Effect of carbonization temperature on properties of char from coconut shell

  • Authors

    • U. F. Hassan Sheda Science and Technology Complex, Abuja, Nigeria.
    • A. A. Sallau
    • E. O. Ekanem
    • A. Jauro
    • A. M. Kolo
    2021-04-14
    https://doi.org/10.14419/ijac.v9i1.31433
  • Biomass, Carbonization, Correlation, Morphology, Stacking.
  • Abstract

    The study Investigate the effect of carbonization temperature on properties of coconut shell. The carbonization was carried out at 600, 800, 1000 and 1150°C temperatures for 1 hour under inert condition. The derived chars were proximately, ultimately and structurally analyzed. The results show that there was a significant change in the volatile matter, fixed carbon percentage, elemental C and its functional group as temperature increases. The moisture content and percentage yield decrease with increasing temperature. The morphological characterization of the materials shows fibrous nature of the raw samples while the char products show developed pores which are suitable for adsorption, movement of electrolyte ions and reduced diffusion resistance. The electrical properties of char improved from 3.52 x10-8 to 6.78 x10-2 S/cm as temperature increases from 600°C to 1150°C. results from X-ray diffractometer analysis showed improved graphitic properties; which suggest a possible use of the char samples particular the PKS1150 in electrode fabrication material.

     

     

  • References

    1. [1] Abugu, H. O., Okoye, P. A. C.; Ajiwe, V. I. E. and Ofordile. P. C. (2014). Preparation and Characterisation of Activated Carbon from Agrowastes Peanut Seed (African Canarium) and Palm Kernel Shell. International journal of innovative research & development. 3(13), 418-441. www.ijird.com.

      [2] Agu, H. O., Ukonze, J. A. and Uchola, N. O. (2008). Quality and characteristics of crude and refined Atili Oils. Pakistan journal of nutrition.7(1), 27-30. https://doi.org/10.3923/pjn.2008.27.30

      [3] Bogeat, B. A. (2019): Understanding and Tuning the Electrical Conductivity of Activated Carbon: A State-of-the-Art Review, Critical Reviews in Solid State and Materials Sciences. DOI: 10.1080/10408436.2019.1671800

      [4] Ding, Y., Wang, T., Dong, D. and Zhang, Y. (2020). Using biochar and coal as the electrode material for supercapacitor applications. Front. Energy

      Research. 7:159. doi: 10.3389/fenrg.2019.00159

      [5] Ewansiha, J. C., Ebhoaye, E. J., Asia, O. I., Ekebafe, O. L. and Ehigie, C. (2012). Proximate and Mineral Composition of Coconut (Cocos Nucifera) Shell. International Journal of Pure Applied Science Technology. 13(1), 57-60. www.ijopaasat.in

      [6] Girgis, S. B., Temerk, M. Y., Gadelrab, M. M. and Abdullah, D. I. (2007). X-ray Diffraction

      [7] Hoffmann, V., Rodriguez, C. C., Sautter, D., Maringolo, E. and Kruse, A. (2019). Study of the electrical conductivity of biobased carbonaceous powder materials under moderate pressure for the application as electrode materials in energy storage technologies. GCB Bioenergy. 11:230–248.

      [8] Patterns of Activated Carbons Prepared under Various Conditions. Carbon science. 8(2), 95-100. https://doi.org/10.5714/CL.2007.8.2.095.

      [9] Kang, S. D., Lee, M. S., Lee, H. S. and Roh, S. J. (2018). X-ray diffraction analysis of the crystallinity of phenolic resin-derived carbon as a function of the heating rate during the carbonization process. Carbon Letters. 27,108-111. DOI: http://dx.doi.org/DOI:10.5714/CL.2018.27.108

      [10] Kwon, H. J., Park, B. S., Ayrilmis, N., Oh, W. S. and Kim, H. N. (2013). Effect of carbonization temperature on electrical resistivity and physical properties of wood and wood-based composites. Composites: Part B 46, 102–107. http://dx.doi.org/10.1016/j.compositesb.2012.10.012

      [11] Lee, C. L., H’ng, P. S., Paridah, T., Chin, L. K., Khoo, S. P., Nazrin, R. A. R., Asyikin, N. S. and Maminski, M. (2017). Effect of Reaction time and temperature on the properties of carbon black from palm kernel and coconut shell. Asian Journal of Scientific Research. 10(1), 24-33. https://doi.org/10.3923/ajsr.2017.24.33.

      [12] Li, W., Yanga, K., Penga, J., Zhanga, L., Guoa, S. and Xiaa, H. (2008). Effects of carbonization temperatures on characteristics of porosity in coconut shell chars and activated carbons derived from carbonized coconut shell chars. Industrial crops and products 2(8):190–198. https://doi.org/10.1016/j.indcrop.2008.02.012.

      [13] Liu, Y., He, Z. and Uchimiya, M. (2015). Comparison of Biochar Formation from Various Agricultural By-Products Using FTIR Spectroscopy. Modern Applied Science. 9(4). 246-253. https://doi.org/10.5539/mas.v9n4p246.

      [14] Liyanage D. C. and Pieris, M. (2015). A physico-chemical analysis of coconut shell powder. Procedia chemistry. 16. 222-228. www.sciencedirect.com. https://doi.org/10.1016/j.proche.2015.12.045.

      [15] Ma, X., Yuan, C. and Liu, X. (2014). Mechanical, Microstructure and Surface Characterizations of Carbon Fibers Prepared from Cellulose after Liquefying and Curing. Materials. 7:75-84. https://doi.org/10.3390/ma7010075.

      [16] Mas’udah, W. K., Astuti, F. and Darminto (2016). Study on Physical Properties of Reduced Graphene Oxide from Heating Coconut Shell. Journal of Physical Science and Engineering. 1(1). 1 – 6. http://journal2.um.ac.id/index.php/jpse. https://doi.org/10.17977/um024v1i12016p001.

      [17] Mochidzuki, K., Soutric, F., Tadokoro, K., Antal, J. M., Toth, M., Zelei, B. and Varhegyi, G. (2003). Electrical and Physical Properties of Carbonized Charcoals. Ind. Eng. Chem. Res. 42, 5140-5151.

      [18] Njeugna, E., D. Ndapeu, D., Bistac, S., Drean, Y. J., Ngenefeme J. F. and Fogue, M. (2013). Contribution to the Characterization of the Coconut Shells (Coco Nucifera) of Cameroon. International Journal of Mechanics Structural. 4(1):1-23. http://www.irphouse.com

      [19] Noh, C. H. C., Azmin, N. F. M. and Amid, A. (2017). Principal Component Analysis Application

      [20] on Flavonoids Characterization. Advances in Science, Technology and Engineering Systems Journal (2) 3, 435-440.

      [21] Ojha, S., Raghavendra, G. and Acharya, S. K. (2016). Effect of Carbonized Coconut Shell Particles on Mechanical Properties of Bio-Based Composite. Journal of Mineral Metal and Material Engineering.2:6-10. http://creativecommons.org/licenses/by-nc/3.0/. https://doi.org/10.20941/2414-2115.2016.02.2.

      [22] Olowoyo D. N. and Orere E. E (2012). Preparation and Characterization of Activated Carbon Made from Palm-Kernel Shell, Coconut Shell, Groundnut Shell and Obeche Wood (Investigation of Apparent Density, Total Ash Content, Moisture Content, Particle Size Distribution Parameters. International Journal of Research in Chemistry and Environment. 2(3),32-35. www.ijrce.org

      [23] Rampe, J. M., Setiaji, B., Trisunaryanti, W. and Triyono (2011). Fabrication and Characterization of Carbon Composite from Coconut Shell Carbon. Indonesian journal of chemistry, 11 (2):124 – 130 https://doi.org/10.22146/ijc.21398.

      [24] Reeves, J. (2012). Mid-infrared spectroscopy of biochars and spectral similarities to coal and kerogens: what are the implications? Appl. Spectr.. 66:689-695. https://doi.org/10.1366/11-06478.

      [25] Sanguansat, P. (ed.). (2012). Principal component analysis - engineering applications. Intech, Rijeka, Croatia. https://doi.org/10.5772/2693.

      [26] Satheesh, M., Pugazhvadivu, M., Prabu, B., Gunasegaran, V. and Manikandan, A. (2019). Synthesis and Characterization of Coconut Shell Ash. Journal of Nanoscience and Nanotechnology. 19. 4123–4128. www.aspbs.com/jnn. https://doi.org/10.1166/jnn.2019.16299.

      [27] Stein, I. Y., Ashley L. K., Alexander J. C., Luiz A. and Brian L. W. (2017). “Mesoscale Evolution of Non-Graphitizing Pyrolytic Carbon in Aligned Carbon Nanotube Carbon Matrix Nanocomposites.†Journal of Materials Science. 52(24):13799–13811. https://doi.org/10.1007/s10853-017-1468-9.

      [28] Sulistyania, E., Tamadoa, B. D., Wulandaria, F. and Budi, E. (2015). Coconut Shell Activated Carbon as an Alternative Renewable Energy. New, Renewable Energy and Energy Conservation Conference and Exhibition. 2:76-81. https://doi.org/10.18502/ken.v2i2.360.

      [29] Tangsathitkulchai, C., Junpirom, S. and Katesa, J. (2013). Comparison of Kinetic Models for CO2 Gasification of Coconut-Shell Chars: Carbonization Temperature Effects on Char Reactivity and Porous Properties of Produced Activated Carbons. Engineering journal 17(1). http://www.engj.org/ https://doi.org/10.4186/ej.2013.17.1.13.

      [30] Tangsathitkulchai, C., Junpirom, S. and Katesa, J. (2016). Carbon Dioxide Adsorption in Nanopores of Coconut Shell Chars for Pore Characterization and the Analysis of Adsorption Kinetics. Journal of Nanomaterials. 2016. https://doi.org/10.1155/2016/4292316.

      [31] Wachid, M. F., Adhi Y. Perkasa, Fandi A. Prasetya, Nurul Rosyidah, and Darminto (2014). Synthesis and characterization of nanocrystalline graphite from coconut shell with heating process. AIP Conference Proceedings 1586, 202. https://doi.org/10.1063/1.4866759.

      [32] Wang, P., Zhang, J., Shao, O., Wang, G. (2018). Physicochemical properties evolution of chars from palm kernel shell pyrolysis. Journal of Thermal Analysis and Calorimetry. https://doi.org/10.1007/s10973-018-7185-z.

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  • How to Cite

    F. Hassan, U., A. Sallau, A., O. Ekanem, E., Jauro, A., & M. Kolo, A. (2021). Effect of carbonization temperature on properties of char from coconut shell. International Journal of Advanced Chemistry, 9(1), 34-39. https://doi.org/10.14419/ijac.v9i1.31433

    Received date: 2021-02-06

    Accepted date: 2021-03-03

    Published date: 2021-04-14