The effect of Triton X surfactants on Pb (II) transport rate using bulk liquid membrane systems

  • Authors

    • Mersiha Suljkanovic University of Tuzla
    • Jasmin Suljagić University of Tuzla
    • Mustafa PaÅ¡ić University of Tuzla
    2021-03-28
    https://doi.org/10.14419/ijac.v9i1.31451
  • Bulk Liquid Membrane Transport, Pb (II), Triton X Surfactants.

  • Implementation of the "bulk liquid membrane" (BLM) system was investigated in terms of its efficiency for selective removal of heavy metal ions from natural resources and industrial wastewater. In this paper, the removal of lead (II) ions through a liquid membrane system and factors that influence the process were examined. The research was performed using the homemade transport cell. Two organic solvents were used as liquid membranes: 1,2-dichloroethane and chloroform. Metal ion concentration in aqueous phases was monitored by flame atomic absorption spectrophotometry, after 4 hours of experiment. Macrocyclic ether (dicyclohexano-18-crown-6) was used as ligand for Pb (II) ions. The effects of nonionic surfactants (Triton X-100, Triton X-45 and Triton X-405) added in the receiving phase of BLM system were investigated. The results showed significant increase in transport rate compared to systems without surfactants. Considering the surfactant structure, transport rate of Pb (II) ions followed the order: TX-100 >TX-45>TX-405. Presence of TX-100 increased transport of Pb (II) ions up to 78% through chloroform and 58% through 1,2-dichloroethane.

     

     

  • References

    1. [1] Alguacil FJ (2002) Facilitated transport separation of manganese cobalt by a supported liquid membrane using DP-8R as a mobile carrier. Hydrometallurgy 65(1), 9–14. https://doi.org/10.1016/S0304-386X(02)00059-2.

      [2] Amini MK, Shamsipur M (1992) Complex formation of hydronium ion with several crown ethers in 1, 2-dichloroethane, acetonitrile, and nitrobenzene solutions. Journal of Solution Chemistry 21, 275-288. https://doi.org/10.1007/BF00647023.

      [3] Bjelić E, Suljkanović M, Suljagić J, KovaÄević A (2020) Application of Different Ligands to Optimize Cd (II) Removal Through Liquid Membranes. Advances in Analytical Chemistry 10(1), 7-10. https://doi.org/10.14445/23939133/IJAC-V7I1P102.

      [4] Bjelić E, Suljkanović M, Suljagić J, KovaÄević A (2020) The Role of Sodium Dodecyl Benzen Sulfonate in Removal of Pb (II) ions Through Bulk Liquid Membrane Systems. Proceedings of the IX International conference of social and technological development, 372-377.

      [5] Chang SH, Teng TT, Ismail N (2010) Extraction of Cu (II) from aqueous solutions by vegetable oil-based organic solvents. Journal of Hazardous Materials 181, 868–872. https://doi.org/10.1016/j.jhazmat.2010.05.093.

      [6] Fahmideh-Rad E, Rounaghi GH, Arbab Zavar, MH, Chamsaz M (2010) Spectrometric determination of Pb2+ cation after selective bulk liquid membrane transport using benzo-18-crown-6 as carrier. Der Pharma Chemica 2(6), 8-18.

      [7] Izatt RM, Pawlak K, Bradshaw (1991) Thermodynamic and kinetic data for macrocyclic interactions with cations and anions. Journal of Scientific Chemical Reviews 91 (8), 1721. https://doi.org/10.1021/cr00008a003.

      [8] Kakhki RMZ, Rounaghi GH (2011) Competitive bulk liquid membrane transport of heavy metal ions. Journal of Chemical & Engineering Data 56, 3169–3174. https://doi.org/10.1021/je200220d.

      [9] Kashanian S, Shamsipur M (1989) Complex formation of alkaline earth cations with benzo-15-crown-5 and some 18-crowns in methanol, dimethylformamide and dimethyl sulfoxide solutions. Inorganica Chimica Acta 155, 203-206. https://doi.org/10.1016/S0020-1693(00)90410-9.

      [10] Kazemi MS, Rounaghi GH (2010) Highly selective transport of lead cation through bulk liquid membrane by macrocyclic ligand of decyl-18-crown-6 as carrier. Russian Journal of Inorganic Chemistry 55 (12), 1987–1991. https://doi.org/10.1134/S0036023610120272.

      [11] Nipamanjari D, Sanjib B, Mukherjee AK (2010) Charge transfer complex formation between TX-100/CCl4. Molecular Physics 108 (11), 1505–1511. https://doi.org/10.1080/00268971003762126.

      [12] Reusch CF, Cussler EL (1973) Selective membrane transport. AlChE Journal 19(4), 736-741. https://doi.org/10.1002/aic.690190409.

      [13] Rounaghi GH, Arbab-Zavar MH, Fahmideh-Rad E (2009) Transport Study of Metal Cations Through a Bulk LiquidMembrane Using Benzo-18-crown-6 as an Ionophore. Asian Journal of Chemistry 21(2), 1389.

      [14] Salman SR, Derwish GAW, Al-Marsoumi SMH, (1996) Molecular complexes of crown ethers, part 4 Complexes of crown ethers with picric acid, Journal of Inclusion Phenomena and Molecular Recognition in Chemistry 25, 295-302. https://doi.org/10.1007/BF01044999.

      [15] Shokrollahi A, Ghaedi M, Shamsipur M (2009) Highly selective transport of mercury (II) ion through a bulk liquid membrane. Quimica Nova 32(1), 153-157. https://doi.org/10.1590/S0100-40422009000100029.

      [16] Suljkanović M, Nurković E, Suljagić J, (2017) Influence of nonionic surfactants as competitive carriers in Bulk Liquid Membrane transport of metal cations using macrocyclic ligands. Journal of Chemical, Biological and Physical Sciences 8(1), 77-89. https://doi.org/10.24214/jcbps.A.8.1.07789.

      [17] Suljkanović M, Bjelić E, Suljagić J, KovaÄević A (2020) The Effect Of Nonionic Surfactants on Cadmium (II) Removal Rate Using Bulk Liquid Membrane System. Proceedings of the XI International Scientific Agricultural Symposium “Agrosym 2020â€, 645-650.

  • Downloads

  • How to Cite

    Suljkanovic, M., Suljagić, J., & Pašić, M. (2021). The effect of Triton X surfactants on Pb (II) transport rate using bulk liquid membrane systems. International Journal of Advanced Chemistry, 9(1), 25-28. https://doi.org/10.14419/ijac.v9i1.31451