev S.V., KarelinYa.A., LaskovYu.N., Voronov Yu.V. Ochistkaproizvodstvennykhstochnykhvod [Industrial wastewater treatment]. M.: Stroyizdat, 1979. 320 p.
[11] Demopoulos G.P., Droppert D.J., WeertG.Van, Harris B. and E.Krause. Option for the immobilization of arsenic as crystalline scorodite // Impurity Control and Disposal in Hydrometallurgical Processes. CIM, Montreal. 1994. P. 57-69.
[12] Robins R.G., Kudryk V., Corrigan D.A., Liang W.W. The Stability of arsenic in gold mine processing wastes / // Precious metals: Mining, extraction and processing. 1984. February 27 -29. pp. 241-249.
[13] Golovnev N.N., Egizaryan M.B. Rastvorimost' arsenatakal'tsiya v karbonatnykhrastvorakh [The solubility of calcium arsenate in carbonate solutions] // Zhurnalneorganicheskoykhimii [Journal of Inorganic Chemistry]. 1994. â„–1 (V.39). pp. 37-39.
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How to Cite
V. Petrov, G., B. Fokina, S., Y. Boduen, A., E. Zotova, I., & F. Fidarov, B. (2018). Arsenic behavior in the autoclave-hydrometallurgical processing of refractory sulfide gold-platinum-bearing products. International Journal of Engineering & Technology, 7(2.2), 35-39. https://doi.org/10.14419/ijet.v7i2.2.9897Received date: 2018-03-05
Accepted date: 2018-03-05
Published date: 2018-03-05